印尼褐煤无黏结剂型煤自燃与燃烧特性研究

在内辊式高压型煤机上将一种印度尼西亚褐煤压制成高强度的无黏结剂型煤,对其比表面积、孔容积和表面官能团进行分析,测定了型煤的相对着火温度和绝热氧化升温速率,研究了其热解和燃烧行为特性.结果表明,印尼褐煤在干燥和高压成型过程中,发生了孔的收缩和崩塌,特别是微孔收缩程度要更大一些;干燥和成型过程中有羟基、羰基和羧基含氧官能团的分解;经过提质处理后,褐煤的自燃着火倾向降低,热解和燃烧反应性降低.     

In situ emulsion polymerization and characterization of PVAc nanocomposites including colloidal silica nanoparticles for wood specimens bonding

Polyvinyl acetate (PVAc) nanocomposites for wood adhesives containing different amounts of colloidal silica nanoparticles (CSNs) were synthesized via in situ one-step emulsion polymerization. The adhesion strength of wood specimens bonded by PVAc nanocomposites was investigated by the tensile test. Thermal properties of PVAc nanocomposites were also characterized by differential scanning calorimetry and thermogravimetric analysis. Rheological and morphological properties of the PVAc nanocomposites were investigated using rheometric mechanical spectrometry and field emission scanning electron microscopy (FESEM), respectively. The obtaining results showed that the shear strength of PVAc nanocomposite including 1 wt. % CSNs has the highest shear and tensile strength about 4.7 and 3.2 MPa, respectively. A small increment of T_g (~3 °C) and considerable increment of the ash content proved the enhancement of PVAc thermal characterization in the presence of CSNs. FESEM results showed uniform dispersion of nanoparticles throughout the PVAc matrix due to using the in situ emulsion polymerization process. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48570.     

Thermodynamic Phase Diagram,Half-Metallic and Optical Properties of the Zr2TiSi [111] Films Based on DFT

Silicon - Thermodynamic stability, electronic and optical properties of the Zr2TiSi compound in the bulk and its [111] films have been investigated, based on the density functional theory (DFT)...     

Synthesis of sulfides via reaction of aryl/alkyl halides with S8 as a sulfur-transfer reagent catalyzed by Fe3O4-magnetic-nanoparticles-supported L-Histidine-Ni(II)

One-pot synthesis of symmetrical diaryl/alkyl sulfides in high yields from the reaction between aryl/alkyl halides and S₈ can be carried out in a short period, using Fe₃O₄@SiO₂@His@Ni(II) as a reusable catalyst. The present approach offers the advantages of a clean reaction, simple methodology and high efficiency, and avoids the use of a toxic catalyst.     

Absorption Enhancement in Ultrathin Structures Based on Crystalline-Si/Ag Parabola Nanocones Periodic Arrays with Broadband Antireflection Property

In this study, we examine the optical properties and unique features of a novel design of a parabola nanocone consisting of a homogenous shell-like cover layer of crystalline silicon (c-Si) and an Ag core which provides an enhanced absorption efficiency and significant photocurrent conversion during exposure to an incident light. Determining the geometrical sizes of the c-Si/Ag parabola nanocone, we designed an antireflection nanostructure based on certain arrays of investigated cone arrays on a GaAs substrate. We proved that the examined nanostructure shows a low percentage of reflectance of 6.24 % and a significant short current density of ~37.2 mA/m ² as well as broadband antireflection facility. This understanding paves the way for novel methods toward the use of a simple and two layer nanoparticle in designing efficient and high performance antireflection layers of photovoltaics and solar cells that are able to function over a wide range of spectrum.     

Catalytic olefin polymerisation at short times: Studies using specially adapted reactors

Despite the fact that the very early stages (several tens of seconds) of catalysed olefin polymerisation processes appear negligibly short with respect to the residence time of most industrial reactors, they are critical in terms of catalyst activation, obtaining good particle morphology, and avoiding irreparable problems caused by particle overheating. The different types of reactors that have been used over the course of the past few years are discussed in this feature article. It is shown that despite the difficulties encountered in finding the perfect experimental tool for this purpose, different configurations of stopped flow reactors can be used successfully to explore different aspects of what happens to the catalyst (supported and molecular) during these critical moments of polymerisation. © 2012 Canadian Society for Chemical Engineering