Phase Formations and Electrical Properties of Various (Bi, La)4Ti3O12 Thin Films by Chemical Solution Deposition

The phase formation and electrical properties of (Bi, La)₄Ti₃O₁₂ (BLT) thin film and V-, Sm-doped BLT thin films prepared by the chemical solution deposition method on Pt/TiO₂/SiO₂/Si substrates have been investigated. It was observed that the microstructure and electrical properties of BLT thin films dramatically varied with V- and Sm-doping. The crystallinity and grain size of BLT thin films were definitely increased by V- and Sm-doping into BLT films, which resulted in the enhancement of remanent polarization in doped BLT films. The remanent polarization (Pr) of Sm-doped BLT films annealed for 3 min by an RTA system was about 9 C/cm². The V- and Sm-doped BLT films also exhibited good fatigue characteristics under bipolar stressing to 10¹⁰ cycles.     

Non-stoichiometry, grain boundary transport and chemical stability of proton conducting perovskites

The interrelationship between defect chemistry, non-stoichiometry, grain boundary transport and chemical stability of proton conducting perovskites (doped alkaline earth cerates and zirconates) has been investigated. Non-stoichiometry, defined as the deviation of the A : M molar ratio in AMO₃ from 1 : 1, dramatically impacts conductivity, sinterability and chemical stability with respect to reaction with CO₂. In particular, alkaline earth deficiency encourages dopant incorporation onto the A-atom site, rather than the intended M-atom site, reducing the concentration of oxygen vacancies. Transport along grain boundaries is, in general, less favorable than transport through the bulk, and thus only in fine-grained materials does microstructure impact the overall electrical properties. The chemical stability of high conductivity cerates is enhanced by the introduction of Zr. The conductivity of BaCe_0.9–x Zr _x M_0.1O₃ perovskites monotonically decreases with increasing x (increasing Zr content), with the impact of Zr substitution increasing in the order M = Yb Gd Nd. Furthermore, the magnitude of the conductivity follows the same sequence for a given zirconium content. This result is interpreted in terms of dopant ion incorporation onto the divalent ion site.     

Dephasing Rate and Superconducting Proximity

We show that the maximum penetration depth of the anomalous quasiclassical Green's function from a superconductor into an adjacent normal metal is directly related to the phase relaxation time . The latter describes normal-metal phase correlations between two electrons with opposite spins. In the presence of spin-dependent interactions this phase relaxation time differs from the one found in weak localization corrections to the conductivity. The Josephson current measurements in a SINIS-structure could be used to determine experimentally.     

Collaborative object-oriented visualization environment

In this paper, we present a Collaborative Object-oriented Visualization Environment (COVE) which provides a flexible and extensible framework for collaborative visualization. COVE integrates collaborative and parallel computing environments based on a distributed object model. It is built as a collection of concurrent objects: collaborative and application objects which interact with one another to construct collaborative parallel computing environments. The former enables COVE to execute various collaborative functions, while the latter allows it to execute fast parallel visualization in various modes. Also, flexibility and extensibility are provided by plugging the proper application objects into COVE at run-time, and making them interact with one another through collaboration objects. For our experiment, three visualization modes for volume rendering are designed and implemented to support the fast and flexible analysis of volume data in a collaborative environment. This work has been supported by KIPA-Information Technology Research Center, University research program by Ministry of Information & Communication, and Brain Korea 21 projects in 2005.     

Insertion of Vertically Aligned Nanowires into Living Cells by Inkjet Printing of Cells

Effective insertion of vertically aligned nanowires (NWs) into cells is critical for bioelectrical and biochemical devices, biological delivery systems, and photosynthetic bioenergy harvesting. However, accurate insertion of NWs into living cells using scalable processes has not yet been achieved. Here, NWs are inserted into living Chlamydomonas reinhardtii cells (Chlamy cells) via inkjet printing of the Chlamy cells, representing a low‐cost and large‐scale method for inserting NWs into living cells. Jetting conditions and printable bioink composed of living Chlamy cells are optimized to achieve stable jetting and precise ink deposition of bioink for indentation of NWs into Chlamy cells. Fluorescence confocal microscopy is used to verify the viability of Chlamy cells after inkjet printing. Simple mechanical considerations of the cell membrane and droplet kinetics are developed to control the jetting force to allow penetration of the NWs into cells. The results suggest that inkjet printing is an effective, controllable tool for stable insertion of NWs into cells with economic and scale‐related advantages.     

