A Unified Artificial Neural Network Architecture for Active Power Filters

In this paper, an efficient and reliable neural active power filter (APF) to estimate and compensate for harmonic distortions from an AC line is proposed. The proposed filter is completely based on Adaline neural networks which are organized in different independent blocks. We introduce a neural method based on Adalines for the online extraction of the voltage components to recover a balanced and equilibrated voltage system, and three different methods for harmonic filtering. These three methods efficiently separate the fundamental harmonic from the distortion harmonics of the measured currents. According to either the Instantaneous Power Theory or to the Fourier series analysis of the currents, each of these methods are based on a specific decomposition. The original decomposition of the currents or of the powers then allows defining the architecture and the inputs of Adaline neural networks. Different learning schemes are then used to control the inverter to inject elaborated reference currents in the power system. Results obtained by simulation and their real-time validation in experiments are presented to compare the compensation methods. By their learning capabilities, artificial neural networks are able to take into account time-varying parameters, and thus appreciably improve the performance of traditional compensating methods. The effectiveness of the algorithms is demonstrated in their application to harmonics compensation in power systems     

Formation and Etching of the Insulating Sr-Rich V5+ Phase at the Metallic SrVO3 Surface Revealed by Operando XAS Spectroscopy Characterizations

In the search of low cost and more efficient electronic devices, here the properties of SrVO₃ transparent conductor oxide (TCO) thin film are investigated, both visible-range optically transparent and highly conductive, it stands as a promising candidate to substitute the standard indium-tin-oxide (ITO) in applications. Its surface stability under water (both liquid and vapor) and other gaseous atmospheres is especially addressed. Through the use of spectroscopy characterizations, X-ray photoemission and operando X-ray absorption measurements, the formation of a thin Sr-rich V⁵⁺ layer located at the surface of the polycrystalline SrVO₃ film with aging is observed, and for the first time how it can be removed from the surface by solvating in water atmosphere. The surface recovery is associated to an etching process, here spectroscopically characterized in operando conditions, allowing to follow the stoichiometric modification under reaction. Once exposed in oxygen atmosphere, the Sr-rich V⁵⁺ layer forms again. The findings improve the understanding of aging effects in perovskite oxides, allowing for the development of functionalized films in which it is possible to control or to avoid an insulating surface layer. This constitutes an important step towards the large-scale use of V-based TCOs, with possible implementations in oxide-based electronics.     

Photoluminescence from Liquid‐Exfoliated WS2 Monomers in Poly(Vinyl Alcohol) Polymer Composites

While liquid phase exfoliation can be used to produce nanosheets stabilized in polymer solutions, very little is known about the resultant nanosheet size, thickness, or monolayer content. The present study uses semiquantitative spectroscopic metrics based on extinction, Raman, and photoluminescence (PL) spectroscopy to investigate these parameters for WS₂ nanosheets exfoliated in aqueous poly(vinyl alcohol) (PVA) solutions. By measuring Raman and PL simultaneously, the monolayer content can be tracked via the PL/Raman intensity ratio while varying processing conditions. The PL is found to be maximized for a stabilizing polymer concentration of 2 g L^?1. In addition, the monolayer content can be controlled via the centrifugation conditions, exceeding 5% by mass in some cases. These techniques have allowed tracking the ratio of PL/Raman in a droplet of polymer‐stabilized WS₂ nanosheets as the water evaporates during composite formation. No evidence of nanosheet aggregation is found under these conditions although the PL becomes dominated by trion emission as drying proceeds and the balance of doping from PVA/water changes. Finally, bulk PVA/WS₂ composites are produced by freeze drying where >50% of the monolayers remain unaggregated, even at WS₂ volume fractions as high as 10%.     

Closing the hydrogen cycle with the couple sodium borohydride-methanol,via the formation of sodium tetramethoxyborate and sodium metaborate

Methanolysis of sodium borohydride (NaBH₄) is one of the methods efficient enough to release, on demand, the hydrogen stored in the hydride as well as in 4 equiv of methanol (CH₃OH). It is generally reported that, in methanolysis, sodium tetramethoxyborate (NaB(OCH₃)₄) forms as single component of the spent fuel. It is, however, necessary to clearly investigate some critical aspects related to it. We first focused on the methanolysis reaction where NaBH₄ was reacted with 2, 4, 8, 16, or 32 equiv of CH₃OH. With 2 equiv of CH₃OH, the conversion of NaBH₄ is not complete. With 4 to 32 equiv of CH₃OH, NaBH₄ is totally methanolized (conversion of 100%). The best conditions are those involving 4 equiv of CH₃OH as they offer the highest effective gravimetric hydrogen storage capacity with 4.8 wt%, an attractive H₂ generation rate with 331 mL(H₂) min⁻¹—a performance achieved without any catalyst—and the formation of NaB(OCH₃)₄ as single product as identified by X-ray diffraction, Fourier transform infrared spectroscopy, and nuclear magnetic resonance. We then focused on the transformation of this product NaB(OCH₃)₄ into sodium metaborate (NaBO₂), via the formation of sodium tetrahydroxyborate (NaB(OH)₄). NaB(OCH₃)₄ is easily transformed in water, by hydrolysis, at 80°C and for 90 minutes, into NaB(OH)₄ and 4 equiv of CH₃OH. In doing so, the cycle with CH₃OH is closed. Subsequently, NaB(OH)₄ is recovered and converted into NaBO₂ under heating at 500°C. This reaction liberates 4 equiv of H₂O, which allows to close the cycle with water. Based on these achievements, we have finally proposed a triangular recycling scheme aiming at closing the cycle with the protic reactants of the aforementioned reactions. This scheme may be used as base for implementing a closed cycle with the couple NaBH₄-CH₃OH.     

