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91.
Summary The cyclopolymerization of 1,8-diethynylnaphthalene(DEN) and its copolymerization with diethyl dipropargylmalonate(DEDPM) were carried out by various transition metal catalysts. MoCl5-based catalyst was found to be very effective and gave almost a quantitative polymer yield. The resulting dark-brown homopolymer(PDEN) was partially soluble in chloroform, tetrahydrofuran, and dimethyl sulfoxide, whereas copolymer (1:1) with number avaerage molecular weight
of 2.1x104 by GPC showed good solubility in those solvents. The structure of the polymers was analysed by IR, NMR, and UV-VIS spectroscopies. From the spectral and solubility data, it is proposed that cyclized products with the conjugated system are formed. Room temperature conductivities of the I2-doped homo and copolymer were found to be about 7.5x10-3 and 5.1x10-3 S/cm, respectively. 相似文献
92.
Sung-Yong Cho Seung-Shik Park Seung-Jai Kim Tae-Young Kim 《Korean Journal of Chemical Engineering》2006,23(4):638-644
Adsorption and desorption characteristics of the 2-methyl-4-chlorophenoxyacetic acid (MCPA) from aqueous solution onto the
activated carbon (GAC, F-400) were studied. Adsorption equilibrium capacities of the MCPA increased with decreasing pH and
temperature of the solution. Adsorption equilibrium of the MCPA could be represented by the Sips equation. The internal diffusion
coefficients were determined by comparing the experimental concentration decay curves with those predicted from surface diffusion
model and pore diffusion model. The adsorption model based on the linear driving force approximation (LDFA) was used for simulating
the adsorption behavior of the MCPA in a fixed bed. Over ninety five percent desorption of the MCPA could be obtained using
distilled water. 相似文献
93.
94.
Seong-Youl Bae Du-Hyon Cho Hee-Taik Kim Hidehiro Kumazawa 《Korean Journal of Chemical Engineering》1994,11(2):127-130
Sorption equilibria and permeation rates for oxygen and carbon dioxide in polycarbonate membrane were measured at different
temperature between 30 and 60°C and at pressures up to 2.5 MPa. The pressure dependence of mean permeability coefficient to
oxygen obeyed the conventional dual-mode mobility model, whereas that to carbon dioxide followed a modified dual-mode mobility
model with concentration-dependent diffusivities, as that of polystyrene to the same gas did. 相似文献
95.
Young-Ho Lee Shin-Guk Kim Tae-Yong Kuc Jong-Koo Park Sang-Hoon Ji Yong-Seon Moon Young-Jo Cho 《International Journal of Control, Automation and Systems》2014,12(2):390-398
A virtual target tracking approach is proposed for kinematic control of mobile robot. In the controller, linear and angular velocity inputs are generated by using the local data of robot position and orientation along with the estimated velocity of target object. Applying the proposed approach to a cooperative robot group with arbitrary number of multiple mobile robots, it is possible to create various robot formations for cooperative navigation and tracking of moving object. The developed controller is shown to be stable and convergent through theoretical proof and a series of experiments. 相似文献
96.
Graft copolymerization of acrylonitrile (AN) and methyl methacrylate (MMA) onto polychloroprene (CR) was carried out using benzoyl peroxide as initiator. The effects of mole ratio of AN to MMA, reaction temperature, reaction time, solvent, and initiator concentration on the graft copolymerization were examined. It was found that the thermal stability and weatherability of the AN—CR—MMA graft copolymer (ACM) were considerably better than those of CR. 相似文献
97.
Ki Soo ParkMyung Hun Cho Sang Ho ParkKee Suk Nahm Yang Kook SunYun Sung Lee Masaki Yoshio 《Electrochimica acta》2002,47(18):2937-2942
Layered Li0.7[M1/6Mn5/6]O2 (M=Li, Ni) was synthesized using a sol-gel method. P2-Na0.7[M1/6Mn5/6]O2 precursor was first synthesized by a sol-gel method, and then O2-Li0.7[M1/6Mn5/6]O2 was prepared by an ion exchange of Li for Na in P2-Na0.7[M1/6Mn5/6]O2 precursor. From charge/discharge curves, it was seen that Li0.7[Li1/6Mn5/6]O2 has two plateaus similar to those observed from a spinel structure, but Li0.7[Ni1/6Mn5/6]O2 holds a single plateau as observed from a typical layered structure. It was considered that Li0.7[Li1/6Mn5/6]O2 undergoes a phase transformation from layered to spinel structure during the charge/discharge cycle, but Li0.7[Ni1/6Mn5/6]O2 maintains O2-layered structure after the cycles. Li0.7[Ni1/6Mn5/6]O2 was higher in discharge capacity and retention rate than Li0.7[Li1/6Mn5/6]O2. 相似文献
98.
Polymer gel electrolytes were prepared by thermal crosslinking reaction of a series of acrylic end‐capped poly(ethylene glycol) and poly(propylene glycol) [P(EG‐co‐PG)] having various geometries and molecular weights. Acrylic end‐capped prepolymers were prepared by the esterification of low molecular weight (Mn: 1900–5000) P(EG‐co‐PG) with acrylic acid. The linear increase in the ionic conductivity of polymer gel electrolyte films was observed with increasing temperature. The increase in the conductivity was also monitored by increasing the molecular weight of precursor polymer. Nanocomposite electrolytes were prepared by the addition of 5 wt % of organically modified layered silicate (montmorillonite) into the gel polymer electrolytes. The enhancement of the ionic conductivity as well as mechanical properties was observed in the nanocomposite systems. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 894–899, 2004 相似文献
99.
Acicular goethite particles were synthesized by oxidation of an alkaline suspension of ferrous hydroxide using a bubble column with draft tubes of different diameters at a constant temperature of 40°C. The oxidation rate increased with decreasing draft tube diameter. The mean size based on the major axis of acicular particle decreased with increasing oxidation rate and decreasing draft tube diameter. The major axis was found to grow preferentially compared with the minor axis. The mean size of major axis was correlated well to the modified reaction rate defined as a product of the reaction rate per unit volume of the reactor multiplied by the ratio of the column diameter to the draft tube diameter, irrespective of the draft tube diameter. 相似文献
100.
An increase in the depolymerization of chitosan was found with an increased concentration of sodium perborate. Acetic anhydride was added to reacetylated chitosan in a molar ratio per gulcosamine unit, and the amide I band of IR spectra changed with the addition of acetic anhydride. Sixteen chitosans with various molecular weights (MWs) and degrees of deacetylation (DODs) were prepared. X‐ray diffraction patterns indicated their amorphous and partially crystalline states. Increases in the chitosan MW and DOD increased the tensile strength (TS). TS of the chitosan films ranged from 22 to 61 MPa. However, the elongation (E) of chitosan films did not show any difference with MW. TS of chitosan films decreased with the reacetylation process. However, E of chitosan films was not dependent on DOD. The water vapor permeabilities (WVPs) of the chitosan films without a plasticizer were between 0.155 and 0.214 ng m/m2 s Pa. As the chitosan MW increased, the chitosan film WVP increased, but the values were not significantly different. Moreover, the WVP values were not different from low DOD to high DOD. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3476–3484, 2003 相似文献