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111.
Devi Neena Patel Sanjay K. S. Kumar Pradeep Singh Archana Thakur Nandita Lata Jeevan Pandey Deepak Thakur Vikram Chand Duni 《Catalysis Letters》2022,152(4):944-953
Catalysis Letters - In this study, Rhodococcus pyridinivorans cells containing hyperactive acyltransferase was immobilized on various macromolecules based-polymeric matrices and used to improve... 相似文献
112.
Silicon - Abundant applications of silica nanoparticles (SiNPs) have motivated many research groups for silica nanoparticles synthesis with tuned properties. Here we show the formation of SiNPs... 相似文献
113.
Vertically aligned carbon nanotube‐based composite: Elaboration and monitoring of the nanotubes alignment
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Mickael Huard Florent Roussel Stéphan Rouzière Stéphanie Patel Mathieu Pinault Martine Mayne‐L'Hermite Pascale Launois 《应用聚合物科学杂志》2014,131(1)
We present the different elaboration steps of a composite formed of carbon nanotubes (CNT) carpet embedded in an epoxy polymer. Detailed characterization at each step of the elaboration process is performed. The good alignment of CNT in as‐grown carpets is kept all along the elaboration process of the composite, as it is measured at both macro and microscopic scales by X‐ray scattering. We also ensured by X‐ray fluorescence measurements that the iron‐based catalyst particles used for the synthesis were removed from the carpet after a high temperature post‐annealing treatment. These measurements give valuable information for further applications involving unidirectional nanotube composites and membranes, where CNT alignment is a key parameter. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39730. 相似文献
114.
Nanographitic materials are gaining enormous interest as a new class of reinforcement for nanocomposites, promising revolutionary electrical, thermal, and mechanical properties. However, the progress has been quite limited especially in terms of mechanical properties. Here we report a significant leap, >2× increases in tensile strength and modulus of an epoxy composite using surface treated graphite nanoplatelets (GnPs). This corroborated by increases in Tgs as well as the presence of oxygen‐functionalized groups verified by XPS, suggest improved distribution and chemical interaction at the filler‐to‐matrix interface. Toughness values also showed increases with concentration, without compromising the strength or failure strain. However, if solvent levels during degassing were not reduced sufficiently, negligible contributions to strength and stiffness were observed with GnP loading. Subsequent elevated temperature treatments increased the strength of the composite due to cure enhancement of the matrix material, yet did not provide mechanical enhancements due to the incorporation of the filler. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40802. 相似文献
115.
Teaching-learning-based optimization (TLBO) is a recently developed heuristic algorithm based on the natural phenomenon of teaching-learning process. In the present work, multi-objective improved teaching-learning-based optimization (MO-ITLBO) algorithm is introduced and applied for the multi-objective optimization of plate-fin heat exchangers. The basic TLBO algorithm is improved to enhance its exploration and exploitation capacities by introducing the concept of number of teachers, adaptive teaching factor, tutorial training and self-motivated learning. The MO-ITLBO algorithm uses a grid-based approach to adaptively assess the non-dominated solutions maintained in an external archive. Minimizing total annual cost and the total weight of heat exchanger as well as minimization of total pressure drop and maximization of heat exchanger effectiveness for specific heat duty requirement are considered as objective functions. Two application examples are presented to demonstrate the effectiveness and accuracy of the proposed algorithm. 相似文献
116.
This two-part paper focuses on the characterization and simulation of two important molding defects in liquid composite molding—poor wetting and void formation. Part I analyzes resin-fiber wettability. This involved characterization of various liquids/resins and fiber filaments/fiber mats by using wicking test and capillary pressure measurement. Methodology to quantify capillary pressurewettability relationships was developed. It was found that the Leverett J function can correlate capillary pressure-saturation relationships for fiber reinforcements with various porosities and fiber architecture. 相似文献
117.
The grafting of acrylonitrile (AN) onto sodium salt of partially carboxymethylated amylose (Na-PCMA) using ceric ammonium nitrate (CAN) as an initiator has been studied in water/solvent mixtures. The solvents used include methanol, ethanol, propanol, butanol, acetone and carbon tetrachloride. The results have been discussed. The effect of reaction medium on the molecular weight of grafted PAN has also been studied. The chain transfer constants (Cs) for solvents like methanol, ethanol, propanol, butanol, acetone and carbon tetrachloride have been evaluated at 30°C by the help of Mayo's equation. 相似文献
118.
The quaternary ammonium compounds of guar gum (QAGG) and hydroxylethyl guar gum ether (QAHEG) were prepared by the reaction of guar gum (GG) or hydroxyethyl guar gum ether (HEG) with amine condensates of epichlorohydrin using either aliphatic or heterocyclic tertiary amines. These quaternary salts were characterized by infra-red spectra, viscometry and thermogravimetry. The temperature characteristics like initial decomposition temperature (IDT), ten percent volatilization temperature (T10), temperature of maximum rate of decomposition (Tmax), integral procedural decomposition temperature (IPDT) and activation energy of QAGG and QAHEG salts are compared with those of GG and HEG. 相似文献
119.
Sodiummonochloroacetate and sodiumhydroxide were employed under different conditions to prepare and optimize the carboxymethyl derivative of Leucaena glauca seed gum. The effects of concentration of reactants, reaction temperature and time have been interpreted in terms of degree of carboxymethylation as well as efficiency and rate of carboxymethylation reaction. The formation of the proposed derivative has also been supported by providing infra-red spectral characterization. 相似文献
120.
Polymer Bulletin - Depletion of the petroleum resources and poor flame-retardant properties of the epoxy resins drive researchers to develop an epoxy resin with good heat stability from... 相似文献