Ecosystem Service Impacts of Urban Water Supply and Demand Management

Utilities face the challenge of enhancing long-term water security while minimising undesirable economic, social and environmental impacts of supply and demand management options. This paper provides an example of how the ecosystem services concept can be used to enumerate and organise broad impacts of water supply options. A case study of Adelaide, South Australia, is used to examine costs and benefits associated with different sources of water and source-water mix scenarios. Ecosystem service impacts are estimated using estimates from the literature. Seven water supply and demand management options are considered for Adelaide: 1) the River Murray, 2) Mt. Lofty Ranges catchments, 3) wastewater reuse, 4) desalination, 5) stormwater harvesting, 6) groundwater and 7) water conservation. The largest costs are associated with sourcing water from conservation measures such as water restrictions on outdoor watering estimated at $1.87/kL. Salinity damage costs associated with residential uses are estimated at up to $1.54/kL. Salinity damage costs of wastewater reuse were estimated at $1.16/kL. The largest benefit is coastal amenity services associated with stormwater harvesting and treatment estimated at $1.03/kL. Results show that there is a trade-off between financial costs and ecosystem services impacts with source-water mix scenarios with the highest ecosystem services cost having the lowest financial O&M cost and vice versa. This highlights the importance of taking ecosystem services into account when evaluating water supply options.     

<Superscript>1</Superscript>H NMR characterization of milk lipids: A comparison between cow and buffalo milk

Characterization of the lipid fraction of raw cow and buffalo milk samples, collected in different breeding areas in Apulia, a region of southern Italy, were performed by means of ¹H NMR. The aim of this work was to establish whether FA composition data obtained by ¹H NMR can be used in the differentiation of buffalo and cow milk samples according to species. A complete assignment of the signals present in the spectrum was attempted by COSY, heteronuclear coherence spectra. Quantification of FA was carried out by inserting the integrals of particular peaks in suitable calculations. Multivariate statistical analysis, conducted on the results of the quantification, permitted buffalo and cow milks to be distinguished.     

Alumina-, niobia-, and niobia/alumina-supported NiMoS catalysts: Surface properties and activities in the hydrodesulfurization of thiophene and hydrodenitrogenation of 2,6-dimethylaniline

The activity of NiMoS catalysts supported on niobia, alumina, and niobia/alumina was compared for the thiophene hydrodesulfurization (HDS) and 2,6-dimethylaniline (2,6-DMA) hydrodenitrogenation (HDN) reactions. To evaluate the acidity of the supports and identify the nature of the sulfide sites, adsorption of 2,6-dimethylpyridine, pyridine, and CO was performed and followed by IR spectroscopy. This study has shown that with niobia as a support, the activity of NiMoS catalysts in thiophene HDS and in HDN of 2,6-DMA was no longer promoted by the synergy between Ni and Mo. The absence of synergy between molybdenum and nickel on niobia can be explained by the strong interaction of each metal with niobia at the expense of interaction with each other. Moreover, it has been shown that on a niobia/alumina support, the formation of the NiMoS phase can be directly linked to the presence of alumina not covered by niobia. However, niobia is an interesting support for the HDN of 2,6-DMA, because it favors the formation of xylene through direct ammonia elimination involving low H₂ consumption. The activity for xylene formation on niobia is linked to the electron-deficient nature of the Mo sulfide site, as demonstrated by CO adsorption followed by IR.     

Flavonoid pigments in chalkhill blue (Lysandra coridon Poda) and other lycaenid butterflies

Nine flavonoids, namely, kaempferol, kaempferol 7-rharanoside, kaempferol 3-rhamnoside, kaempferol 3-glucoside, kaempferol 3-glucoside, 7-rhamnoside, quercetin 3-glucoside, quercetin 3,7-diglucoside, isorhamnetin 3-glucoside, and isorhamnetin 3,7-diglucoside, have been identified in the body and wings of the chalkhill blue butterflyLysandra coridon Poda. Flavonoids have also been found in 15 of a further 17 lycaenid species examined. Analysis of the two-dimensional paper chromatographic flavonoid patterns and aglycone results has shown that the flavonoid content ofL. coridon and the other lycaenids is dependent on the flavonoid content of the larval diet. Differences in the flavonoid patterns ofL. coridon and its leguminous larval food plantsHippocrepis comosa, Anthyllis vulneraria, andLotus corniculatus, indicate that the ingested flavonoids are metabolized byL. coridon or its gut flora before sequestration. Despite the presence of fiavones, glycoflavones, and isoflavones in the larval food plant species, only flavonols are sequestered by the lycaenid species examined. The relationship between lycaenid butterflies and their larval food plants, and the possible role(s) of flavonoids in lycaenids has been discussed. Interactions between ants, plants, flavonoids, and myrmecophilous lycaenids have also been considered.     

