聚氧化乙烯改性水玻璃粘结剂的研究

确定了聚氧化乙烯改性水玻璃粘结剂的基本组分,测试了有机酯自硬和CO2气硬型砂的常温粘结强度和高温残留强度。研究发现,在水玻璃中加入聚氧化乙烯树脂能改善水玻璃的老化现象,充分发挥其粘结效率;粘结剂加入量相同时,型砂强度是普通水玻璃砂的1.5倍,800～1000℃时,型砂残留强度≤0.5MPa。结果表明,聚氧化乙烯改性水玻璃粘结剂加入量低,型砂工艺性能良好,浇注后出砂容易,有利于旧砂进一步干法回用。     

Microstructure and mechanical property of irradiated Zr−2.5Nb pressure tube in Wolsong unit-1

With the aim of assessing the degradation of Zr−2.5Nb pressure tubes operating in the Wolsong unit-1 nuclear power plant, characterization tests are being conducted on irradiated Zr−2.5Nb tubes removed after 10-year operation. The examined tube had been exposed to temperatures ranging from 264 to 306°C and a neutron fluence of 8.9×10²¹ n/cm² (E>1 MeV) at the maximum. Tensile tests were carried out at temperatures ranging from RT to 300°C. The density of a-type and c-type dislocations was examined on the irradiated Zr-2.5Nb tube using a transmission electron microscope. Neutron irradiation up to 8.9×10²¹ n/cm² (E>1 MeV) yielded an increase in a-type dislocation density of the Zr−2.5Nb pressure tube to 7.5×10¹⁴ m⁻², which was highest at the inlet of the tube exposed to the low temperature of 275°C. In contranst, the c-component dislocation density did not change with irradiation, keeping an initial dislocation density of 0.8×10¹⁴ m⁻² over the whole length of the tube. As expected, the neutron irradiation increased mechanical strength by about 17–26% in the transverse direction and by 34–39% in the longitudinal direction compared to that of the unirradiated tube at 300°C. The change in the mechanical properties with irradiation is discussed in association with the microstructural change as a function of temperature and neutron fluence.     

刮板造型的改进

介绍了对传统刮板造型存在问题所进行的改进.     

高温模具表面激光熔覆耐磨合金

用2kw CO 激光和送粉工艺,在4Cr5MoV_1Si 钢表面熔覆一层高温耐磨合金(Ni 基高温合金+WC),并应用于轧钢机导向板工作面。用扫描电子显微镜、电子探针和 x 射线衍射技术分别进行熔覆层的组织形态观察,微区成分分析和物相的鉴定。结果表明,熔覆层显微组织主要有许多弥散分布的 W_2C、(W,Ti)C_(1-x)、WC 和共晶态的 M_(12)C 及γ(f、c、c)母体相组成。室温及高温硬度测试结果表明,熔覆层有适中的室温硬度和相对较高的高温硬度。实际生产考核结果表明,激光熔覆导向板使用寿命大大提高,每对可轧钢1000～1100吨,而4Cr_5MoV_1Si 和普碳钢分别为400～500吨和200吨。     

Al—Li—Cu—Mg合金应力腐蚀性能及机理研究

利用恒应变速率方法研究了Al—Li—Cu—Mg合金的应力腐蚀开裂,包括时效条件及外加电位对应力腐蚀的影响,同时研究了试样表面相对氢浓度与外加电位及应力腐蚀时间的关系,实验结果表明,合金的应力腐蚀性能取决于时效条件,其中峰时效条件下最差,自然时效条件下最好,应力腐蚀敏感性及试样表面氢浓度与外加电位有关,阳极电位增加应力腐蚀敏感性,阴极电位低于临界电位时加速应力腐蚀,认为合金在应力腐蚀过程中阳极溶解与氢脆机制联合作用。     

Mg,Ca,Y,La和Ce在Ni3Al中的合金化行为

利用Ｘ射线衍射法确定了合金元素Ｍｇ，Ｃａ，Ｙ，Ｌａ及Ｃｅ在Ｎｉ３Ａｌ中的合金化行为。结果表明，Ｍｇ，Ｃａ，Ｙ，Ｌａ及Ｃｅ原子占据Ｎｉ３Ａｌ中的Ａｌ位，并按以下顺序增加Ｎｉ３Ａｌ的有序度：Ｍｇ，Ｃａ，Ｙ和Ｌａ－Ｃｅ。随着合金元素含量的增加，Ｎｉ３Ａｌ的点阵常数亦按Ｍｇ，Ｃａ，Ｙ，Ｌａ－Ｃｅ的顺序呈线性增大。     

