Pollution Buildup on Road Surfaces

Samples of sediment found on an urban road in Aberdeen (Scotland) were collected by washing designated surfaces. This method, called the “wet” method, was capable of collecting sediment of the smallest particle size range that is normally left behind by traditional sampling techniques using dry vacuuming. Over 17 months (mainly on a weekly basis), 66 samples were collected and analyzed for sediment loading, particle size distribution, concentration of heavy metals (Zn, Cu, Pb, Cd) in four sediment size fractions, and several dissolved pollutants in the effluent collected from washing (NO3?,?SO42?,?PO43?,?Cl?,?F?,?NH4+, total organic carbon, total carbon). Standard statistical methods, including multiple regressions, were used to determine relationships amongst different sediment characteristics. It was found that sediment loading, as well as concentrations of Cl? and SO42?, were highest in the winter months, especially when snow was present on the road surface. It was observed that 66% of total road sediment loading was found within a 0.5 m strip next to the curb. The average sediment particle sizes found were smaller than those previously recorded in the literature. As expected, the concentrations of heavy metals were highest in the smallest particle size fraction analyzed (<63?μm), and this occurred during the summer months when less sediment was available on the street surface. The antecedent dry weather period had a very weak and negative influence on the loading rate of the smallest particle size fraction next to the curb.     

Influence diagnostics in regression with complex designs through conditional bias

One of the areas of Statistics in which the influence analysis has been widely studied is the multiple linear regression model. Nevertheless, the influence diagnostics proposed in this context cannot be applied to regression in complex survey, under randomized inference, since the i.i.d. case does not incorporate any probability weighting or population structure, such as clustering, stratification or measures of size into the analysis. In this paper we introduce some influence diagnostics in regression in complex survey. They are built on the conditional bias concept (Moreno-Rebollo et al., 1999). We emphasize the similarities and differences of the proposed measures with respect to the existing ones for the i.i.d. case. Research partly supported by the Spanish MCYT grant BFM2001-3844 and Spanish MEC grant MTM2004-0111433.     

Probabilistic Approach to Predict Cracking in Lightly Reinforced Microconcrete Panels

The ultimate strength of structures made of brittle materials—such as microconcrete—strongly depends on microstructural defects, the structure size, and the loading pattern. Probabilistic approaches allow one to take account of such dependencies. By using a Weibull model, cracking of ferrocement panels is analyzed. Provided the behavior of the reinforcement remains elastic, it is shown that the Weibull parameters identified on unreinforced microconcrete samples tested in flexure may be used to predict multiple cracking in ferrocement panels tested in tension. A key aspect of the analysis is related to the understanding and modeling of the stress heterogeneity effect on the local failure probability of unreinforced as well as reinforced microconcrete by the use of a so-called Weibull stress.     

Use of Repetitive Sequences for Molecular and Cytogenetic Characterization of Avena Species from Portugal

Genomic diversity of Portuguese accessions of Avena species—diploid A. strigosa and hexaploids A. sativa and A. sterilis—was evaluated through molecular and cytological analysis of 45S rDNA, and other repetitive sequences previously studied in cereal species—rye subtelomeric sequence (pSc200) and cereal centromeric sequence (CCS1). Additionally, retrotransposons and microsatellites targeting methodologies—IRAP (inter-retrotransposon amplified polymorphism) and REMAP (retrotransposon-microsatellite amplified polymorphism)—were performed. A very high homology was detected for ribosomal internal transcribed sequences (ITS1 and ITS2) between the species analyzed, although nucleolar organizing regions (NOR) fluorescent in situ hybridization (FISH) analysis revealed distinct number of Nor loci between diploid and hexaploid species. Moreover, morphological diversity, evidenced by FISH signals with different sizes, was observed between distinct accessions within each species. pSc200 sequences were for the first time isolated from Avena species but proven to be highly similar in all genotypes analyzed. The use of primers designed for CCS1 unraveled a sequence homologous to the Ty3/gypsy retrotransposon Cereba, that was mapped to centromeric regions of diploid and hexaploid species, being however restricted to the more related A and D haplomes. Retrotransposon-based methodologies disclosed species- and accessions-specific bands essential for the accurate discrimination of all genotypes studied. Centromeric, IRAP and REMAP profiles therefore allowed accurate assessment of inter and intraspecific variability, demonstrating the potential of these molecular markers on future oat breeding programs.     

