Reduction of percolation threshold of multiwall carbon nanotube (MWCNT) in polystyrene (PS)/low‐density polyethylene (LDPE)/MWCNT nanocomposites: An eco‐friendly approach

In this article, we introduce an eco‐friendly approach to achieve electrical conductivity at sufficiently lower loading of MWCNT in the PS/LDPE/MWCNT nanocomposites through judicious control of temperature during melt blending. The percolation threshold was achieved at 0.21 wt% of MWCNT following this method, which is lower, compared to the result obtained from direct mixing as well as the previously reported data. The morphological analysis revealed a co‐continuous structure of the (70/30, PS/LDPE)/MWCNT nanocomposites in such a high asymmetric composition of blend constituents, which facilitates in the lowering of percolation threshold through selective dispersion of MWCNT in the minor LDPE phase. The electron conduction in the nanocomposites has well been explained in terms of tunneling mechanism, supporting thin coating of polymer over individual CNTs. The morphological, electric and dielectric properties have been well explained in this article. POLYM. COMPOS., 36:1574–1583, 2015. © 2014 Society of Plastics Engineers     

Capillary forces between sediment particles and an air-water interface

In the vadose zone, air-water interfaces play an important role in particle fate and transport, as particles can attach to the air-water interfaces by action of capillary forces. This attachment can either retard or enhance the movement of particles, depending on whether the air-water interfaces are stationary or mobile. Here we use three standard PTFE particles (sphere, circular cylinder, and tent) and seven natural mineral particles (basalt, granite, hematite, magnetite, mica, milky quartz, and clear quartz) to quantify the capillary forces between an air-water interface and the different particles. Capillary forces were determined experimentally using tensiometry, and theoretically assuming volume-equivalent spherical, ellipsoidal, and circular cylinder shapes. We experimentally distinguished between the maximum capillary force and the snap-off force when the air-water interface detaches from the particle. Theoretical and experimental values of capillary forces were of similar order of magnitude. The sphere gave the smallest theoretical capillary force, and the circular cylinder had the largest force due to pinning of the air-water interface. Pinning was less pronounced for natural particles when compared to the circular cylinder. Ellipsoids gave the best agreement with measured forces, suggesting that this shape can provide a reasonable estimation of capillary forces for many natural particles.     

Effect of steam environment on severe core damage behaviour for VVER-1000 with the ASTEC V1 code

Severe accident studies for very low frequency events for VVER-1000 (V320) are carried out to estimate in-vessel damage progression under steam-rich and starved conditions. The analyses with code ASTEC, jointly developed by IRSN (France) and GRS, Germany), have shown the influence of steam environment on core heat-up followed by material relocation, hydrogen production, vessel failure and aerosol generation along with release to containment. Hydro-accumulator injection for studied transients also gives rise to a steam-rich environment enhancing the material oxidation depending on the injection time and period. The generated information along with PSA-Level 2 is helpful to decide Plant Damage State (PDS) and fruitfully develop accident management strategies for the plant.     

Conjugate Heat Transfer Analysis for a Finite Thickness Cylinder in a Hypersonic Flow

Prediction of surface heating rates is of prime importance for the hypersonic flow regime. Experimental and conventional computational efforts overlook the heat transfer phenomenon in the solid due to the rigid assumptions involved in the solution methodologies. In order to address this fact, conjugate heat transfer (CHT) studies are carried out using various coupling techniques to examine their implementation abilities. Three types of solution methodologies are adopted, namely, decoupled, strongly coupled, and loosely coupled analysis. This study is also focused on looking into the effect of a hypersonic flow field on wall heat flux for a finite thickness insulating cylinder at moderately large time scales. Increase in wall temperature and decrease in surface heat flux have been noticed using strong and loose coupling techniques with an increase in simulation time. Decoupled fluid and solid domain analysis is found to be useful for typical shock tunnel test durations (～1 ms) while investigations with loose coupling techniques are advisable for time scales corresponding to flight testing (～1 s). Efforts are also made to reason the discrimination in prediction of stagnation point heat flux using conventional computational and experimental analysis.     

