A Surface Chemistry Approach to Tailoring the Hydrophilicity and Lithiophilicity of Carbon Films for Hosting High‐Performance Lithium Metal Anodes

Porous carbon scaffolds can host lithium (Li) metal anodes to potentially enable stable Li metal batteries. However, the poor Li metal wettability on the carbon surface has inhibited the uniform distribution of metallic Li on most carbon scaffolds. Herein, this work reports a lithiophilic top layer through mild surface ozonolysis and ammoniation methods can universally facilitate the infiltration of liquid Li metal into most carbon matrices. Based on this finding, thin, a lightweight Li@carbon film (CF) composite anode with a high practical capacity of 3222 mAh g^?1 and suppressed volume expansion and dendrite formation is reported. It is observed that the deep stripping/plating pre‐cycling yields dense, trunky Li metal in the Li@CF composite, which allows for favorable long‐term cycling performance. The full cell combining the thin Li@CF composite anode and a high‐mass‐loading, cobalt‐free cathode can deliver high reversible capacity, good cycle stability, and good rate capability in the conventional carbonate electrolyte. The present study further establishes the relationship between lithiophilicity and hydrophilicity for carbon materials as well as provides insights into improving the liquid Li metal infiltration into other carbon scaffolds.     

How r-Plane Al<Subscript>2</Subscript>O<Subscript>3</Subscript> Surface Modifications Impact the Growth of Epitaxial (001) CeO<Subscript>2</Subscript> Thin Films

We present evidence that it is the presence or absence of atomic terraces with a specific crystallographic orientation on the (102) Al₂O₃ surface that promotes growth of single-crystal (001) CeO₂ films over polycrystalline (111) CeO₂ films. The CeO₂ film nucleates so that the [010] and [100] directions of the film align parallel and perpendicular to the terrace edges. In the absence of terraces, multidomain (111) CeO₂ films result in which the in-plane orientation of the two domains are rotated by 85.71°, so that a [110] CeO₂ direction aligns parallel to either the or Al₂O₃ direction.     

Design of linear equalizers optimized for the structural similarity index.

We propose an algorithm for designing linear equalizers that maximize the structural similarity (SSIM) index between the reference and restored signals. The SSIM index has enjoyed considerable application in the evaluation of image processing algorithms. Algorithms, however, have not been designed yet to explicitly optimize for this measure. The design of such an algorithm is nontrivial due to the nonconvex nature of the distortion measure. In this paper, we reformulate the nonconvex problem as a quasi-convex optimization problem, which admits a tractable solution. We compute the optimal solution in near closed form, with complexity of the resulting algorithm comparable to complexity of the linear minimum mean squared error (MMSE) solution, independent of the number of filter taps. To demonstrate the usefulness of the proposed algorithm, it is applied to restore images that have been blurred and corrupted with additive white gaussian noise. As a special case, we consider blur-free image denoising. In each case, its performance is compared to a locally adaptive linear MSE-optimal filter. We show that the images denoised and restored using the SSIM-optimal filter have higher SSIM index, and superior perceptual quality than those restored using the MSE-optimal adaptive linear filter. Through these results, we demonstrate that a) designing image processing algorithms, and, in particular, denoising and restoration-type algorithms, can yield significant gains over existing (in particular, linear MMSE-based) algorithms by optimizing them for perceptual distortion measures, and b) these gains may be obtained without significant increase in the computational complexity of the algorithm.     

Monitoring the Formation of a CH3NH3PbI3–xClx Perovskite during Thermal Annealing Using X‐Ray Scattering

Grazing incidence wide and small angle X‐ray scattering (GIWAXS and GISAXS) measurements have been used to study the crystallization kinetics of the organolead halide perovskite CH₃NH₃PbI_3–xCl_x during thermal annealing. In situ GIWAXS measurements recorded during annealing are used to characterize and quantify the transition from a crystalline precursor to the perovskite structure. In situ GISAXS measurements indicate an evolution of crystallite sizes during annealing, with the number of crystallites having sizes between 30 and 400 nm increasing through the annealing process. Using ex situ scanning electron microscopy, this evolution in length scales is confirmed and a concurrent increase in film surface coverage is observed, a parameter crucial for efficient solar cell performance. A series of photovoltaic devices are then fabricated in which perovskite films have been annealed for different times, and variations in device performance are explained on the basis of X‐ray scattering measurements.     

Nanoimprint lithography fabrication of waveguide-integrated optical gratings with inexpensive stamps

We demonstrate that a replica grating can be effectively used as an inexpensive stamp for nanoimprint lithography to pattern diffractive optical couplers integrated with planar optical waveguides. Imprinted grating patterns were integrated with silicon oxynitride waveguide films to be used as an evanescent wave sensor in the input grating-coupler configuration. An anti-adhesion layer using an inexpensive, two-step chemical functionalization was developed for the stamps. The stamps were able to withstand imprint temperatures ranging from 140 to 190 °C and high fidelity imprints were obtained. The groove pattern was integrated in waveguide films by etch transfer and light-coupling properties of gratings with 1.2 μm pitch were tested using a λ = 1.55 μm laser. Compared to etched silicon masters, replica optical gratings provide uniform pattern density over their entire surface with no unstructured regions, are inexpensive, and readily available for R&D use.     

