Characterization and physical properties of polymethylphenylsilsesquioxane (PMPSQ) and hydroxyl‐functionalized polystyrene (PS–OH) hybrids

Polymethylphenylsilsesquioxane (PMPSQ–OH) and trimethylsilyl end‐blocked PMPSQ (PMPSQ–EC) were prepared. The thermal decomposition behavior of these polymers was studied by thermogravimetric analysis (TGA) and FT‐Raman spectroscopy. Hydroxyl‐functionalized polystyrene (PS–OH) was also prepared by anionic living polymerization. Thin hybrid films of PMPSQ/PS–OH with various blend ratios were obtained by spin‐coating on freshly cleaned glass. The surface morphology of the hybrid films was investigated by atomic force microscopy (AFM). In 80/20 PMPSQ/PS–OH hybrid film, the PS–OH component produced a very uniformly dispersed phase. This hybrid film contained small domains of PS–OH whose size ranged from 60 to 80 nm. As the content of PS–OH was increased, the domain morphology coarsened and phase inversion took place around 50 wt %. In the phase‐inversed system, the PMPSQ‐rich phase was uniformly distributed in the PS–OH‐rich continuous phase. In addition, temperature‐dependent dielectric properties of PMPSQ/PS–OH hybrids were investigated. Relaxation of the hybrids was observed with an increasing content of the PS–OH component due to the amorphous glass transition behavior of PS–OH. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 2801–2812, 2003     

Ozonolysis of cyclododecene

Ozonolysis of cyclododecene was carried out to produce an w-formyl carboxylic acid (12-oxododecanoic acid) which is derived from zwitterion and aldehyde moiety that are formed during the reaction. The ozonolysis was performed to examine the product distribution under such reaction variables as temperature, kinds of solvent, and presence of catalyst. The yield of polymeric ozonide, which is undesirable product, was measured to be dominantly 86% without pyridine catalyst, whereas, only 10.25% with the catalyst. The optimum reaction condition was to be in MC (methylene chloride) solvent, and in the presence of equimolar olefin and pyridine catalyst at O°C, at which the yields of polymeric ozonide, 1,12-dodecanedialdehyde, 1,12-dodecanedicarboxylic acid, and 12-oxo-dodecanoic acid were 10.25%, 26.72%, 26.31%, and 36.72%, respectively.     

Effect of the matrix crystallinity on the percolation threshold and dielectric behavior in percolative composites

Through the use of polyethylenes with different crystallinities as matrices, the effects of the matrix crystallinity on the percolation threshold and dielectric behavior of percolative composites have been investigated. The results suggest that the percolation threshold is negatively related to the matrix crystallinity, whereas the enhancement of the dielectric constant is positively related to the matrix crystallinity. A two‐dimensional diagram is proposed to illustrate such relationships. In addition, it has been found that the insulator–conductor transition is much flatter in low‐crystallinity‐matrix‐based composites, and this may be favorable for preparing threshold composites with a high dielectric constant and a low loss tangent. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Preparation of nanosize Pt clusters using ion exchange of Pt(NH3) 4 2+ inside mesoporous channel of MCM-41

Mesoporous molecular sieve MCM-41 with a Si/Al ratio of 35 was obtained by hydrothermal synthesis using a gel mixture with a molar composition of 6 SiO₂0.1 Al₂O₃1 hexadecyltrimethylammonium chloride 0.25 dodecyltrimethylammonium bromide 0.25 tetrapropylammonium bromide0.15 (NH₄)₂O1.5 Na₂O300 H₂O. The MCM-41 sample was calcined in O₂ flow at 813 K and subsequently ion exchanged with Ca²⁺. A small Pt cluster has been supported on the MCM-41 sample following a procedure using ion exchange of Pt(NH₃) ₄ ²⁺ . The Pt(NH₃) ₄ ²⁺ ion supported on MCM-41 has been activated in O₂ flow at 593 K and subsequently reduced with Fh flow at 573 K, in the same way used for the preparation of a Pt cluster entrapped inside the supercage of zeolite NaY. The resulting Pt cluster supported on the MCM-41 shows hydrogen chemisorption oftotal two H atoms per Pt at 296 K (based on the total amount of Pt) and high catalytic activity for hydrogenolysis of ethane. The chemical shift in¹²⁹Xe NMR spectroscopy of adsorbed xenon indicates that the Pt cluster is located inside the mesoporous molecular sieve.     

