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排序方式: 共有1226条查询结果,搜索用时 395 毫秒
91.
Gd-doped BiFeO3 polycrystalline ceramics were synthesized by solid-state reaction method and their dielectric and magnetic properties were investigated. X-ray diffraction pattern showed that Bi1 − xGdxFeO3 (x = 0, 0.05 and 0.1) ceramics were rhombohedral. The Gd substitution has suppressed the usual impurity peaks present in the parent compound and we obtained single phase Bi0.9Gd0.1FeO3 ceramic. Gd substitution reduced the antiferromagnetic Néel temperature (TN) in Bi1 − xGdx FeO3. An anomaly in the dielectric constant(ε) and dielectric loss(tan (δ)) in the vicinity of the antiferromagnetic Néel temperature (TN) was observed. Ferroelectric and magnetic hysteresis loops measured at room temperature indicated the coexistence of ferroelectricity and magnetism. The room temperature magnetic hysteresis loops were not saturated, but the magnetic moment was found to increase with increase in Gd concentration. 相似文献
92.
The present study reports a simple and low cost synthesis of zero‐valent silver nanoparticles (ZVSNPs) from silver nitrate using the leaf extract of Spondias dulcis. The ZVSNPs showed a unique peak at 420 nm in UV–vis spectrum. The SEM image portrayed cuboidal shaped particles. The EDX spectrum designated the elemental silver peak at 3 keV. In XRD, a sharp peak at 32.47° denoted the existence of (1 0 1) lattice plane and the average crystallite size was calculated as 48.61 nm. The lattice parameter was determined as 0.39 nm. The FTIR spectra of the leaf extract and ZVSNPs showed shifts in the specific functional group bands which ascertained the involvement of phytoconstituents in the formation and capping of nanoparticles. The average hydrodynamic size was measured as 59.66 nm by DLS method. A low PDI, 0.187 witnessed the monodispersity. A negative zeta potential value of −15.7 mV indicated the negative surface charges of the nanoparticles. The bactericidal action of ZVSNPs was demonstrated against two pathogens S.typhimurium and E.coli during which a dosage dependent zone of inhibition results was observed. Additionally, the catalytic potential of ZVSNPs was examined for the degradation of methylene blue dye in which an accelerated degradation of the dye was observed.Inspec keywords: antibacterial activity, crystallites, electrokinetic effects, scanning electron microscopy, nanoparticles, particle size, ultraviolet spectra, X‐ray chemical analysis, microorganisms, light scattering, nanofabrication, materials preparation, X‐ray diffraction, visible spectra, silver, dyes, Fourier transform infrared spectraOther keywords: wavelength 420.0 nm, Ag, voltage ‐15.7 mV, size 59.66 nm, size 0.39 nm, size 48.61 nm, electron volt energy 3.0 keV, Fourier transform infrared spectra, methylene blue dye, bactericidal action, dynamic light scattering, lattice parameter, Escherichia coli, Salmonella typhimurium, Spondias dulcis, negative zeta potential, polydispersity index, crystallite size, leaf extract, X‐ray diffraction, energy dispersive X‐ray spectrum, cuboidal‐shaped particles, scanning electron microscopy image, ultraviolet–visible spectrum, silver nitrate, zero‐valent silver nanoparticles 相似文献
93.
Bal K Agrawal S Agrawal P S Yadav S Kumar J S Negi Namrata Varshney 《Bulletin of Materials Science》1991,14(4):967-971
In the series of the layered highT
c
superconductors (A)1,2 B2Ca
n−1Cu
n
O2n+3,4 (A=Tl or Bi;B=Ba or Sr), withn=number of consecutive Cu-O layers, the electron energy states of some of the Tl-based systems have been investigated. The
electron and phonon dispersion curves have been obtained. The electronic states near the Fermi level are dominated by the
hybridized Cu(d) and the O(p) orbitals. The dispersion curves are highly two-dimensional with very small dispersion alongc-axis. The number of bands is enhanced with increase in the number of the consecutive Cu-O planes (n). The present results agree with those obtained earlier for other superconducting phases. The phonons are overall dominated
by the vibrations of the light mass oxygen atom modes both lying in or outside the Cu-O planes. The low-frequency phonons
involve the motions of the heavier Tl, Ba atoms etc. 相似文献
94.
Blend samples of cardanol-based epoxidized novolac resin and different weight percentages of carboxyl-terminated butadiene
acrylonitrile (CTBN) were developed and cured with stoichiometric amounts of aliphatic amine. The formation of various products
during the curing of blend samples has been studied by Fourier-transform infrared spectroscopy. The dynamic differential scanning
calorimeter scans showed that the pure epoxies and their blend samples with CTBN cured in the temperature range of 100–150°C.