Pre-annealing effect of electroless Ni−B deposit as a diffusion barrier for electroplated Cu electrodes

Ni−B film of 1 μm thickness was electrolessly deposited on an electroplated Cu bus electrode. The film, which encapsulates the Cu bus electrodes, prevents Cu oxidation and serves as a diffusion barrier against Cu contamination of the transparent dielectric layer in a plasma display during the firing process at 580 °C. The microstructure of theas-deposited barrier film was amorphous phase and crystallized to Ni and Ni₃B after annealing at 300 °C. The good barrier properties observed here can be explained by Ni₃B precipitates at the grain boundaries acting as a fast diffusion path via pre-annealing at 300 °C before the firing process at 580 °C.     

先天性心脏病相关PITX2c基因新突变研究

目的:研究先天性心脏病(congenital heart disease,CHD)相关PITX2c基因的新突变。方法:收集150例CHD患者和200名正常对照者的外周静脉血标本,使用DNA纯化试剂盒分离基因组DNA。使用DNA聚合酶扩增PITX2c基因的编码区和剪接位点,应用DNA测序试剂盒在DNA分析仪上对扩增片段进行测序。将所测序列与GenBank数据库中的PITX2c基因序列进行比对以发现PITX2c基因突变。使用在线程序MUSCLE分析突变氨基酸的保守性,分别应用MutationTaster和PolyPhen-2分析突变氨基酸的致病性。结果:在1例散发性CHD患者发现了1个新的PITX2c基因杂合错义突变,即p.S101G突变,突变率约为0.67%。该错义突变不存在于200名正常对照者。跨物种PITX2c蛋白之氨基酸序列对比显示第101位的丝氨酸在进化上完全保守,致病性预测显示所发现的PITX2c基因变异是致病性突变。结论:本研究揭示了CHD相关PITX2c基因新突变,对于制定新的CHD防治策略具有潜在的意义。     

Development of Habitat Suitability Criteria and In‐Stream Habitat Assessment for the Benthic Cyanobacteria Phormidium

Global demand for freshwater has led to unprecedented levels of water abstraction from riverine systems. This has resulted in large alterations in natural river flows. The deleterious impacts of reduced flows on fish and macroinvertebrate abundances have been thoroughly investigated; in contrast, there is a limited understanding of the potential for changes in the abundance of nuisance benthic algal/cyanobacterial blooms. In New Zealand, Phormidium sp. blooms are common in numerous rivers during summer low flows. In this study, an in‐stream habitat assessment is used to examine the relationship between Phormidium habitat availability and reducing flows. Over 650 observations of Phormidium mats, from seven sites (Hutt River, lower North Island, New Zealand), were used to construct habitat suitability curves for depth, velocity and substrate. Preference curves were fitted using both the ‘forage ratio’ and ‘quantile regression’ methods. Phormidium growth, observed at all seven sites, increased significantly from upstream (uppermost site, 5.2% mat cover) to downstream (63.5%). The habitat suitability curves revealed Phormidium had a large tolerance to velocity, depth and substrate type. Consequently, decreases in flow had only negligible effects on available Phormidium habitat. During periods of stable flow, Phormidium abundance positively correlated with increased nitrogen concentrations, potentially explaining the large variation in Phormidium cover from upstream to downstream. Quantile regression generated habitat suitability criteria were a more accurate predictor of available Phormidium habitat than the forage ratio criteria. Copyright © 2013 John Wiley & Sons, Ltd.     

Synchronization for linear singularly perturbed complex networks with coupling delays

This paper is concerned with the synchronization problem about linear singularly perturbed complex network system with coupling delay. The sufficient delay-dependent conditions for the synchronization of the network are established by introducing an equivalent network system with the Lyapunov stability theory. These conditions, which are formulated in terms of linear matrix inequalities, can be solved efficiently by the LMI toolbox of MATLAB. A simulation example is provided to show the validity of the proposed the synchronization conditions of the whole network.