Synthesis and Characterization of <Emphasis Type="Italic">p</Emphasis>-Type Pb<Subscript>0.5</Subscript>Sn<Subscript>0.5</Subscript>Te Thermoelectric Power Generation Elements by Mechanical Alloying

A mechanical alloying (MA) process to transform elemental powders into solid Pb_0.5Sn_0.5Te with thermoelectric functionality comparable to melt-alloyed material is described. The room-temperature doping level and mobility as well as temperature-dependent electrical conductivity, Seebeck coefficient, and thermal conductivity are reported. Estimated values of lattice thermal conductivity (0.7 W m⁻¹ K⁻¹) are lower than some reports of functional melt-alloyed PbSnTe-based material, providing evidence that MA can engender the combination of properties resulting in highly functional thermoelectric material. Though doping level and Sn composition have not been optimized, this material exhibits a ZT value >0.5 at 550 K.     

A Test of the Equality of Survival Distributions Based on Paired Observations from Conditionally Independent Exponential Distributions

A model describes the joint distribution of paired survival times based on certain reasonable assumptions appropriate for biological data generated in a clinical trial setting or for certain failure data. An exact parametric test for equality of mean survival times for data following this distribution is developed. The power of the exact test is investigated by a computer simulation study for various sample sizes and values of the model parameters and compared to that of alternative tests. Heretofore, researchers desiring to analyze paired survival data have resorted to paired t tests or nonparametric procedures such as the sign test or signed ranks test. The t-test is invalid for non-normally distributed data although the robustness of the test might minimize the difficulty. The nonparametric tests, by their nature, fail to use the data completely. This paper presents an exact parametric test based on a distribution whose justification requires rather modest and reasonable assumptions. Critical values for the test can be obtained from a table of the chi-square distribution. This exact test appears to be a viable alternative to non-parametric approaches to the analysis of paired survival data. It is extremely easy to calculate on a hand calculator. In fact, since no data storage is required (unlike the signed ranks test), the calculations can be readily programmed on a programmable calculator. The modeling of bivariate and multivariate survival data we believe has not been adequately addressed in the statistical and engineering literature. We hope that this paper will spark additional work.     

Theoretical basis for controlling minimal tumor temperature duringinterstitial conductive heat therapy

This paper describes simulation of steady-state intratumoral temperatures achieved by a simple modality of local heat therapy: interstitial treatment with parallel arrays of warmed, conductive heating elements. During "conductive heating" power is directly deposited only in the interstitial probes. Adjacent tissue is warmed by heat conduction. Simulations of interstitial conductive heating involved solution of the bioheat transfer equation on a digital computer using a finite difference model of the treated tissue. The simulations suggest that when the complete temperature distributions for conductive interstitial hyperthermia are examined in detail, substantial uniformity of the temperature distributions is evident. Except for a thin sleeve of tissue surrounding each heating element, a broad, flat central valley of temperature elevation is achieved, with a well defined minimum temperature, very close to modal and median tissue temperatures. Because probes are inserted directly in tumor tissue, the thin sleeve of overheated tissue would not be expected to cause normal tissue complications. The temperature of the heated probes must be continuously controlled and increased in the face of increased blood flow in order to maintain minimum tumor temperature. However, correction for changes in blood flow is possible by adjusting probe temperature according to a feedback control scheme, in which power dissipation from each probe is the sensed input variable. Conductive interstitial heating with continually controlled probe temperature deserves investigation as a technique for local hyperthermia therapy.     

Effects of drought on yield and on grain and malt characters in spring barley

The effects on yield and on grain and malt characters, of drought stress applied at different stages of grain development and ripening were studied in three varieties of spring barley grown in a glasshouse. Differences between variety means were found for most of the characters studied, but only for wort filtration time was there a significant interaction between variety and irrigation treatment. Grain yield was reduced by all the treatments involving drought stress and the reduction was greatest when stress was applied at heading and maintained for at least 14 days. A similar response was found for the number of ears per plant. Number of grains per main-shoot ear was reduced by drought stress applied at heading but not when the stress was applied from 32 days after heading until harvest. Grain size was significantly reduced by all treatments. Raw-grain characters known to be correlated with malt extract were found to be affected by the treatments: grain nitrogen content, barley extract viscosity and the rate of sedimentation of barley flour in ethanol were all increased by drought stress, the degree of response varying with the length and timing of the period of drought. Malt extracts were reduced by drought stress whether this was applied early or late in grain development. Malting loss and germinative energy were reduced, and wort filtration time increased by late stress. α-Amylase activity in the germinating grain was unaffected by any of the treatments.