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排序方式: 共有2212条查询结果,搜索用时 31 毫秒
41.
42.
Zhenya Wang Hao Guo De Ning Xiaobai Ma Lirong Zheng Dmitry Smirnov Kai Sun Dongfeng Chen Limei Sun Xiangfeng Liu 《Journal of the American Ceramic Society》2021,104(11):5934-5945
Li4Ti5O12 (LTO) attracts great interest due to the “zero strain” during cycles but the poor electronic and ionic conductivity critically impede the practical application. Herein, we report a synergy strategy of tuning localized electrons to shift Fermi level and band gap by Mg/Zr co-doping and oxygen vacancy incorporation, which significantly improves Li+ and electronic transport. More importantly, the intrinsic synergistic mechanism has been revealed by neutron diffraction, X-ray absorption spectra, and first-principles calculations. The “elastic effect” of lattice induced by Mg/Zr co-doping allows LTO to accommodate more oxygen vacancies to a certain degree without a severe lattice distortion, which largely improves the electronic conductivity. Mg/Zr co-doping and oxygen vacancy incorporation effectively enhanced the dynamic characteristics of LTO electrode, achieving the excellent rate performance (90 mAh/g at 20C) and cycle stability (96.9% after 500 cycles at 10C). First-principles calculations confirm Fermi level shifts to the conduction band, and the band gap becomes narrowed due to the synergistic modulation, and the intrinsic mechanism of the enhanced electronic and Li-ion conductivity is clarified. This study offers some insights into achieving the fast Li+ insertion/extraction by tuning the crystal and electronic structure with lattice doping and oxygen vacancy engineering. 相似文献
43.
Agroskin V. Ya. Bravyi B. G. Vasil’ev G. K. Gur’ev V. I. Kashtanov S. A. Makarov E. F. Sotnichenko S. A. Chernyshev Yu. A. 《Combustion, Explosion, and Shock Waves》2021,57(2):138-149
Combustion, Explosion, and Shock Waves - The ignition of methane–air mixtures with additives of ClF5, ClF3, OF2, and H2O2 (additive content in the mixtures $$\le$$ 1%) is studied by... 相似文献
44.
Fibre Chemistry - Traditionally, prediction of functioning processes of uniaxially oriented polymeric materials faces objective difficulties due to inhomogeneity of the rheological structure of... 相似文献
45.
Fibre Chemistry - Results are given for a study and modelling of short-term creep of polypropylene and polyvinylidene fluoride threads designed for medical purposes. A physical analysis is given... 相似文献
46.
Dmitry V. Orekhov Oleg A. Kazantsev Sergey V. Orekhov Alexey P. Sivokhin Denis M. Kamorin Alexander S. Simagin Maria V. Savinova Evgeniya A. Bolshakova Michail S. Korotaev 《应用聚合物科学杂志》2021,138(38):50982
Thermoresponsive PEG-based (PEG stands polyethylene glycol) polymers are unique for use in medicine because of their low toxicity, good biocompatibility and biodegradability, but usually more hydrophobic and more toxic comonomers are used to adjust lower critical solution temperature (LCST). A convenient way to overcome this problem and to finely tune LCST is to use alkoxy oligo(ethylene glycol)- or alkoxy oligo(propylene glycol) (meth)acrylates as starting comonomers. Here we report on the conditions for the simple and affordable synthesis of methoxy oligo(propylene glycol) (meth)acrylate- and methoxy oligo(propylene glycol)-block-oligo(ethylene glycol) (meth)acrylate-based macromonomers with high yields (80%–98.7%) by the acid-catalyzed esterification of (meth)acrylic acid with alkoxy oligo(alkylene glycols) containing oligo(ethylene glycol) (OEG) and/or oligo(propylene glycol) (OPG) blocks. p-Toluene sulphonic acid (pTSA), alkyl(C12–C14)benzene sulfonic acid (ABSA) and H2SO4 were used as catalysts. It has been shown that pTSA and ABSA are practically the same in catalytic activity and are superior to sulfuric acid. The reaction orders with respect to catalyst was found to be close to 1 in all cases. It has been shown that the reaction is actually insensitive to the lengths of OEG and OPG blocks, as well as to the structure of the terminal alkyl group, while the esterification of acrylic acid (AA) proceeds much faster compared to methacrylic acid (MAA) one under the same conditions. The influence of temperature on the equilibrium conversions of alcohols was determined, which were found to be 89%–93% for the esterification of AA and 61%–86% for MAA in the temperature range of 60–120°C. A further increase in conversion was achieved by introducing an azeotropic agent (toluene), its optimal concentration was found to be 10%–15%. 相似文献
47.
A. V. Makarov R. A. Savrai V. M. Schastlivtsev T. I. Tabatchikova L. Yu. Egorova 《The Physics of Metals and Metallography》2007,104(5):522-534
The hardness and mechanical properties of the U10 steel (1.03 wt % C) with pearlite structures that were formed by isothermal decomposition at temperatures of 650°C (coarse-lamellar pearlite) and 500°C (fine-lamellar pearlite) as well as upon subsequent annealing of fine-lamellar pearlite at a temperature of 650°C for 10–300 min have been studied upon tensile tests. Fractures of the steel with different types of pearlite structure have been examined using scanning electron microscopy. The interrelation between the mechanical properties and the structural features and character of fracture has been analyzed for this steel with pearlite structures differing in the dispersity, morphology, and defect structure of cementite, and in the levels of solid-solution strengthening and microdistortions of the ferrite-constituent lattice. 相似文献
48.
We report operation and characterization of a lab-assembled single-photon detector based on commercial silicon avalanche photodiodes (PerkinElmer C30902SH, C30921SH). Dark count rate as low as 5 Hz was achieved by cooling the photodiodes down to -80 °C. While afterpulsing increased as the photodiode temperature was decreased, total afterpulse probability did not become significant due to detector's relatively long deadtime in a passively-quenched scheme. We measured photon detection efficiency >50% at 806 nm. 相似文献
49.
50.
Composite Materials Based on Shape‐Memory Ti2NiCu Alloy for Frontier Micro‐ and Nanomechanical Applications 下载免费PDF全文