Preparation and properties of novel polyurethane insulating coatings based on glycerin‐terminated urethane prepolymers and blocked isocyanate

Novel polyurethane insulating coatings were prepared from the reaction of glycerin‐terminated polyurethane prepolymers (GPUPs) and a blocked isocyanate curing agent (BIC). The GPUPs were prepared from the reaction of one equivalent of polycaprolactone polyol (CAPA 210) with an excess amount of 4,4′‐methylene bis(phenyl isocyanate) (MDI) and subsequent reaction of the NCO‐terminated polyurethane with glycerin. The BIC was prepared from the reaction of trimethylol propane (TMP), toluene diisocyanate (TDI) and N‐methylaniline (NMA). The polyols and curing agent were characterized by conventional methods while the curing condition was optimized via gel content measurements. The curing kinetics of the polyurethane coating were investigated and the kinetic parameters derived. The crosslink densities of the samples were determined via the equilibrium swelling method, using the Flory–Rehner equation. The relationships between the crosslink density and the electrical, physical, mechanical and dynamic mechanical properties of the coatings were also studied. Copyright © 2005 Society of Chemical Industry     

逆向反射镜光度测量

为了正确评价逆向反射镜的加工质量与使用效果，且将二者有机地统一起来，本文提出应根据测试目的来选择合适的光度测量方法，并进一步分析了不同测试目的将导致测量装置的组成、几何条件（距离，孔径角，工作姿态等）、光度条件（光源色温、稳定性与均匀性，接收器线性、灵敏度与光谱修正等）、测量参数（反光强度系数、逆反射系数、逆亮度系数等）等各不相同。     

Mixed formulation of nonlinear beam on foundation elements

This paper presents an inelastic element for the analysis of beams on foundations. The element is derived from a two-field mixed formulation with independent approximation of forces and displacements. The state determination algorithm for the implementation of the element in a general purpose nonlinear finite element analysis program is presented and its stability characteristics are discussed. Numerical studies are performed to compare the model with the classical displacement formulation. The studies confirm the superiority of the proposed model in describing the inelastic behavior of beams on foundations.     

Survival of rotavirus SA-11 on vegetables

Survival of rotavirus on lettuce, radishes, and carrots was studied to evaluate the potential of rotavirus transmission by vegetables irrigated with wastewater. The vegetables were contaminated with rotavirus SA-11 and stored at 4°C and room temperature in covered and uncovered containers to simulate post harvest conditions. Virus decay rates were greater on radishes and carrots than lettuce. Decay rates of rotavirus on lettuce, radish, and carrot ranged from ?0·057 to ?0·479 (log₁₀ pfu/day). Rotavirus SA-11 survived on lettuce, radish, and carrot for 25 to 30 days at 4°C but at room temperature survival was very different for the various vegetables varying from 5 to 25 days. Greatest survival was always observed on the lettuce. These data suggest that rotaviruses can survive long enough on contaminated vegetables as to be transmitted by this vehicle.     

Pad effects on material-removal rate in chemical-mechanical planarization

The role of a porous pad in controlling material-removal rate (MRR) during the chemical-mechanical planarization (CMP) process has been studied numerically. The numerical results are used to develop a phenomenological model that correlates the forces on each individual abrasive particle to the applied nominal pressure. The model provides a physical explanation for the experimentally observed domains of pressure-dependent MRR, where the pad deformation controls the load sharing between active-abrasive particles and direct pad-wafer contact. The predicted correlations between MRR and slurry characteristics, i.e., particle size and concentration, are in agreement with experimentally measured trends reported by Ouma¹ and Izumitani.²     

A novel interference suppression scheme for global navigation satellite systems using antenna array

This paper considers interference suppression and multipath mitigation in Global Navigation Satellite Systems (GNSSs). In particular, a self-coherence anti-jamming scheme is introduced which relies on the unique structure of the coarse/acquisition (C/A) code of the satellite signals. Because of the repetition of the C/A-code within each navigation symbol, the satellite signals exhibit strong self-coherence between chip-rate samples separated by integer multiples of the spreading gain. The proposed scheme utilizes this inherent self-coherence property to excise interferers that have different temporal structures from that of the satellite signals. Using a multiantenna navigation receiver, the proposed approach obtains the optimal set of beamforming coefficients by maximizing the cross correlation between the output signal and a reference signal, which is generated from the received data. It is demonstrated that the proposed scheme can provide high gains toward all satellites in the field of view, while suppressing strong interferers. By imposing constraints on the beamformer, the proposed method is also capable of mitigating multipath that enters the receiver from or near the horizon. No knowledge of either the transmitted navigation symbols or the satellite positions is required.     

A study of neutron and gamma radiation effects on transmission of various types of glasses, optical coatings, cemented optics and fiber

A study of radiation effects on various types of glasses, dielectric optical coatings, cemented optics and fiber was undertaken with a view to select them for extreme radiation environments. Samples were exposed to different radiation doses in the Pakistan Research Reactor-I (PARR-I) for neutron and Cobalt 60 source for gamma irradiation. Transmissions were measured before and after irradiation. The dielectric coatings were subjected to additional tests (adhesion, abrasion and humidity, etc.) as per MIL-M-13508C and MIL-C-675C. All 15 glasses studied showed varying amounts of transmission loss as expected, with negligible degradation for three types. Recovery of transmissions with time/ageing was also studied, with more or less complete recovery with temperature annealing. A faster bleaching of darkened/brown glasses was achieved by using UV lamps or UV laser. The dielectric coatings (HR, AR) and one of the two commercial optical cements showed excellent resistance to neutrons and gamma radiations, and could be good candidates for the fabrication and utilization of optical components in extreme radiation environments. The data allowed several Chinese glasses to be studied for the first time.     

KINEMATIC VISCOSITY-TEMPERATURE BEHAVIOR OF HEAVY TBP-FRACTIONS (455°C+) OF ARABIAN CRUDE OILS

A generalized kinematic viscosity-temperature correlation for undefined liquid heavy petroleum fractions has been developed to represent the data for a wide range of temperature from 100°C to 200°C. The correlation is based on the experimental kinematic viscosity data of true boiling point fractions of four Arabian crude oils. The characterization property required for estimation is 50% boiling point. The proposed correlation fits the experimental data with an overall absolute error of 6.1%. Experimental measurements of kinematic viscosity of heavy true boiling point fractions of Arabian crude oils were also obtained in order to develop the proposed correlation.     

An extended minimax disparity to determine the OWA operator weights

This paper contributes to extend the minimax disparity to determine the ordered weighted averaging (OWA) model based on linear programming. It introduces the minimax disparity approach between any distinct pairs of the weights and uses the duality of linear programming to prove the feasibility of the extended OWA operator weights model. The paper finishes with an open problem.