Determination of the optimum conditions in the removal of Bomaplex Red CR-L dye from the textile wastewater using O3, H2O2, HCO3- and PAC

Bomaplex Red CR-L textile dye was used in the experimental studies. Taguchi method was applied to determine optimum conditions in the removal of dye from synthetic textile wastewater. After the parameters were determined to remove Bomaplex Red CR-L dye from synthetic textile wastewater, the experimental studies were realized. The chosen experimental parameters and their ranges: HCO3- (mM), 0-39; temperature (degrees C), 18-70; ozone-air flow rate (l min-1), 5-15; the dye concentration (ppm), 200-600; particulate activated carbon (PAC) (g), 0-1.5; H2O2 (mM), 0-0056; pH, 3-12; and treatment time (min), 10-30, respectively. An orthogonal array L18 (2(1)x3(7)) for experimental plan and the smaller the better performance statistics formula were selected to define optimum conditions. The optimum conditions were found to be as follows: HCO3- (mM), 0; temperature (degrees C), 70; ozone-air flow rate (l min-1), 10; the dye concentration (ppm), 200; particulate activated carbon (PAC) (g), 1; H2O2 (mM), 0.056; pH, 12; and time (min), 20. Under these optimum conditions, it was determined that the Bomaplex Red CR-L removal efficiency from textile wastewater was 99%.     

Nondestructive sizing of a 3D surface crack generated in a railway component using closely coupled probes for direct-current potential drop technique

The direct-current potential drop technique was applied to the quantitative estimation of the size and shape of the crack generated in railway components. First, calibration equations that relate the potential drop to the crack depth and crack length along with its location were derived where the boundary element method was used for the electric potential problem. The crack depth, crack length and its location were then determined by analyzing an inverse problem by using the quasi-Newton method which compared the potential drop obtained by the calibration equations with measurements using a carbon steel specimen containing a crack. Although the values of depths were slightly scattered because depth estimations were sensitive to the crack location and changed with even a minimal change in distance between the crack and probes, the estimations of lengths and locations were adequate.     

A comparative study of the mechanical strength of chemical vapor-deposited diamond and physical vapor-deposited hard coatings

Four mechanical parameters of physical vapor-deposited (PVD) hard coatings were obtained, which were the residual strain, Young's modulus, film toughness, and interface toughness, concerning titanium aluminum nitride (TiAlN) and titanium nitride (TiN) coatings deposited on WC-Co substrates. The results were quantitatively compared with the author's previous trials for the case of chemical vapor-deposited (CVD) diamond coatings. Due to the significant difference in the mechanical properties between PVD hard coatings and CVD diamond coatings, it was necessary to develop new experimental techniques, which could properly evaluate those parameters for the case of PVD hard coatings. As a conclusion, film toughness of PVD hard coatings was surprisingly brittle. It was an order of magnitude smaller than that of CVD diamond coatings. In contrast, no significant difference was found in interface toughness between these different kinds of coatings. Concerning the residual strain, TiN had far larger level than the other two. These differences in mechanical properties were further discussed in relation to the difference in their wear behavior.     

Damage and replication checkpoint control in fission yeast is ensured by interactions of Crb2, a protein with BRCT motif, with Cut5 and Chk1

Fission yeast Cut5/Rad4 plays a unique role in the genome maintenance as it is required for replication, replication checkpoint, and normal UV sensitivity. It is unknown, however, how Cut5 protein is linked to other checkpoint proteins, and what part it plays in replication and UV sensitivity. Here we report that Cut5 interacts with a novel checkpoint protein Crb2 and that this interaction is needed for normal genome maintenance. The carboxyl terminus of Crb2 resembles yeast Rad9 and human 53BP1 and BRCA1. Crb2 is required for checkpoint arrests induced by irradiation and polymerase mutations, but not for those induced by inhibited nucleotide supply. Upon UV damage, Crb2 is transiently modified, probably phosphorylated, with a similar timing of phosphorylation in Chk1 kinase, which is reported to restrain Cdc2 activation. Crb2 modification requires other damage-sensing checkpoint proteins but not Chk1, suggesting that Crb2 acts at the upstream of Chk1. The modified Crb2 exists as a slowly sedimenting form, whereas Crb2 in undamaged cells is in a rapidly sedimenting structure. Cut5 and Crb2 interact with Chk1 in a two-hybrid system. Moreover, moderate overexpression of Chk1 suppresses the phenotypes of cut5 and crb2 mutants. Cut5, Crb2, and Chk1 thus may form a checkpoint sensor-transmitter pathway to arrest the cell cycle.     