Influence of dietary long-chain PUFA on premature baboon lung FA and dipalmitoyl PC composition

One of the major survival challenges of premature birth is production of lung surfactant. The lipid component of surfactant, dipalmitoyl PC (DPPC), increases in concentration in the period before normal term birth via a net shift in FA composition away from unsaturates. We investigated the influence of dietary DHA and arachidonic acid (AA) on lung FA composition and DPPC concentration in term and preterm baboons. Pregnant animals/neonates were randomized to one of four groups: breast-fed (B), term formula-fed (T⁻), preterm formulafed (P⁻), and preterm fed formula supplemented with DHA-AA (P⁺). Breast milk contained 0.68%wt DHA and the P⁺ group formula contained 0.61%wt DHA. In the preterm groups (P⁻ and P⁺), pregnant females received a course of antenatal corticosteroids. At the adjusted age of 4 wk, neonate lung tissue was harvested, and FA composition and DPPC were analyzed. Palmitate was ∼28%wt of lung total FA and no significant differences were found among the four treatment groups. In contrast, DPPC in the B group lung tissue was significantly greater than DPPC in the unsupplemented groups, but not compared with the P⁺ group. The B and P⁺ groups were not significantly different in DHA and AA, but were different compared with the unsupplemented (T, P⁻) groups. These results indicate that LCP supplementation increases lung DHA and AA, without compromising overall lung 16∶0 or DPPC. The shift in FA composition toward greater unsaturation in the groups consuming LCP supported improved surfactant lipid concentration in preterm neonate lungs.     

Aggregation pheromone characterization and comparison inDrosophila ananassae andDrosophila bipectinata

(Z)-11-Octadecenyl acetate (Z11–18Ac) and (Z)-11-eicosenyl acetate (Z11–20Ac) were identified as the aggregation pheromones ofDrosophila ananassae, andZ11–20Ac was identified as the aggregation pheromone ofDrosophila bipectinata. Z11–18Ac andZ11–20Ac were not attractive alone; however, in combination with fermenting food odors, the acetates attracted flies of both sexes in a wind-tunnel olfactometer. The pheromones were present in the ejaculatory bulb of sexually mature male flies and transferred to the female during mating. MaleD. bipectinata released little if anyZ11–20Ac to the food; however, recently mated females releasedZ11–20Ac to the surrounding surfaces in just a few hours after mating.D. ananassae males, on the other hand, appeared to release moreZ11–18Ac andZ11–20Ac to the surroundings than mated females. AlthoughD. bipectinata males had noZ11–18Ac, flies were as attracted toZ11–18Ac as to an equal quantity ofZ11–20Ac.D. ananassae were attracted toZ11–18Ac but not toZ11–16Ac orZ11–20Ac. However,Z11–20Ac in combination withZ11–18Ac was significantly more attractive thanZ11–18Ac alone.     

How to maneuver in the world of negative online reviews,the important ethical considerations for attorneys,and changes needed to protect the legal profession

The advent of the Internet and social media has revolutionized the way society communicates, the speed in which news is disseminated, and the approach that people take in their daily decision-making. Online reviews are now common place on nearly every consumer-related website. Consequently, attorneys are also being publicly scrutinized by their clients on a range of topics from price, competence, satisfaction, personality, communication, and effectiveness. On one side of the coin, this new phenomenon can be very rewarding since attorneys were previously limited to receiving a small number of referrals from the word-of-mouth promotion before the creation of online reviews. However, the exact opposite is true. Negative online reviews, whether accurate or not, may deter potential clients from even giving the attorney a second thought. As a result, a firm's business can feel the immediate impact of negative reviews. Attorneys, who legitimately need and want to protect their business and reputation, cannot speak freely online to defend their honor. Rather, an attorney must be mindful of not disclosing confidential client information or crossing other ethical lines that may then expose the attorney to potential discipline. There are several interests that must be considered such as allowing attorneys to exercise their First Amendment right to free speech, respect and adherence to the ethical rules of non-disclosure of confidential information, allowing attorneys to preserve their reputation, and protecting an attorney's marketability and means of generating income. This article explores the trend in offering reviews online in a variety of industries, including legal services, the statistical findings regarding the prevalence of this information and consumers' reliance on the information while making a purchasing decision. This article also considers the positive and negative implications of the reviews being so widely spread, while highlighting unique considerations as it relates to the practice of law and factors that may greatly skew a reviewer and reader's perceptions. Next, this article outlines the ethical considerations of attorneys if they want to respond to negative online feedback, such as disclosure of confidential information. Then, this article analyzes the American Bar Association (ABA) and several US states' ethics opinions for guidance for attorneys who wish to respond negative reviews. Finally, this article details the author's recommendations for attorneys, the ABA, and the US states and propose the areas where additional ethics opinions, rules and guidelines should be focused to establish a proper balance between the valuable insights discovered from a client's review and attorneys' legitimate interests in protecting their reputation and livelihood from inaccurate, malicious, or erroneous postings.     

