Conducting banding analysis with trained networks of sigmoid units

Berkeley et al. (1995, Connection Science, 7: 167–186) introduced a novel technique for analysing the hidden units of connectionist networks that had been trained using the backpropagation learning procedure. The literature concerning banding analysis is equivocal with respect to the kinds of processing units this technique can be used on. In this paper, it will be shown that, contrary to the claims in some published sources, banding analysis can be conducted on networks that use standard processing units that have a sigmoid activation function. The analytic process is then illustrated and the potential benefits of this kind of technique are discussed.     

Lead(II) Adsorption from Aqueous Solution by Poly(ethylene terephthalate)-g-Acrylamide Fibers

In this study, a reactive fibrous adsorbent was prepared by graft copolymerization of Acrylamide (AAm) onto poly(ethylene terephthalate) (PET) fibers and the adsorption properties of Pb(II) ion from aqueous solution by the reactive fibers were examined by batch equilibration technique. The effects of graft yield, pH, adsorption time, initial ion concentration and adsorption temperature on the adsorption amount of Pb(II) ion was studied. The results show that the adsorption amounts of Pb(II) ion increased with grafting yield, shaking time, initial ion concentration and adsorption temperature. Adsorption of Pb(II) ion was strongly affected by pH. A Lagergren pseudo-second-order was the model that best described the adsorption mechanism. It was found that the adsorption isotherm of the Pb(II) ion fit Langmuir-type isotherms. From the Langmuir equation the adsorption capacity was found as 39.57 mg/g fiber for Pb(II) ion for the copolymer with a graft yield of 15.7%. Quantitative desorption of Pb(II) from reactive fibers were found to be 96% by 5 M HNO₃. Five adsorption–desorption cycles demonstrated that the reactive fibers were suitable for repeated use without considerable change in adsorption capacity. The results of the thermodynamic study indicated that the adsorption processes was endothermic and spontaneous.     

Covalent functionalization of single walled carbon nanotubes with peptide nucleic acid: Nanocomponents for molecular level electronics

Imparting molecular recognition to carbon nanotubes (CNTs) by conjugating them with bio-molecules has been an area of great interest as the resulting highly functionalized CNT-bioconjugates find their applications in various fields like molecular level electronics, pharmaceuticals, drug delivery, novel materials and many others. In this work we demonstrate the synthesis of functionally engineered single walled carbon nanotubes (SWNTs)-peptide nucleic acid (PNA) conjugates especially for nanoelectronic applications. Here we exploited the exceptional structural and chemical advantages of PNA (an artificial analogue of DNA) to join SWNTs ropes. SWNT-PNA-SWNT conjugates were synthesized using carbodiimide coupling chemistry and characterized by host of techniques like scanning electron microscopy, atomic force microscopy and Fourier transform infrared spectroscopy. The results from different techniques confirm the formation of these conjugates. Theoretical analysis of molecular orbitals obtained by quantum mechanical simulations show that the highest occupied molecular orbital is located on the glutamate linker and that this interface state will align closely to the valence band of the extended SWNT facilitating charge transfer. The unique electrical and structural properties of these conjugates make them a potential candidate for application in CNT based nanodevices.     

Studies on synthesis,characterization, and metal adsorption of mimosa and valonia tannin resins

A few thermosetting wood adhesive tannin resin system from formaldehyde reaction with both condensed and hydrolysable tannin has been developed. Polymerization of formaldehyde with mimosa tannin and valonia tannin was carried out at optimal conditions obtained from literature to establish the adhesive resin formulation. Formed reaction products were characterized by FTIR spectroscopy. The possible adsorption mechanisms for the adsorption of various metal ions onto tannin‐formaldehyde resins were proposed. Also, thermal analysis were studied and discussed by differential scanning calorimetry and thermogravimetry. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 786–797, 2006     

The study of MIG weldability of heat-treated aluminum alloys

In this article, Metal Inert Gas (MIG) weldability of commercially received and aged samples of 6061-T₆ and 7075-T₆₅₁ aluminum alloys was investigated. The welding joints were prepared in ten different combinations. Microstructure, microhardness, EDX, energy-dispersive spectroscopy (EDS), and X-ray diffraction (XRD) analyses were used in order to evaluate the effect of aged heat treatment on the performance of welded joints. In addition, the mechanical properties of welding joints were characterized using the tensile and microhardness tests. In conclusion, it was shown that prewelding aging heat treatment improves the mechanical properties of welding joints.     

Evaluation of simple methods for assessing the uniaxial compressive strength of rock

Published data on 48 different rocks are used to evaluate the correlations between the uniaxial compressive strength (UCS) values and the corresponding results of point load, Schmidt hammer, sound velocity and impact strength tests. The variability of test results for each test and each rock type was evaluated by calculating the coefficient of variation. Using the method of least squares regression, the UCS values were correlated with the other test values. Also, the test methods were evaluated by plotting the estimated values of compressive strength vs. the measured values of compressive strength for each test. The results indicate that the least variability is shown in the impact strength test. So, among the test methods included in this study, the impact strength test is the most reproducible test; but the variability of test results for the other test methods is within acceptable limits for most engineering purposes. Strong linear relations between the point load strength index values and the UCS values were found for the coal measure rocks and the other rocks included in this study. The Schmidt hammer and the sound velocity tests exhibit significant non-linear correlations with the compressive strength of rock. In the sound velocity test, the data points are scattered at higher strength values. There is no clear relation between the impact strength values and the compressive strength values for the coal measure rocks. A weak non-linear correlation was found between the impact strength values and the compressive strength values for the other rocks. All test methods evaluated in this study, except the impact strength, provide reliable estimate of the compressive strength of rock. However, the prediction equations derived by different researchers are dependent on rock types and test conditions, as they are in this study.     

Estimating the uniaxial compressive strength of pyroclastic rocks from the slake durability index

Because the preparation of standard samples may not always be possible for weak or soft rocks, the prediction of uniaxial compressive strength (UCS) from indirect methods is widely used for preliminary investigations. In this study, the possibility of predicting UCS from the slake durability index (SDI) was investigated for pyroclastic rocks. For this purpose, pyroclastic rocks were collected from 31 different locations in the Cappadocian Volcanic Province of Turkey. The UCS and SDI tests were carried out on the samples in the laboratory. The UCS values were correlated with the SDI values and a very strong exponential relation was found between the two parameters. Since some data were scattered over the UCS values of 20 MPa, the correlation plot was redrawn for above and below the UCS values of 20 MPa, respectively. Very strong linear correlations were developed for two cases. Our concluding remark is that the UCS of pyroclastic rocks can be estimated from the SDI.

     

Modifications in the properties of gypsum construction element via addition of expanded macroporous silica granules

The present study is focused on the production of light weight silicate based macroporous filler for hardened gypsum and its effect on the product properties. Highly porous, durable foam like silica granules were produced from the relatively low cost material of silica gel desiccant. Swelling behaviour and mineralogical structure of the granules after swelling were examined. Different sample series were produced by replacing gypsum by expanded silica gel. Physical properties of the hardened gypsum were improved by the addition of expanded silica gel granules. Thermal conductivity of the gypsum decreased significantly when the expanded silica gel granules introduced into the gypsum. Expanded silica gel addition also improved the high temperature durability of gypsum. Much better integrity was observed after the testing of samples at 700 °C when compared to control series.