Extraction of high added value biological compounds from sardine,sardine-type fish and mackerel canning residues — A review

Different valuable compounds, which can be employed in medicine or in other industries (i.e. food, agrochemical, pharmaceutical) can be recovered from by-products and waste from the fish canning industries. They include lipids, proteins, bio-polymers, minerals, amino acids and enzymes; they can be extracted from wastewaters and/or from solid residues (head, viscera, skin, tails and flesh) generated along the canning process, through the filleting, cooking, salting or smoking stages.In this review, the opportunities for the extraction and the valorisation of bioactive compounds from sardine, sardine-type fish and mackerel canning residues are examined and discussed. These are amongst the most consumed fishes in the Mediterranean area; moreover, canning is one of the most important and common methods of preservation. The large quantities of by-products generated have great potentials for the extraction of biologically desirable high added value compounds.     

Usability evaluation methods for mobile serious games applied to health: a systematic review

Universal Access in the Information Society - This paper aims to present the results of a systematic review focused on usability evaluation methods for serious games (SG) of mobile devices...     

Incorporation of polyfluorenes into poly(lactic acid) films for sensor and optoelectronics applications

Films of neat and plasticized biodegradable poly(lactic acid) (PLA) matrices containing anionic conjugated polyelectrolytes, poly[9,9‐bis(4‐phenoxybutylsulfonate)]fluorene‐2,7‐diyl‐alt‐arylenes, with 1,4‐phenylene and 4,4″‐p‐terphenylene, respectively, as arylene groups or a neutral poly(9,9‐dialkylfluorene) for comparison were prepared by solution casting. These films were characterized using differential scanning calorimetry, thermogravimetry, scanning electron microscopy and fluorescence spectroscopy. In addition, the effects of plasticizer on the thermal properties and the oxygen permeability of the PLA films were measured through the oxygen transmission rate. Results show that it is possible to obtain thin, optically transparent and luminescent films with potential in oxygen sensing, exhibiting good thermal and photochemical stability. At high polyelectrolyte content, evidence is found for phase separation and aggregate formation and it is no longer possible to obtain completely homogeneous films. The possibility of incorporating the cationic metal complex tris(2,2′‐bipyridyl)ruthenium(II) into plasticized PLA films containing conjugated polyelectrolytes for dual‐wavelength ratiometric luminescence sensing is also discussed. Copyright © 2012 Society of Chemical Industry     

Web-GIS models: accomplishing modularity with aspects

Spatial concerns of Web geographical information systems (Web-GIS) are inherently crosscutting and volatile: crosscutting because they affect multiple functionalities of Web-GIS systems, and volatile because their status may change often. If these concerns are not modularized properly, the quality of Web-GIS services, particularly with regard to adaptation and evolution, can be severely compromised. This paper uses aspect-orientation to model crosscutting and volatile spatial concerns. By modeling both types of concerns, crosscutting and volatile, as candidate aspects, one can use dynamic weaving to add or remove them from a system at runtime. The aspect-oriented approach proposed starts with the identification and specification of crosscutting concerns and follows by composing these using modeling aspects using a transformation approach, an aspect-oriented modeling technique. The conflicts that can emerge due to the composition order are also taken into consideration. Finally, this paper proposes a set of reusable GIS crosscutting concerns, documenting them in a concern catalogue.     

Mathematical modelling of adult hippocampal neurogenesis: effects of altered stem cell dynamics on cell counts and bromodeoxyuridine-labelled cells

In the adult hippocampus, neurogenesis—the process of generating mature granule cells from adult neural stem cells—occurs throughout the entire lifetime. In order to investigate the involved regulatory mechanisms, knockout (KO) experiments, which modify the dynamic behaviour of this process, were conducted in the past. Evaluating these KOs is a non-trivial task owing to the complicated nature of the hippocampal neurogenic niche. In this study, we model neurogenesis as a multicompartmental system of ordinary differential equations based on experimental data. To analyse the results of KO experiments, we investigate how changes of cell properties, reflected by model parameters, influence the dynamics of cell counts and of the experimentally observed counts of cells labelled by the cell division marker bromodeoxyuridine (BrdU). We find that changing cell proliferation rates or the fraction of self-renewal, reflecting the balance between symmetric and asymmetric cell divisions, may result in multiple time phases in the response of the system, such as an initial increase in cell counts followed by a decrease. Furthermore, these phases may be qualitatively different in cells at different differentiation stages and even between mitotically labelled cells and all cells existing in the system.