IMPINGEMENT CASTING PROCESS: TURBULENT MIXING IN AN IMPINGEMENT MIXER

Theoretical analysis for turbulent mixing in an isotropic turbulent field was carried out. Depending on the material properties and flow field, either viscous shear force or dynamic pressure force breaks-up the globules. From an order of magnitude analysis, generalized equations for predicting globule sizes were derived. Experimental work on turbulent impingement mixing of kerosene and water revealed that macromixing and micromixing vary dramatically depending on the mixing chamber geometry. Best mixing (fast macromixing and small globule sizes) was obtained in an arrow shaped mixing chamber where the incoming jets were opposite to each other and slanted upward toward the mixing head. The coefficients of the equation for predicting the maximum globule size of immiscible liquids were obtained from the experimental results of arrow-shaped impingement mixers.     

Mechanical properties of amorphous alloy compacts prepared by different consolidation techniques

Amorphous alloy compacts of Fe₇₈B₁₃Si₉ prepared by three different techniques (explosive consolidation, high hydrostatic pressure consolidation and warm extrusion) were deformed in compression between 573 and 723 K at a strain rate ranging from 8.3×10^–5–4.2×10^–4s^–1. Explosively consolidated compacts had high strength ranging from 1.9–2.5 GPa below 623 K and could be plastically deformed to a strain of more than 50% at 673 K while preserving the amorphous state. Amorphous alloy compacts prepared by high hydrostatic pressure consolidation showed lower compressive strength. Those produced by warm extrusion were anisotropic in strength, the highest strength being as high as 2.74 GPa. It was also found that the geometry of the starting powders had a profound effect on the strength of the product compacts. Compacts prepared from flaky powders were stronger than those prepared from spherical ones. It is concluded that the mechanical properties of the amorphous alloy compacts depend on the consolidation technique, powder geometry and surface conditions of the powders, especially existence of oxide films.     

Effect of Surface Roughness on Droplet Bouncing in Droplet-Based Manufacturing Processes

In droplet-based manufacturing processes, such as drop-wise rapid prototyping, solder bumping and spray forming, the bouncing phenomenon adversely affects the quality of the deposit. This study investigates the effect of surface roughness on bouncing of liquid metal droplets from the substrate. An analytical model was developed to correlate the surface roughness with a non-dimensional droplet bouncing potential. In addition, an experimental study was conducted to image the deposition behavior of Pb-37wt% Sn solder droplets, 280 μm in diameter, on Au-plated substrates with a wide range of surface roughness. The high-speed image data correlate well with the model prediction that droplet bouncing increases as the surface roughness increases.     

Transmission electron microscopy of the iron-zinc δ1 intermetallic phase

• 1. 

  1. Two kinds of polycrystalline specimens, which fall in the δ1 single phase of the Bastin et al.'s binary phase diagram of the Fe-Zn system but fall in the δ1K, and the δ1P phases in Ghoniem et al's phase diagram have been prepared. The hardness of the δ1K, phase is higher than that of the δ1P, phase.

• 2. 

  2. The density of stacking faults and internal strain in the δ1P phase are higher than that of the 8 Ip phase.

• 3. 

  3. Electron di,tkction shows that ordering takes place in δ1K phase, while no ordering takes place in δ1P phase, the lattice parameter of δ1K phase being three times as large as that of δ1P phase.

     

Gel formation and primary chain lengths in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion

Gelation in 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO)-mediated cross-linking copolymerization of styrene and divinylbenzene (8.2 mol%) in aqueous miniemulsion at 125 °C has been investigated. The rate of gel formation relative to monomer conversion was the same in miniemulsion and the corresponding solution polymerization when the organic phase contained 6 vol% tetradecane (TD; hydrophobe) and 48 vol% toluene. However, at 54 vol% TD and no toluene (the same total monomer concentration), the conversion at the gel point was lower in miniemulsion than in solution, consistent with our previous results describing enhanced apparent pendant reactivity related to the presence of TD in the present system. The primary chain lengths were higher in miniemulsion with 54 vol% TD than in miniemulsion with 6 vol% TD and in solution (6 and 54 vol% TD). It was deduced via application of Flory-Stockmayer gelation theory that this difference in primary chain lengths, although significant with regards to gelation, was insufficient to explain the rapid gel formation in the miniemulsion containing 54 vol% TD, which is speculated to be related to specific effects of the heterogeneity of the miniemulsion system.     

Production of biodiesel with glycerol carbonate by non‐catalytic supercritical dimethyl carbonate

New biodiesel production processes comprising one‐step and two‐step supercritical dimethyl carbonate methods have been pioneered. The use of dimethyl carbonate allows the reaction conditions to be mild and thus avoid unwanted deterioration of substrates during reaction. In this process, without any catalyst applied, supercritical dimethyl carbonate converts triglycerides (rapeseed oil) into fatty acid methyl esters (FAME) along with glycerol carbonate as a value‐added by‐product, instead of glycerol. Free fatty acids could be also converted into FAME so that the total yield of biodiesel for both methods resulted in over 96 wt%. In addition, the produced FAME satisfy the fuel requirements for the international standards of biodiesel specification.