Simultaneous Estimation of Properties in a Combined Mode Conduction–Radiation Heat Transfer in a Porous Medium

Simultaneous estimation of thermophysical and optical properties such as the thermal conductivity, the scattering albedo, and the emissivity of a 1‐D planar porous matrix involving combined mode conduction and radiation heat transfer with heat generation is reported. Coupled energy equations for the gas and solid phase account for the nonlocal thermal equilibrium between the two phases. Performances of the genetic algorithm (GA) and the global search algorithm (GSA) in simultaneous estimation of three properties are analyzed. Both the GA and the GSA utilize a priori knowledge of the axial gas temperature distribution, and the magnitudes of the convective and the radiative heat fluxes at the outer surface of the porous matrix. With volumetric radiative information needed in the solid‐phase energy equation computed using the discrete transfer method, the two energy equations are simultaneously solved using the finite volume method. GSA provides better estimation, and computationally, it is much faster than the GA.     

Thermoelectric cold-chain chests for storing/transporting vaccines in remote regions

The cold chain is one of the key elements of the preventive health-care delivery system. Vaccines have to be carried long distances, stored in remote places and during this period the temperature has to be maintained within certain specified values. Realizing the needs of such requirements, the Department of Science & Technology, New Delhi (Govt. of India) assigned a project to the R&D Division of MECON, Ranchi for development of Thermoelectric Cold-Chain Chest operated by 12 V DC vehicular battery. The resulting portable thermoelectric (i.e. Peltier effect) Cold-Chain Chest (TCC) operated successfully even in an ambient environment of 45 °C, mainly for preserving and transporting life-saving medicines for urban as well as rural areas.     

Synthesis of Flexible Graphene/Polymer Composites for Supercapacitor Applications

In this paper, the graphene was synthesized using biocompatible cellulosic component from onions. Onion epidermal cells were chosen as raw material. During heating at high temperature, the bonding among atoms in material was rearranged and forms two-dimensional hexagonal carbon layer (graphene). The characterization of synthesized graphene was done by x-ray diffractometer, Raman spectrometer and field emission scanning electron microscopy, respectively. An attempt has been taken to form the capacitors with two different current collector electrodes, anticipating the performance of the supercapacitors. The observed capacitance values as-obtained for Al and Au current collector were 1.3 μF and 6.08 μF, respectively. However, when thermally exfoliated graphene was used as an electrode on Al and Au current collector, the capacitance value was drastically increased and found to be 1.6 and 41.25 μF, respectively.     

Analytic solution for planar indeterminate impact problems using an energy constraint

This work proposes an analytic method for resolving planar multi-point indeterminate impact problems for rigid-body systems. An event-based approach is used to detect impact events, and constraints consistent with the rigid-body assumption are used to resolve the indeterminacy associated with multi-point impact analysis. The work-energy relation is utilized to determine post-impact velocities based on an energetic coefficient of restitution to model energy dissipation, thereby yielding an energetically consistent set of post-impact velocities based on Stronge’s energetic coefficient of restitution for the treatment of rigid impacts. The effect of stick–slip transition is analyzed based on Coulomb friction. This paper also discusses the transition from impact to contact. This analysis is essential for considering the rocking block problem that is used as an example herein. The predictions of the model for the rocking block problem are compared to experimental results published in the literature. An example of a planar ball undergoing two-point impact is also presented.     

Intermetallic Precipitation in Low-Density Steel

Metallurgical and Materials Transactions A - Low-density steels (LDS) represent a relatively new class of material that contains a large concentration of aluminum. In the present work, we studied...     

Design of Smart Door Closer System with Image Classification over WLAN

Wireless Personal Communications - A dual purpose system is presented in this paper which serves not only as a door closer, but is equally effective for surveillance purposes. The currently...