利用电阻探针对石油设备及管道的腐蚀进行监测

从1998年起，国内石油炼制行业开始大量炼制进口高硫原油，油气管道的腐蚀问题受到了重视。介绍了电阻探针腐蚀监测系统的原理及组成。并针对油气管道，实施了在线监测，安装了6组腐蚀电阻探针，分析了测量结果，为今后防腐工作提供了依据。     

New phenothiazine-containing monomers and polymers

Summary Three new phenothiazine-containing electrono-donor monomers: methacryloyl-2-hydroxyethyl-2-(N-phenothiazinyl)propionate (i) acryloyl-2-hydroxyethyl-2-(N-phenothiazinyl) propionate (ii) and 2-(N-phenothiazinyl) propionic acid vinyl ester (iii) were synthesized and radically polymerized. The ionization potentials of poly(i), poly(iii) and of the model for the structural unit of the acrylic polymers: acetyl-2-hydroxyethyl-2-(N-phenothiazinyl) propionate determined with two small acceptors were discussed in terms of sterical hindrances.     

关于自适应非线性镇定的某些结果

不确定非线性系统的反馈控制一直是控制科学的中心问题之一,迄今已经取得很大进展。然而,目前现有大部分工作所研究的反馈控制规律,或是连续时间形式的,或是采样反馈形式但需要采样频率充分快,或是离散时间反馈形式,但需要被控离散时间系统的非线性函数增长速度不超过线性。要消除或减弱这些约束条件,一般来讲是相当困难的。这就促使我们探究反馈机制的最大能力和根本局限。尽管近年来在这个方向有许多重要进展,但仍有许多非平凡的重要问题有待研究。例如,在反馈通道中有时滞情形,或者系统状态是高维的情形。在本文中,我们将探索两类比较特殊的离散时间不确定非线性动力系统的控制问题,给出关于全局自适应反馈镇定的某些初步结果。     

多传感器集中式增量卡尔曼滤波融合算法

在单个传感器的状态估计系统中,标准的增量卡尔曼滤波方法可以有效消除量测系统误差。对于多传感器情况,标准算法失效。针对该问题,提出了多传感器集中式增量卡尔曼滤波融合算法,即:增量卡尔曼滤波的扩维融合算法和增量卡尔曼滤波的序贯融合算法。在标准增量卡尔曼滤波算法的基础上,结合扩维融合和序贯融合的思想来实现多传感器数据的融合。实验结果表明,当存在量测系统误差时,提出的集中式融合算法与传统的集中式融合算法相比,提高了滤波精度,并且能够成功地消除量测系统误差。     

基于云端协同计算架构的边缘端I/O密集型虚拟机资源分配方案

大型制造业生产车间业务流程复杂,传统固定资源配置方式将产生负载不均衡的问题。针对此问题,设计并实现了一种基于云端协同架构的边缘端I/O密集型虚拟机资源的分配算法,通过定义计算节点中每个I/O密集型虚拟机三个维度的信息计算得出I/O密集型虚拟机的优先级,并按最大优先级队列实时统一分配硬件资源。实验结果表明,该算法在应对工业机械设备高响应和高通量的要求上有较为明显的提升,为实际生产起到了优化资源配置的作用。     

A visual study on flame behavior in tone-excited non-premixed jet flames

A visualization study on the effect of forcing amplitude in tone-excited jet diffusion flames has been conducted. Visualization techniques are employed using optical schemes, which are a light scattering photography. Flame stability curve is attained according to Reynolds number and forcing amplitude at a fuel tube resonant frequency. Flame behavior is globally grouped into two from attached flame to blown-out flame according to forcing amplitude; one sticks the tradition flame behavior which has been observed in general jet diffusion flames and the other shows a variety of flame modes such as the flame of a feeble forcing amplitude where traditionally well-organized vortex motion evolves, a fat flame, an elongated flame, and an in-burning flame. Particular attention is focused on an elongation flame, which is associated with a turnabout phenomenon of vortex motion, and on a reversal of the direction of vortex roll-up. It is found that the flame length with forcing amplitude is the direct outcome of the evolution process of the formed inner flow structure. Especially the negative part of the acoustic cycle under the influence of a strong positive pressure gradient causes the shapes of the fuel stem and fuel branch part and even the direction of vortex roll-up to dramatically change.