The blend sample containing 15 wt% CTBN showed the least cure time (at 120°C) among all other blend samples. Upon evaluation,
it was found that blend samples exhibit better properties compared to pure epoxy resin in terms of increase in impact strength
and elongation-at-break of the casting and gloss, scratch hardness, adhesion, and flexibility of the film. The improvement
in these properties indicates that the rubber modified resin would be more durable than the epoxy based on cardanol. Chemical
and morphological properties of the formulated resins were also determined. The thermal stability of the blend samples containing
15 wt% CTBN in epoxy resin was the highest among all other prepared systems. The blend morphology, studied by scanning electron
microscope, showed the presence of precipitated discrete rubber particles, which dispersed throughout the epoxy matrix—i.e.,
they revealed the presence of two-phase morphological features. 相似文献
95.
Rajesh Patel VishnuP. Srivastava Lal DharS. Yadav 《Advanced Synthesis \u0026amp; Catalysis》2010,352(10):1610-1614
The first procedure to access N‐tosylimines directly from alcohols under mild and neutral conditions is reported. The protocol involves saccharin‐lithium bromide‐catalyzed oxidation of alcohols to aldehydes/ketones with chloramine‐T followed by their condensation with the in situ generated oxidation by‐product p‐toluenesulfonamide in the same reaction vessel to afford N‐tosylimines in 40–90% overall yields. The present work opens up a new and efficient synthetic route to N‐tosyimines directly from alcohols in a one‐pot procedure. 相似文献
96.
Silicon - In this paper, we have studied effect of localised charges on performance of UTBB FDSOI FET. Purpose behind this work is to understand the performance of UTBB FDSOI FET under the... 相似文献
97.
Comparative Performance of Different Sector Arrangement in a Desiccant Wheel Using a Mathematical Model 下载免费PDF全文
A one‐dimensional mathematical model has been used for a three‐sector desiccant wheel (two sectors with purge) with different flow arrangements. The model considers both gas and solid side resistance and shows a good agreement with experimental results. This model has been used to conduct a comparative performance analysis in both the effective adsorption and effective regeneration sector of a desiccant wheel. It was found that an effective regeneration sector gives better results for the performance parameters (rotation of wheel, regeneration temperature, velocity, and ambient moisture) as compared to an effective adsorption sector. © 2013 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com/journal/htj ). DOI 10.1002/htj.21103 相似文献
98.
The aim of this report is to build a portable solar thermal bank based on a Scheffler reflector that is capable of boiling-type cooking using HITEC as a thermal storage material. This report reviews the problems related to solar cooking and evaluates the novel layout of a portable solar thermal bank which includes a daily thermal storage vessel. This stove is in the shape of a cylindrical container filled with phase-changing latent heat storage material. Inside the container, we provide a small gap taking into account the volumetric expansion of the phase change material (PCM) during the melting process. The solar thermal bank is charged in the sun. It is placed directly for a few hours under the focus of a Scheffler reflector, which charges the solar thermal bank with enough thermal energy stored. After a while, the cooking process can be completed by users using that stored heat. The top cavity is used as a cooking pot in a solar thermal bank. Cooking meals do not require direct sunlight, which is typical for most solar cookers. The portable solar thermal bank is an alternative for low-income households and adapts to local traditions of indoor cooking. It is portable and can be used safely to cook indoors or outdoors. In this study, a solar cooker with a thermal storage device was developed using a PCM. The size of the stove has been calculated by calculating the energy consumption for two to three people. HITEC salt has been chosen as a phase change material for thermal storage, which will be used for cooking when there is no sunlight. It enhances the applicability of solar cooking and preserves cooking possibilities using energy stored throughout the day at low production costs. 相似文献
99.
The alkylation of hydroquinone yields industrially important compounds, amongst which tert-butylhydroquinone is a very important precursor for its use in pharmaceuticals and in developing photographic plates. Twenty per cent (w/w) dodecatungstophosphoric acid supported on K10 montmorillonite clay (DTP/K10) was found to be a very efficient and novel catalyst in comparison with several others for alkylation of hydroquinone with different alkylating agents such as methyl-tert-butyl-ether (MTBE) and tert-butanol at 150°C in an autoclave. A summary of characterisation of DTP/K10 is provided and related to the activity. Various reaction parameters were also investigated and a kinetic model was built. The rate of alkylation with MTBE was much faster than that with tert-butanol. The reaction follows a typical second order kinetics at a fixed catalyst loading with weak adsorption of both the species. The energy of activation was found to be 19.34 kcal/mol. 相似文献
100.
In present communication, we propose a modified resource allocation strategy, namely, hybrid connection algorithm, for achieving efficient restoration in WDM optical networks. The main theme of the algorithm is that, while attempting connection establishment, a wavelength is reserved in advance for providing resources for backup lightpaths. The analysis and the comparison of the proposed strategy with other existing strategies has been undertaken using metrics such as, restoration efficiency, number of wavelength links used by primary and backup lightpaths, and the percent link utilization. The proposed strategy provides 100% restoration efficiency and much better performance than the existing techniques. 相似文献