乙苯/乙烯烷基化反应中EA-8402分子筛催化剂的失活动力学研究

用内循环无梯度反应器,在593～633K范围内考察了在乙苯/乙烯进行定向烷基化反应合成对二乙苯时,EA-8402分子筛催化剂的失活行为,建立了相应的失活动力学模型: -da/dt=0.3271exp(-12.94/T)P_(EB)~(0.02)P_(E(?))~(0.383)·α这一模型可作为该反应的宏观动力学模型的补充。由失活级数d=1,按Levenspiel判据推断:其失活机理应该是不受内扩散阻力控制的平行-连串失活。     

基于Nutch与元搜索引擎技术的高校网络舆情监测系统研究

针对高校网络舆情监测工作的不足,结合高校舆情信息的传播特点,提出了在校园网范围内基于Nutch搜索引擎技术进行信息检索,在互联网上采用元搜索引擎技术获取相关信息的舆情监测系统构建方案。采用关键词特征库匹配方式自动进行网络舆情监测,及时准确地发现网络舆情信息;探讨了高校对于网络舆情的监测、分析、引导和反馈等环节的处理方法,从而形成完善的应对机制。     

Investigation and improvement of reversible microfluidic devices based on glass–PDMS–glass sandwich configuration

Reversibly assembled microfluidic devices are dismountable and reusable, which is useful for a number of applications such as micro- and nano-device fabrication, surface functionalization, complex cell patterning, and other biological analysis by means of spatial–temporal pattern. However, reversible microfluidic devices fabricated with current standard procedures can only be used for low-pressure applications. Assembling technology based on glass–PDMS–glass sandwich configuration provides an alternative sealing method for reversible microfluidic devices, which can drastically increase the sealing strength of reversibly adhered devices. The improvement mechanism of sealing properties of microfluidic devices based on the sandwich technique has not been fully characterized, hindering further improvement and broad use of this technique. Here, we characterize, for the first time, the effect of various parameters on the sealing strength of reversible PDMS/glass hybrid microfluidic devices, including contact area, PDMS thickness, assembling mode, and external force. To further improve the reversible sealing of glass–PDMS–glass microfluidic devices, we propose a new scheme which exploits mechanical clamping elements to reinforce the sealing strength of glass–PDMS–glass sandwich structures. Using our scheme, the glass–PDMS–glass microchips can survive a pressure up to 400 kPa, which is comparable to the irreversibly bonded PDMS microdevices. We believe that this bonding method may find use in lab-on-a-chip devices, particularly in active high-pressure-driven microfluidic devices.     

MLS4531立式辊磨的开发与研制

在研究国内外立式辊磨的基础上开发出MLS4531立式辊磨,结合工程实际优化了技术参数、研磨机构及其附属装置。在调试中对MLS4531立式辊磨的液压系统,安全装置进行了改进。     

宽带直流放大器的增益控制设计与研究

首先进行了方案论证与比较,分析各种方案的优点缺点,最后选择亚德诺半导体公司生产的低噪声增益可控集成运算放大器AD603和电流反馈型宽带运算放大器AD811等器件设计宽带直流放大器。输入级采用两级AD603级联,输出级设计通频带0~10MHz的带宽,通过单片机可以对放大器增益进行控制。该放大器具有频带宽、功率高、增益可调、带宽可选择等特点。此外,对提高直流放大器的各种性能指标提出了多种具体措施,在要求较高的系统中具有较强的实用性。     

Supervised discrete hashing through similarity learning

Multimedia Tools and Applications - Supervised hashing has achieved better accuracy than unsupervised hashing in many practical applications owing to its use of semantic label information. However,...     

Person re-identification based on multi-appearance model

Person re-identification plays important roles in many practical applications. Due to various human poses, complex backgrounds and similarity of person clothes, person re-identification is still a challenging task. In this paper, we mainly focus on the robust and discriminative appearance feature representation and proposed a novel multi-appearance method for person re-identification. First, we proposed a deep feature fusion method and get the multi-appearance feature by combining two Convolutional Neural Networks. Then, in order to further enhance the representation of the appearance feature, the multi-part model was constructed by combining the whole body and the six body parts. Additionally, we optimized the feature extraction process by adding a pooling layer. Comprehensive and comparative experiments with the state-of-the-art methods over publicly available datasets demonstrated that the proposed method can get promising results.

     

The effect of washing process on the cracking of ZrO2 microspheres by internal gelation

ZrO₂ microspheres are widely used as a simulant of UO₂ in the development of nuclear fuel. However, the cracking of ZrO₂ microspheres prepared by internal gelation is still a challenge during drying and sintering processes. To address this issue, we designed and optimized the washing process for obtaining crack-free ZrO₂ microspheres. Through thermogravimetric, infrared, Raman, BET, and SEM analysis, it is shown that the cracking of the microspheres is mainly related to the pores in microspheres. The washing solvent with low surface tension is used to reduce the effect of capillary force on pore shrinkage. Therefore, the optimal washing process was designed as trichloroethylene (TCE)—0.5 M NH₃.H₂O—Propylene glycol methyl ether (PM) and gel microspheres with a high specific surface area of 315.3 m²/g and pore volume of 0.4125 cm³/g were obtained. The characterizations also further showed that when the microspheres were dried and sintered, the water vapor and the decomposition gas of organic matter were completely released from the pores in the microspheres. Our new washing process could be directly extended for preparing crack-free ceramic microspheres by internal gelation.     

在工业中采用钛合金的微弧氧化

采用硬度测试，金相显微观察和透射电镜分析等方法，研究了微量稀土Er对高纯铝再结晶行为的影响，结果表明，弥散分布的细小Al3Er质点对位错和亚晶界具有钉扎作用，可以有效抑制再结晶，将高纯铝的再结晶温度提高50左右，同时还能显著细化再结晶晶粒，再结晶形核机制是亚晶聚合和亚昌长大双重机制。     

烷基磺酸钠型砂的质量控制

介绍了控制烷基磺酸钠型砂的混砂工艺、配制要点及保存使用等控制要点，并就实际生产中可能出现的一些问题作了探讨，提出了解决的办法。