Personality and its effects on learning performance: Design guidelines for an adaptive e-learning system based on a user model

An increasingly widespread interest in developing fully adaptable e-learning systems (e.g., intelligent tutoring systems) has led to the development of a wide range of adaptive processes and techniques. In particular, advances in these systems are based on optimization for each user's learning style and characteristics, to enable a personalized learning experience. Current techniques are aimed at using a learner's personality traits and its effect on learning preferences to improve both the initial learning experience and the information retained (e.g., top-down or bottom-up learning organization). This study empirically tested the relationship between a learner's personality traits, analyzed the effects of these traits on learning preferences, and suggested design guidelines for adaptive learning systems. Two controlled experiments were carried out in a computer-based learning session. Our first experiment showed a significant difference in the learning performance of participants who were identified as introverts vs. those who were identified as being extroverts, according to the MBTI scale. As the distinction between extroverted personality types vs. introverted personality types showed the strongest correlation in terms of different learning styles, we used this criteria in our second experiment to determine whether design guidelines for appropriate content organization could reinforce the aforementioned correlation between personality type and learning experience.     

Properties of surface treated transparent conducting single walled carbon nanotube films

Transparent conducting single-walled carbon nanotube (SWCNT) films were fabricated using the spin coating technique. UV-ozone treated and poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate) coated glass substrates together with SWCNT dispersed in 1,2-dichlorobenzene were used to promote the adhesion of SWCNT at room temperature. The produced film had a sheet resistance of 430 Ω/□ for 80% optical transparency at 550 nm. The spin coated SWCNT film after a post fabricated treatment in a mixer of isopropyl alcohol and nitric acid solution had a sheet resistance as low as 120 Ω/□ for 80% optical transparency at 500 nm. Besides reduction in sheet resistance, we obtained stable and strongly adherent SWCNT films on substrate that could serve as an alternative to transparent conducting oxides in display and optoelectronic applications.     

Optimization of the influential factors for the improvement of CO2 utilization efficiency and CO2 mass transfer rate

Microalgae fix CO₂ as energy source and afford biomass and high valued products such as carotenoids, pigments, proteins, and vitamins that can be used for the production of nutraceuticals, pharmaceuticals, animal feed additives, cosmetics, etc. Carbon dioxide is the sole source of carbon and it is supplied continuously for the microalgal cultivation. But undissolved CO₂ is lost by outgassing and sufficient dissolved CO₂ should be provided to avoid carbon limitation. The effect of CO₂ mass transfer with different CO₂ concentrations, aeration rate of gas, bubble size, baffle type and baffle number on the growth of Chlorella sp. AG10002 was investigated and the optimized conditions for the enhancement of biomass productivity were determined. We confirm that these results can be provided as basic data to improve the CO₂ mass transfer ability for the high density culture of Chlorella sp. and some microalgae having commercial value.     

Development and application of gas hydrate reservoir simulator based on depressurizing mechanism

Natural gas hydrates are known to occur in vast quantities at the ocean floor or in permafrost regions. In-situ hydrate contains great volumes of methane gas, which indicates a potential future energy resource. In this study, we have developed a three-dimensional, multi-phase (gas, water, and hydrate) flow finite-difference model by using implicit pressure explicit saturation technique in order to investigate simultaneous flow through ice-liked hydrate reservoir. The developed model is based on the depressurizing method as producing mechanism. The model evaluates local gas generation dissociated from the hydrate with the aid of kinetic dissociation theory proposed by Kim-Bishnoi. The computation of kinetic dissociation uses the empirical dissociation rate as a function of specific surface area between phases and pressure difference. With the developed model, a one-dimensional system has been simulated for analyzing the production performance of a hydrate reservoir and for investigating the effect of hydrate saturation on absolute permeability and relative permeability characteristics. Also, for the three-dimensional field-scaled reservoir system, a number of numerical exercises have been conducted to understand the effect of mass transfer and to characterize the flowing mechanism under the conditions of increased permeability resulting from the dissociation hydrate.