Electrode surface confinement of self-assembled enzyme aggregates using magnetic nanoparticles and its application in bioelectrocatalysis

Self-assembled enzyme aggregates, prepared from magnetic iron oxide nanoparticles, avidin, and a biotinylated redox enzyme, were shown particularly useful for the simple, fast, and efficient construction of highly enzyme-loaded electrodes with the help of a magnet. The approach was illustrated in the case of the bioelectrocatalytic oxidation of NADH by a diaphorase oxidoreductase in the presence of a ferrocene mediator. Two different self-assembling procedures were tested, taking advantage of the spontaneous aggregation of the nanoparticles in the presence of avidin and also of the multivalency binding of biotinylated diaphorase toward avidin. Activities of the bound and unbound diaphorase were systematically controlled allowing determination of the number of active biotinylated diaphorase per nanoparticle incorporated within each magnetic enzyme aggregate. An active enzyme loading capacity of up to 2.35 nmol mg-1 was found for the best nanostructured enzyme assembly, which is 200 times better than for commercialized magnetic micrometer-sized beads coated with streptavidin and saturated with diaphorase. With the help of a permanent magnet, the magnetic enzyme aggregates were finally magnetically collected as a film on the surface of a small screen-printed carbon electrode and the catalytic currents recorded by cyclic voltammetry. From the analysis of the steady-state catalytic current responses and the kinetic rate constants of biotinylated diaphorase, it was possible to determine the enzyme concentration within the magnetic films. Owing to the high enzyme loading in the aggregates of nanoparticles (i.e., 130 microM), the catalytic current responses were definitely higher than the ones measured at an electrode coated with a closed-packed monolayer of diaphorase or at an electrode covered with a film of magnetic micrometer-sized streptavidin beads saturated with diaphorase.     

Comprehensive profiling and quantitation of amine group containing metabolites

Primary and secondary amines, including amino acids, biogenic amines, hormones, neurotransmitters, and plant siderophores, are readily derivatized with 6-aminoquinolyl-N-hydroxysuccinimidyl carbamate using easily performed experimental methodology. Complex mixtures of these amine derivatives can be fractionated and quantified using liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS). Upon collision induced dissociation (CID) in a quadrupole collision cell, all derivatized compounds lose the aminoquinoline tag. With the use of untargeted fragmentation scan functions, such as precursor ion scanning, the loss of the aminoquinoline tag (Amq) can be monitored to identify derivatized species; and the use of targeted fragmentation scans, such as multiple reaction monitoring, can be exploited to quantitate amine-containing molecules. Further, with the use of accurate mass, charge state, and retention time, identification of unknown amines is facilitated. The stability of derivatized amines was found to be variable with oxidatively labile derivatives rapidly degrading. With the inclusion of antioxidant and reducing agents, tris(2-carboxyethyl)-phosphine (TCEP) and ascorbic acid, into both extraction solvents and reaction buffers, degradation was significantly decreased, allowing reproducible identification and quantification of amine compounds in large sample sets.     

Goniocolorimetry: From measurement to representation in the CIELAB color space

The classical definitions of color are well adapted to diffusing objects, whose color is almost independent of the viewing angle, and to very glossy object observed in the specular direction in respect to the light source. For glossy or iridescent objects, the color is difficult to characterize due to its dependence on the viewing direction. In order to cope with such objects and to represent their angle‐dependent colors in a colorimetric space, we adapt the CIELAB space to “goniocolorimetric” measurements. A crucial point when defining this space is the statement of the viewing solid angle. First, we suggest performing a BRDF measurement at high angular resolution in order to characterize the gloss of the specimen. Then, since for the definition of colors the CIE recommends cones of half‐angle of 2° or 10°, we propose to convert the measured BRDF into a reflectance factor defined in respect to these solid angles. This procedure is eased by a planar multispectral image of the BRDF, where solid angles are specified by the pixel size. At last, the reflectance factors are converted into CIELAB coordinates. By using this procedure, the perfect white diffuser but also the perfect mirror can be represented in this colorimetric space. © 2010 Wiley Periodicals, Inc. Col Res Appl, 36, 169–178, 2011;     

Transition from core-shell to Janus chemical configuration for bimetallic nanoparticles

In order to determine the possibilities to control the chemical configuration of bimetallic nanoparticles, we have considered CuAg nanoparticles synthesized by a physical route as a model in this study. The synthesis was made by pulsed laser deposition under ultra-high vacuum conditions, via a sequential deposition procedure. We show that the temperature of the substrate and the absolute quantity of Ag in a particle are the main parameters that drive the chemical configuration. To explain the transition from a core-shell configuration to a Janus configuration as a function of Ag quantity, we have conducted density-functional theory calculations and atomistic molecular dynamics simulations to investigate the stability of this system. The results are presented together with the experimental observations.