直流微电网的储-荷虚拟直流电机优化控制技术

为提升虚拟直流电机（VDCM）控制对直流微电网的电压惯性与阻尼支持能力,并改善负荷侧的电压响应,提出了储-荷VDCM优化控制技术。通过类比直流电机的外特性建立储能侧和负荷侧VDCM动态模型。对VDCM控制进行改进,在储能侧对系统提供惯性支持,在负荷侧对系统施加阻尼控制,从而消除储能侧VDCM中电压惯性和阻尼的冲突,为系统母线提供足够的动态支撑。在此基础上,设计负荷侧惯性灵敏度控制环节,使储-荷VDCM能够为负荷提供灵活可控的电压惯性。根据李雅普诺夫稳定理论,分析所提VDCM优化控制对系统的稳定支持作用,根据分析提出参数优化方案,并利用时域仿真分析,验证所提控制策略的有效性。     

基于模型预测控制的配电网单相接地故障有源消弧

针对配电网非有效接地系统长期存在单相接地故障消弧的难题,现多采用附加有源补偿和消弧线圈相结合的方案对接地故障电弧进行抑制,而有源补偿系统的控制策略的性能直接决定了消弧的性能,本文设计了一种基于预测控制的有源消弧的实现方案,分析了采用注入电流方式的有源消弧的原理,采用三级联多电平H桥的有源补偿的拓扑,优选了代价函数,设计了基于预测控制的有源电流消弧闭环控制系统方案。该方案较PI控制策略的有源电流消弧闭环控制系统具有无需进行参数整定,即能实现对多次谐波电流的精确追踪,能进一步实现对接地电流的有效补偿。仿真分析以及实验验证均表明：本文所提的方案能够更加有效的抑制接地故障电流,满足不同场景下可靠消弧的要求     

基于新型掺钪氮化铝的级联马赫-曾德尔结构(解)复用器

在新型掺钪(Sc)氮化铝(Al1-xScxN)集成光学平台上设计了插入损耗低、传输通道谱线平坦的O波段四通道波分(解)复用器,并提出了优化方法。所设计的器件结构基于级联马赫-曾德尔干涉仪(MZI)滤波器,结合弯曲波导结构的定向耦合器改善波长敏感度。针对粗波分复用(CWDM)应用的特性,文章使用粒子群算法(PSO)提升器件性能优化的效率,通过调整器件结构的设计参数对四路通道的传输谱线质量进行优化。针对0%,9%,23%的掺Sc浓度,设计的解复用器表现出宽达约15.6nm的1-dB带宽和小于0.1dB的插入损耗,传输谱线呈“盒状”响应,各通道间串扰均优于-30.6dB。     

基于GNSS多通道跟踪接收机的阵列反欺骗方法

近年来,基于阵列天线的空域处理方法被认为是最有效的欺骗检测和抑制手段之一。提出了一种基于卫星导航接收机多通道跟踪能力的阵列反欺骗方法。多通道跟踪接收机对每一个捕获到的导航信号在所有阵元通道后均进行跟踪处理并提取信号幅度和载波相位观测量,首先计算载波相位双差平方和进行欺骗检测,然后利用载波相位单差和信号幅度比估计信号导引矢量,从而进行基于子空间投影的欺骗信号抑制或基于波束形成的真实卫星信噪比提升。理论分析和仿真试验证明,该方法可有效检测并消除同一来向的欺骗信号且不影响真实卫星信号质量。由于前端非理想因素带来的幅度和相位偏移都已包含在接收机跟踪通道提取的观测量内,实际应用时对阵列天线校准和射频通道均衡的要求明显降低。     

基于特征因素选取的IVMD-GLSSVM光伏出力短期预测

针对短期光伏发电功率预测输入特征数据冗余,抗干扰能力差,预测精度受限等问题,提出了基于特征因素选取的IVMD-GLSSVM短期光伏出力预测模型。首先利用GRA-KCC对影响特征因素进行分析,提取影响光伏发电功率的极相关特征因素,随后采用IVMD对光伏发电数据进行分解,降低数据非线性和波动性对预测精度的影响。然后将各模态分量分别输入GLSSVM预测模型进行预测,求得的各子序列预测结果叠加即为最终预测结果。最后在 MATLAB中对该预测模型及其他模型进行算例验证和误差分析,结果表明采用所提预测模型抗干扰能力强,预测精度高。     

