Phosphate recovery through struvite precipitation by CO2 removal: effect of magnesium, phosphate and ammonium concentrations

In the present study, the precipitation of struvite (MgNH(4)PO(4)·6H(2)O) using the CO(2) degasification technique is investigated. The precipitation of struvite was done from supersaturated solutions in which precipitation was induced by the increase of the solution supersaturation concomitant with the removal of dissolved carbon dioxide. The effect of magnesium, phosphate and ammonium concentrations on the kinetics and the efficiency of struvite precipitation was measured monitoring the respective concentrations in solution. In all cases struvite precipitated exclusively and the solid was characterized by powder XRD and FTIR. The morphology of the precipitated crystals was examined by scanning electronic microscopy and it was found that it exhibited the typical prismatic pattern of the struvite crystals with sizes in the range between 100 and 300 μm. The increase of magnesium concentration in the supersaturated solutions, resulted for all phosphate concentration tested, in significantly higher phosphate removal efficiency. Moreover, it is interesting to note that in this case the adhesion of the suspended struvite crystals to the reactor walls was reduced suggesting changes in the particle characteristics. The increase of phosphate concentration in the supersaturated solutions, for the magnesium concentrations tested resulted to the reduction of struvite suppression which reached complete suppression of the precipitate formation. Excess of ammonium in solution was found favour struvite precipitation. Contrary to the results found with increasing the magnesium concentration in solution, higher ammonium concentrations resulted to higher adhesion of the precipitated crystallites to the reactor walls. The results of the present work showed that it is possible to recover phosphorus in the form of struvite from wastewater reducing water pollution and at the same time saving valuable resources.     

Magnetic and specific heat studies of the frustrated Er2Mn2O7 compound

A new Er2Mn2O7 compound was synthesized by the ceramic method and its crystal structure was characterized using powder X-ray diffraction (XRD) and observed by scanning electron microscopy (SEM). The magnetic properties were investigated using a BS2 magnetometer and the heat capacity was studied using a quantum design (PPMS). The structural study revealed that this compound was monophasic and crystallized in the monoclinic system with the P2/M space group. Magnetization measurements were carried out in the temperature range of 1.8-200 K under an applied magnetic field of 0.05 T. A crossover from a room temperature paramagnetic phase to an antiferromagnetic one at low temperature was detected from the magnetic study. The magnetic susceptibility, in the paramagnetic region above 40 K, was found to present a simple Curie-Weiss type behavior. From the specific heat (CP) measurements in magnetic fields up to 5 T, we noted the presence of a wide peak characteristic of a second order mag-neto-structural transition.     

Genoepidemiology and pathogenicity of hepatitis G virus in Japan

Danish artificial insemination (AI) centres house several boars antibody positive to porcine reproductive and respiratory syndrome virus as well as PRRSV-naive boars which may become acutely infected. The risk of transmission of PRRSV by semen may therefore constitute a serious problem to the Danish pig industry. The use of a vaccination-program may be a way to avoid or reduce the problem. This study evaluates the use of two vaccines: One live, attenuated vaccine and one inactivated vaccine. A pronounced reduction in viremia and shedding of virus in semen was demonstrated by use of the live vaccine compared to the non-vaccinated control animals. In contrast, no changes in onset, level and duration of viremia and shedding of virus in semen were observed using the inactivated vaccine. Neither viremia nor seminal shedding of virus was detected in previously PRRSV-infected, PRRSV-antibody positive boars after challenge with a Danish field strain of PRRSV.     

Imaging of multiple myeloma

Multiple myeloma (MM) is characterized by a proliferation of plasma cells responsible for osteolytic lesions. Imaging studies are performed in MM to establish diagnosis and prognosis, and may also be used to judge the efficacy of treatment and to detect complications. TO ESTABLISH THE DIAGNOSIS: Conventional radiography demonstrates, at the time of diagnosis, characteristic features in 80% of cases. These lytic lesions involve more often the sites of red marrow. More rarely the only abnormal finding is diffuse osteopenia. Tomodensitometry and, above all, magnetic resonance imaging (MRI), which is a reference method for bone marrow disorders, can be useful for diagnosis in some difficult cases. But the lesions observed, hyposignals on spin echo T1 sequences and hyposignals on T2-weighted gradient echo, are not specific and usually do not allow to distinguish MM from osteolytic metastasis or other bone marrow disorders. TO DETERMINE EXTENT OF DISEASE AND TO EVALUATE PROGNOSIS: According to Durie and Salmon, the extension of home lesions at diagnosis is strongly correlated with the myelomatous measured cellular mass and with survival of patients. But this relation is denied by some authors who have noted that the shortest survival was seen in patients with normal X-rays. TO JUDGE THE EFFICACY OF TREATMENT: Improvement of the radiological abnormalities is observed in nearly 30% of patients responding to a conventional chemotherapy and appears to be an adverse pronostic sign. A good correlation between MRI and the biological response to treatment has also been reported. TO RECOGNIZE COMPLICATIONS OF DISEASE: Conventional radiography is also very important in diagnosis of complications like fractures or vertebral compression. Lastly, MRI is the investigation of first choice in the evaluation of patients with suspected spinal cord compression.     

Dynamic graph summarization: a tensor decomposition approach

Due to the scale and complexity of todays’ social networks, it becomes infeasible to mine them with traditional approaches. A possible solution to reduce such scale and complexity is to produce a compact (lossy) version of the network that represents its major properties. This task is known as graph summarization, which is the subject of this research. Our focus is on time-evolving graphs, a more complex scenario where the dynamics of the network also should be taken into account. We address this problem using tensor decomposition, which enables us to capture the multi-way structure of the time-evolving network. This property is unique and is impossible to obtain with other approaches such as matrix factorization. Experimental evaluation on five real world networks implies promising results demonstrating that tensor decomposition is quite useful for summarizing dynamic networks.     

A self-duty-cycled 7.2–8.5 GHz IR-UWB receiver for low power and low data rate applications

A self-duty-cycled non-coherent impulse radio-ultra wideband receiver targeted at low-power and low-data-rate applications is presented. The receiver is implemented in a 130 nm CMOS technology and works in the 7.2–8.5 GHz UWB band, which covers the IEEE 802.15.4a and 802.15.6 mandatories high-band channels. The receiver architecture is based on a non-coherent RF front-end (high gain LNA and pulse detector) followed by a synchronizer block (clock and data recovery or CDR function and window generation block), which enables to shut down the power-hungry LNA between pulses to strongly reduce the receiver power consumption. The main functions of the receiver, i.e. the RF front-end and the CDR block, were measured stand-alone. A maximum gain of 40 dB at 7.2 GHz is measured for the LNA. The RF front-end achieves a very low turn-on time (<1 ns) and an average sensitivity of ?92 dBm for a 10^?3 BER at a 1 Mbps data rate. A root-mean-square (RMS) jitter of 7.9 ns is measured for the CDR for a power consumption of 54 µW. Simulation results of the fully integrated self-duty-cycled 7.2–8.5 GHz IR-UWB receiver (that includes the measured main functions) confirm the expected performances. The synchronizer block consumes only 125 µW and the power consumption of the whole receiver is 1.8 mW for a 3% power duty-cycle (on-window of 30 ns).