An exergetic analysis of a membrane desalination system

In this paper, the exergetic analysis of a seawater membrane-based desalination plant has been carried out. The desalination plant has been described in detail, then the exergy of the various saline water streams has been determined and a comprehensive analysis towards the exergy distribution of the major process components has been conducted. The examination of the exergy losses throughout the plant revealed that exergy destruction was mainly due to pressure drops in the membrane modules, valves and brine lines. Moreover, 12.9% of the exergy input to the system was supplied by the heater. Therefore, the most reasonable way to reduce power input to the plant, thus improving its performance and cost, has been shown (i) to be replacing the valves on the reverse osmosis brine stream by an energy recovery system, and (ii) to have thermal energy available in the plant. With the identified technical changes, energy consumption decreased from 18.3 to 2.05 kWh/m³, resulting in an annual saving of 0.17$/m³.     

Nanostructured TiO2-based mixed metal oxides prepared using microemulsions for carbon monoxide detection

Nanostructured powders of Nb-doped TiO₂ (TN) and SnO₂ mixed with Nb-doped TiO₂ in two different atomic ratios—10 to 1 (TSN 101) and 1 to 1 (TSN 11)—were synthesized using the reverse micelle microemulsion of a nonionic surfactant (brine solution/1-hexanol/Triton X-100/cyclohexane). The powders were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). Thick films were fabricated for gas sensors and characterized by XRD analysis and field emission scanning electron microscopy (FE-SEM). The effects of the film morphology and firing temperature in the range 650–850 °C on CO sensitivity were studied. The best gas response, expressed as the ratio between the resistance in air and the resistance under gas exposure (R _air/R _gas), was measured for TSN 11 at 11 for 1,000 ppm CO exposure. All types of sensors showed good thermal stability. The electrochemical impedance spectroscopy (EIS) measurements were performed in different gas atmospheres (air, O₂, CO and NO₂) to better understand the electrical properties of the nanostructured mixed metal oxides.     

Residual Stresses in Alumina/Zirconia Composites: Effect of Cooling Rate and Grain Size

Alumina/zirconia composites with various compositions at the zirconia-rich part of the phase diagram have been prepared with various grain sizes of the starting alumina powders. After firing under identical conditions, the pellets have been cooled systematically, changing the cooling rates from 0.5 to 8000 K/min. Subsequently, the residual stresses in alumina have been determined by monitoring the frequency shifts of the R ₂ luminescence line of alumina (14 430 cm⁻¹). The data indicate that the stress in alumina is compressive in all cases, with increasing absolute values of the stress with decreasing alumina content. Within the same composition, the residual stress as a function of the cooling rate presents a minimum for values between 10 and 100 K/min, with no clear dependence on the alumina or zirconia grain size. An interpretation of the experimental data in terms of a Coble-type diffusional relaxation applies for intermediate cooling rates (from 10 to 800 K/min), but it fails to account for the large stresses at low cooling rates. The width of the stress distribution is narrow (∼150 MPa) and constant for all compositions and grain sizes at low cooling rates, but it increases for cooling rates >10 K/min, depending on the grain size but not on the composition. For fast cooling rates, a correlation is found when reporting the average width of the stress distribution as function of the average sintered grain-size distribution of alumina. Overall, zirconia grain size seems to influence the average stress, whereas alumina grain size determines the stress distribution.     

Crystallisation of high density polyethylene from dilute solution: Heterogeneous nucleation

The self-seeding crystallisation technique is applied to a dilute solution of polyethylene in xylene containing, in suspension, foreign particles; data concerning some pigments usually employed for colouring the plastics are reported. It is shown that this method allows easy demonstration of the interactions existing between the dissolved polymer and the pigment; at the same time, it is possible to study the morphology which is evolved as a consequence of these interactions under particularly simple conditions as only a small amount of polymer crystallises on the pigment particles. The behaviour of several pigments is consistent with the results obtained by crystallising the bulk polyethylene coloured with the same pigments. Some unusual morphologies are made evident.     

Mode II intersonic crack propagation in poroelastic media

A crack is steadily running in an elastic isotropic fluid-saturated porous solid at an intersonic constant speed c. The crack tip speeds of interest are bounded below by the slower between the slow longitudinal wave-speed and the shear wave-speed, and above by the fast longitudinal wave-speed. Biot’s theory of poroelasticity with inertia forces governs the motion of the mixture. The poroelastic moduli depend on the porosity, and the complete range of porosities n ∈ [0, 1] is investigated. Solids are obtained as the limit case n = 0, and the continuity of the energy release rate as the porosity vanishes is addressed. Three characteristic regions in the plane (n, c) are delineated, depending on the relative order of the body wave-speeds. Mode II loading conditions are considered, with a permeable crack surface. Cracks with and without process zones are envisaged. In each region, the analytical solution to a Riemann–Hilbert problem provides the stress, pore pressure and velocity fields near the tip of the crack. For subsonic propagation, the asymptotic crack tip fields are known to be continuous in the body [Loret and Radi (2001) J Mech Phys Solids 49(5):995–1020]. In contrast, for intersonic crack propagation without a process zone, the asymptotic stress and pore pressure might display a discontinuity across two or four symmetric rays emanating from the moving crack tip. Under Mode II loading condition, the singularity exponent for energetically admissible tip speeds turns out to be weaker than 1/2, except at a special point and along special curves of the (n, c)-plane. The introduction of a finite length process zone is required so that 1. the energy release rate at the crack tip is strictly positive and finite; 2. the relative sliding of the crack surfaces has the same direction as the applied loading. The presence of the process zone is shown to wipe out possible first order discontinuities.     

A support vector machine integrated system for the classification of operation anomalies in nuclear components and systems

A support vector machine (SVM) approach to the classification of transients in nuclear power plants is presented. SVM is a machine-learning algorithm that has been successfully used in pattern recognition for cluster analysis. In the present work, single- and multiclass SVM are combined into a hierarchical structure for distinguishing among transients in nuclear systems on the basis of measured data. An example of application of the approach is presented with respect to the classification of anomalies and malfunctions occurring in the feedwater system of a boiling water reactor. The data used in the example are provided by the HAMBO simulator of the Halden Reactor Project.     

Market-based control of computational systems: introduction to the special issue

We introduce the Special Issue of the journal on the topic of Market-Based Control of Computational Systems. The special issue collects six peer-reviewed papers arising from an International Workshop on the topic held in Liverpool, UK, in September 2008.     

What the 2007 TAC Market Design Game tells us about effective auction mechanisms

This paper analyzes the entrants to the 2007 tac Market Design Game. We present a classification of the entries to the competition, and use this classification to compare these entries. The paper also attempts to relate market dynamics to the auction rules adopted by these entries and their adaptive strategies via a set of post-tournament experiments. Based on this analysis, the paper speculates about the design of effective auction mechanisms, both in the setting of this competition and in the more general case.