Soft solution fluorine-free synthesis of anatase nanoparticles with tailored morphology

TiO₂ nanoparticles with tailored morphology have been synthesized under exceptionally soft conditions. The strategy is based on the use of a non-aqueous alcoholic reaction medium in which water traces, coming either from the air (atmospheric water) or from an ethanol–water azeotropic mixture (ethanol 96%), are incorporated in order to accelerate hydrolysis of the Ti–precursor. Moreover, organic surfactants have been used as capping agents so as to tailor crystal growth in certain preferential directions. Combinations of oleic acid and oleylamine, which lead to the formation of another surfactant, dioleamide, are employed instead of fluorine-based compounds, thus increasing the sustainability of the process. As a result, TiO₂ nanostructured hierarchical microspheres and individual nanoparticles with exposed high-energy facets can be obtained at atmospheric pressure and temperatures as low as 78 °C.     

Neural basis for recognition confidence in younger and older adults.

Although several studies have examined the neural basis for age-related changes in objective memory performance, less is known about how the process of memory monitoring changes with aging. The authors used functional magnetic resonance imaging to examine retrospective confidence in memory performance in aging. During low confidence, both younger and older adults showed behavioral evidence that they were guessing during recognition and that they were aware they were guessing when making confidence judgments. Similarly, both younger and older adults showed increased neural activity during low- compared to high-confidence responses in the lateral prefrontal cortex, anterior cingulate cortex, and left intraparietal sulcus. In contrast, older adults showed more high-confidence errors than younger adults. Younger adults showed greater activity for high compared to low confidence in medial temporal lobe structures, but older adults did not show this pattern. Taken together, these findings may suggest that impairments in the confidence–accuracy relationship for memory in older adults, which are often driven by high-confidence errors, may be primarily related to altered neural signals associated with greater activity for high-confidence responses. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Recipes for Spatial Statistics with Global Datasets: A Martian Case Study

The Mars Odyssey Gamma Ray Spectrometer has yielded planetary data of global extent. Such remote-sensing missions usually assign the value of a continuous-valued geospatial attribute to a uniform latitude-longitude grid of bins. Typical attributes include elemental-mass fraction, areal fraction of a mineral type, areal fraction of rocks, thermal inertia, etc. The fineness of the grid is chosen according to the spatial resolution of the orbiter and concomitant data processing. We describe methods to maximize the information extracted from both bin and regional data. Rigorous use of statistical parameters and related methods for inter- and intra- regional comparisons are also discussed. While we discuss results from the Mars Odyssey mission, the techniques we describe are applicable whenever continuous-valued attributes of a planet’s surface are characterized with bins and regions. Our goal is to distill the simplest statistical methods for regional comparisons that would be intuitively accessible to planetary scientists.     

Validity of the WISC–IV Spanish for a clinically referred sample of Hispanic children.

The Wechsler Intelligence Scale for Children (WISC) is the most commonly used intelligence test for children. Five years ago, a Spanish version of the WISC–IV was published (WISC-IV Spanish; Wechsler, 2005), but a limited amount of published information is available regarding its utility when assessing clinical samples. The current study included 107 children who were Spanish speaking and of Puerto Rican descent that had been administered the WISC–IV Spanish. They were subdivided into a clinical sample of 35 children with diagnoses of various forms of brain dysfunction (primarily learning disability, attention-deficit/hyperactivity disorder, and epilepsy) and a comparison group made up of 72 normal children who were part of the WISC–IV Spanish version standardization sample. Comparisons between these groups and the standardization sample were performed for the WISC–IV Spanish index and subtest scores. Results indicated that the clinical sample performed worse than the comparison samples on the Working Memory and Processing Speed Indexes, although findings varied to some extent depending on whether the clinical group was compared with the normal comparison group or the standardization sample. These findings provide support for the criterion validity of the WISC–IV Spanish when it is used to assess a clinically referred sample with brain dysfunction. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Using Superconducting Magnet to Reproduce Quick Variations of Gravity in Liquid Oxygen

A ground based facility (OLGA), providing magnetic compensation of gravity in oxygen, has been developed. A 2-T superconducting magnetic solenoid is used to create the required magnetic field. A novel electrical supply permits to quickly vary the magnetic field, leading to rapid variation of the acceleration forces applied to oxygen. These variations can be made from overcompensation of gravity (−0.5g) to zero gravity or from zero gravity to reduced gravity (0.4g) with a time constant of 340 ms. This time is typical of the cutoff or reignition of spacecraft engines. Preliminary results on the transient flows induced by these acceleration variations in a reservoir filled with liquid and gaseous oxygen are presented.     

Fully Automatic Visualisation of Overlapping Sets

Visualisation of taxonomies and sets has recently become an active area of research. Many application fields now require more than a strict classification of elements into a hierarchy tree. Euler diagrams, one of the most natural ways of depicting intersecting sets, may provide a solution to these problems.
In this paper, we present an approach for the automatic generation of Euler-like diagrams. This algorithm differs from previous approaches in that it has no undrawable instances of input, allowing it to be used in systems where the output is always required. We also improve the readability of Euler diagrams through the use of Bézier curves and transparent coloured textures. Our approach has been implemented using the Tulip platform. Both the source and executable program used to generate the results are freely available.     

Catalytic properties of dendron–OMS hybrids

The synthesis and catalytic testing of several dendron–ordered mesoporous silica hybrids are reported. These materials are active in both the nitroaldol (Henry) reaction and the transesterification of glyceryl tributyrate to afford methyl esters. In both reactions it is observed that dendrons terminated with primary amines are more catalytically active than samples containing dendrons terminated with secondary amines. On a mmol nitrogen per gram of silica basis, the first generation dendrons are the most active for both chemistries, and the SBA-15 samples display a higher activity than the MCM-41 samples. The pore-size effect observed is consistent with significant diffusion resistance in the MCM-41 samples. The activity trend observed in the SBA-15 materials is consistent with decreased cooperative effects between the amines and surface silanols as the dendrons become larger. Clear trends are observed indicating that higher generation dendrons are more selective to alcohol formation in the Henry reaction. The dendron catalysts are much more active and stable than simple amines attached to silica in the transesterification of triglycerides. Preliminary results shown indicate that these materials can also catalyze more demanding chemistries, an example of which is the Aldol condensation of 5-(hydroxymethyl)furfural and acetone. The results shown indicate that dendron–OMS hybrids can serve as effective solid base catalysts for a diverse range of chemistries.     

Next-generation tools for evolutionary invasion analyses

Evolutionary invasion analysis is a powerful technique for modelling in evolutionary biology. The general approach is to derive an expression for the growth rate of a mutant allele encoding some novel phenotype, and then to use this expression to predict long-term evolutionary outcomes. Mathematically, such ‘invasion fitness’ expressions are most often derived using standard linear stability analyses from dynamical systems theory. Interestingly, there is a mathematically equivalent approach to such stability analyses that is often employed in mathematical epidemiology, and that is based on so-called ‘next-generation’ matrices. Although this next-generation matrix approach has sometimes also been used in evolutionary invasion analyses, it is not yet common in this area despite the fact that it can sometimes greatly simplify calculations. The aim of this article is to bring the approach to a wider evolutionary audience in two ways. First, we review the next-generation matrix approach and provide a novel, and easily intuited, interpretation of how this approach relates to more standard techniques. Second, we illustrate next-generation methods in evolutionary invasion analysis through a series of informative examples. Although focusing primarily on evolutionary invasion analysis, we provide several insights that apply to biological modelling in general.