Computational auditory models in predicting noise reduction performance for wideband telephony applications

The performance of several noise reduction algorithms intended for wideband telephony was evaluated both subjectively and objectively. The chosen algorithms were based on statistical modeling, spectral subtraction, Wiener filtering, or subspace modelling principles. A customized wideband noise reduction database containing speech samples corrupted by three types of background noises at three SNR levels, along with their enhanced versions was created. The overall quality of the speech samples in the database was subsequently rated by a group of listeners with normal hearing capabilities. Comprehensive statistical analyses were performed to assess the reliability of the subjective data, and to assess the performance of noise reduction algorithms across varied noisy conditions. The subjective quality ratings were then used to investigate the performance of several auditory model-based objective quality metrics. Key results from these investigations include: (a) there was a high degree of inter- and intra-subject reliability in the subjective ratings, (b) noise reduction algorithms enhance speech quality for only a subset of the noise conditions, and (c) auditory model-based metrics perform similarly in predicting speech quality ratings, when speech quality scores pertaining to a particular noise condition were averaged.     

B?ckerei-technologische Qualit?t von Winterweizen in Abh?ngigkeit vom Reifestadium des Kornes

Zusammenfassung Kornpartien verschiedener Winterweizensorten wurden in verschiedenen Reifestadien auf ihre Theologischen Eigenschaften und ihre Backqualität untersucht. Die Rohproteingehalte sind zu Beginn bzw. in der Mitte der Milchreife des Kornes sehr hoch, gehen dann aber deutlich zurück. Auch die Sedimentationswerte liegen in früheren Reifestadien höher als in der Vollreife. In den frühen Reifestadien liegen auch die relativen Sedimentationswerte (=Sed.-Wert: Rohproteingehalt des Kornes) am höchsten. Der Aschegehalt der Körner sinkt, die Mehlausbeute an Type 550 steigt mit fortschreitender Kornentwicklung und größeren Tausendkorngewichten.-Die im Farinographen und Extensographen ermittelten Teigeigenschaften der Mehle des unreifen und reifen Kornes unterscheiden sich meist deutlich; Art und Ausmaß dieser Veränderungen sind sortenabhängig.-Die bei vier Sorten in verschiedenen Reifestadien durchgeführten Backversuche lassen sowohl bei der Teigbeschaffenheit als auch bei den Gebäckeigenschaften deutliche, z. T. sortenspezifische Veränderungen in Abhängigkeit vom Reifestadium des Kornes erkennen. Spätestens ab der Teigreife weisen die geprüften Winterweizensorten dem reifen Korn vergleichbare Gebäckeigenschaften auf.

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Rheological properties and baking quality of winter wheat in dependence on the stage of grain maturity

Grains of several wheat varieties in different stages of maturity were investigated for rheological properties and baking quality. Crude protein content was found to be very high at the beginning and in the middle of milk ripeness of the grain; later crude protein decreases strongly. Sedimentation values and relative sedimentation values (sed.-val.: protein content of the grain) are higher in the earlier stages of grain development, too. Mineral content of the grain decreases, flour yield (type 550) increases with processing grain development and increasing thousand kernel weights.-The dough properties (farinograph and extensiograph) of the flours of the unripe and the full ripe grains mostly differed markedly; type and extent of this changes are in dépendance on the genotype. For instance genotype Monopol with a genetical caused excellent baking quality has the best rheological properties in the flour of the full ripe grain. On the other hand the genotypes in the flour of the full ripe grain. On the other hand the genotypes Benno and Clement with genetical caused adhesive doughs and poorer baking quality develop their very negative rheological properties primarily in the later stages of ripeness.-Baking tests with four other cultivars demonstrate genotypical differences in sensory determined dough properties and in bread quality in dependence on stage of grain maturity. These four genotypes show comparable baking results for flours from grains in the wax-ripe stage and in the full ripeness.