Focused ion beam (FIB) etching to investigate aluminium-coated polymer laminates subjected to heat and moisture loads

Multilayered aluminium-coated polymer laminates are the common barrier envelopes of vacuum insulation panels used as high performance thermal insulation in building applications. These laminates are made of up to ten distinct layers including three aluminium barrier layers applied by vacuum web coating. During their expected lifetime, which is required to last longer than 20 years, they will be subjected to heat and moisture loads induced by internal and external climatic conditions. This paper investigates the deteriorations of the barrier function of two different laminates commonly used for the production of vacuum insulation panels. These were subjected to well defined exterior heat and moisture loads and investigated by means of focused ion beam etching. Delamination of the polyurethane adhesive layers and stress induced relaxation in them are made visible. Oxidised aluminium layers are also detected by this method.     

嵌入式系统专家部落格(ind River Blog) BMW寻求迈向开放之路

Eclipse Foundation行销总监lan Skerrett在MotorAuthority,com表示,BMW正在探寻市场,看看主流制造商是否有兴趣为车用娱乐信息系统开发一个开放来源堆栈.     

A Software Package for Design and Manufacture of Prosthetic Sockets for Transtibial Amputees

A software package, written in Pascal, whkh automates the shape management process associated with fitting prosthetic sockets to transtibial (below-knee) amputees, is described. The system allows an operator to apply global and piecewise transformations, based upon clinkal measurements, to a primitive socket database. These transformations yield a modified socket database which defines the surface shape of a positive socket mold over which an amputee's prosthetic socket is formed. The mold is replicated using a computer numerkally controled milling machine, with the final socket being formed over this mold by a specialized vacuum former. Preliminary clinical trials indkate that this automated approach to shape management yields comfortable prostheses, with savings in time and cost over the traditional methods of prosthesis manufacture.     

Polypropylene-graphite nanocomposites made by solid-state shear pulverization: Effects of significantly exfoliated, unmodified graphite content on physical, mechanical and electrical properties

Nanocomposites made from polypropylene and as-received graphite were prepared by solid-state shear pulverization (SSSP) as a function of graphite loading (0.3-8.4 wt%). X-ray diffraction indicates that SSSP employing harsh pulverization conditions yields substantial graphite exfoliation at 0.3-2.7 wt% graphite content with less exfoliation being achieved at higher graphite content. With increasing graphite content, thermal degradation temperature and non-isothermal onset crystallization temperature increase substantially (by as much as 35 and 23 °C relative to neat polypropylene) while isothermal crystallization half-time decreases dramatically. In contrast, Young’s modulus and tensile yield strength exhibit maxima (∼100% and ∼60% increases, respectively, relative to neat polypropylene) at 2.7 wt% graphite content, with all nanocomposites retaining high elongation at break values except at the highest filler loading. Electrical conductivity measurements indicate percolation of graphite at 2.7 wt% and higher graphite content, consistent with rheology measurements showing the presence of a solid-like response of melt-state shear storage modulus as a function of frequency. Significant tunability of graphite exfoliation and property enhancements is demonstrated as a function of SSSP processing.     

Gas transport through ceramic membranes under super-critical conditions

In order to select and to apply a porous membrane under supercritical conditions, it is necessary to understand the transport mechanism affecting the permeation behaviour.This paper describes the investigation of gas transport through micro porous ceramic membranes consisting of several layers. The separation layer is made from TiO² with a nominal pore size diameter of 0.9 nm. Single gas permeation of helium, nitrogen, argon, methane, and carbon dioxide was measured in the temperature range of 293-443 K and in the pressure range of 1-10 MPa.Observation of the permeability of these membranes revealed that the transport of non?adsorbing gases under these conditions is governed by Knudsen diffusion and viscous flow.     

Conductive Anodic Filament Formation Part II: Electrochemical Reactions Leading to CAF

Conductive anodic filament (CAF) formation has been studied for a number of years, but the mechanism of its formation has not previously been defined. In 2002, Ready identified CAF as atacamite, Cu₂(OH)₃Cl. Electrochemical studies have shown that both CuCl and CuCl ₂ ^? participate in the formation of Cu₂(OH)₃Cl, with the predominating species being CuCl. This paper proposes a mechanism for CAF formation based on x-ray photoelectron spectroscopy. The data show that CuCl is the precursor to the formation of Cu₂(OH)₃Cl in the presence of oxygen and water. Earlier, Meeker and Lu Valle had proposed that CAF failure is best represented by two competing reactions: the formation of a copper chloride corrosion compound (now identified as Cu₂(OH)₃Cl) and the formation of innocuous trapped chlorine compounds. Since no evidence of any trapped chloride compounds has been found, we propose that the formation of CAF is best represented by a single nonreversible reaction.     

Regelungstechnik für die Schnittholztrocknung heute

After explaining the requirements which must be fulfilled by modern microprocessor- or computer-operated control units for kiln dryers, four control methods are compared. Concerning these methods, the initial moisture content of the wood as well as the constantly changing moisture content play very different roles depending on whether it is above, below or within the so-called range of fibre saturation of the wood. The most highly developed method No. IV includes the distribution of moisture content over the cross section of the board as a comparative figure in the control data processed by the computer, with the aim of optimizing the drying time and guaranteeing a high drying quality.     

The Changing Role Of The City Centre In Adelaide And Melbourne

It is not too often that sufficient similarities and comparable data enable us to make significant comparisons between the central areas of Australian capital cities. This article presents such material about Adelaide and Melbourne. In particular, it takes advantage of floorspace and employment surveys carried out in these central areas in 1987 and 1992 to identify not only trends but important points of similarity and difference. Some of the more important reasons for these changes are canvassed in the context of current literature. The different policy responses of the two state governments and central city authorities are also examined as there has been a change in both cities to a state Liberal government following Labor governments which have incurred heavy financial losses and increased state debt.     

The investigation of basic processes of rapidly hardening wood-cement-water mixture with CO2

The rapid hardening of wood-cement-water mixture in a carbon dioxide enriched environment was investigated, by studying the development of carbonation degree and monitoring the phase changes in the mixture. The carbonation reaction was a diffusion-controlled process. It occurred very quickly in the first two minutes of reaction. After that, its rate decreased drastically, due to the increasing difficulty of transporting reactants to reaction sites. Jander’s model was found ineffective in predicting the carbonation process. However, its modified version, developed by Kroger and Ziegler, could describe this progress accurately. In addition, the rapid hardening appeared to result mainly from the reactions of calcium silicates in cement with carbon dioxide. The reaction between ettringite and carbon dioxide might also contribute to this rapid hardening process. However, the reaction between calcium hydroxide and carbon dioxide was not confirmed.