基于改进ICP的复杂机械零件测量点云配准方法

点云配准是基于机器视觉进行复杂机械零件三维非接触精密测量的关键环节。针对传统迭代最近点(iterative closest point, ICP)算法对初始位置依赖性强,迭代收敛速度慢,错误对应点对多,难以满足大批量复杂机械零件测量点云配准效率和精度要求的问题,提出了一种基于ISS-FPFH(intrinsic shape signature-fast point feature histogram)特征结合改进ICP的复杂机械零件测量点云配准方法。为了减少点云配准数量,并保留点云表面原来的细微特征,提出了基于重心邻近点的体素滤波器对点云进行下采样预处理。为解决传统ICP算法因合适初始位置难以确定而导致多视角测量点云配准失败的问题,采用了基于ISS-FPFH特征的采样一致性初始配准(sample consensus intial alignment, SAC-IA)算法进行粗配准。为解决传统ICP算法迭代收敛速度慢、错误对应点对多的问题,提出结合法向量夹角约束的点到平面ICP算法进行精配准。以斯坦福大学的bunny点云模型为对象,验证了本文提出方法对噪声点云的鲁棒性。以常见的复杂机械零...     

Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.     

Incombustible Polymer Electrolyte Boosting Safety of Solid-State Lithium Batteries: A Review

Lithium-ion batteries with their portability, high energy density, and reusability are frequently used in today's world. Under extreme conditions, lithium-ion batteries leak, burn, and even explode. Therefore, improving the safety of lithium-ion batteries has become a focus of attention. Researchers believe using a solid electrolyte instead of a liquid one can solve the lithium battery safety issue. Due to the low price, good processability and high safety of the solid polymer electrolytes, increasing attention have been paid to them. However, polymer electrolytes can also decompose and burn under extreme conditions. Moreover, lithium dendrites are formed continuously due to the uneven charge distribution on the surface of the lithium metal anode. A short circuit caused by a lithium dendrite can cause the battery to thermal runaway. As a result, the safety of polymer solid-state batteries remains a challenge. In this review, the thermal runaway mechanism of the batteries is summarized, and the batteries abuse test standard is introduced. In addition, the recent works on the high-safety polymer electrolytes and the solution strategies of lithium anode problems in polymer batteries are reviewed. Finally, the development direction of safe polymer solid lithium batteries is prospected.     

Optical Design of Silica Aerogels for On-Demand Thermal Management

Silica aerogels, a type of porous material featuring extra low density and thermal conductivity, have drawn increasing interest from both academia and industry owing to their excellent thermal insulation performance. However, thermal insulation is always the single consideration when silica aerogels are used for thermal management. In this study, the on-demand thermal management (ODTM) of silica aerogel with either passive thermal insulation, passive heating, or passive cooling in different environments is revealed. The ODTM behavior of silica aerogels can be simply fulfilled through their optical property variations such as solar light transparency and infrared emissivity, which are controllable via the microstructures of the building blocks and surface composition design. Robust solar heating of 25 °C higher than the ambient in the daytime and sub-ambient cooling of 7 °C at night is achieved with the traditional transparent silica aerogel. Interestingly, sub-ambient cooling of 5 °C in the daytime and a warmer state on cold nights is achieved by modifying its solar transmittance and infrared emissivity. This study guides a comprehensive understanding of the thermal management behavior of silica aerogels and leads to ODTM applications of silica aerogels by tailoring their optical and thermal conductivity properties.     

Amine Coordinated Electron-Rich Palladium Nanoparticles for Electrochemical Hydrogenation of Benzaldehyde

Electrocatalytic hydrogenation (ECH) is a burgeoning strategy for the sustainable utilization of hydrogen. However, how to effectively suppress the competitive hydrogen evolution reaction (HER) is a big challenge to ECH catalysis. In this study, amine (NH₂ R)-coordinated Pd nanoparticles loaded on carbon felt (Pd@CF) as a catalyst is successfully synthesized by a one-step solvothermal reduction method using oleylamine as the reducing agent. An exceptional ECH reactivity on benzaldehyde is achieved on the optimal Pd@CF catalyst in terms of a high conversion (89.7%) and selectivity toward benzyl alcohol (89.8%) at −0.4 V in 60 min. Notably, the Faradaic efficiency for producing benzyl alcohol is up to 90.2%, much higher than that catalyzed by Pd@CF-without N-group (41.1%) and thecommercial Pd/C (20.9%). The excellent ECH performance of Pd@CF can be attributed to the enriched electrons on Pd surface resulted from the introduction of NH₂ R groups, which strengthens both the adsorption of benzaldehyde and the adsorbed hydrogen (H_ads) on Pd, preventing the combination of H_ads to form H₂, that is, inhibiting the HER. This study gives a new insight into design principles of highly efficient electrocatalysts for the hydrogenation of unsaturated aldehydes molecules.