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Kai Feng Ning Gao Wanlin Zhang Kang Zhou Hao Dong Peng Wang Li Tian Guokang He Guangtao Li 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(9)
Droplet‐based microfluidics enable the production of emulsions and microparticles with spherical shapes, but the high‐throughput fabrication of nonspherical emulsions and microparticles still remains challenging because interfacial tension plays a dominant role during preparation. Herein, ionic liquids (ILs) containing salts, which possess sufficient osmotic pressure to realize water transport and phase separation, are introduced as inner cores of oil‐in‐oil‐in‐water double emulsions and it is shown that nonspherical emulsions can be constructed by osmosis‐driven arrested coalescence of inner cores. Subsequently, ultraviolet polymerization of the nonspherical emulsions leads to nonspherical microparticles. By tailoring the number, composition, and size of inner cores as well as coalescence time, a variety of nonspherical shapes such as dumbbell, rod, spindle, snowman, tumbler, three‐pointed star, triangle, and scalene triangle are created. Importantly, benefitting from excellent solvency of ILs, this system can serve as a general platform to produce nonspherical microparticles made from different materials. Moreover, by controlling the osmotic pressure, programmed coalescence of inner cores in double emulsions is realizable, which indicates the potential to build microreactors. Thus, a simple and high‐throughput strategy to create nonspherical microparticles with arrested coalescence shapes is developed for the first time and can be further used to construct novel materials and microreactors. 相似文献
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Donglin He Ping Li Wei Wang Qi Wan Jian Zhang Kai Xi Xiumei Ma Zhiwei Liu Lin Zhang Xuanhui Qu 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(5)
Although silicon‐based materials are ideal candidate anodes for high energy density lithium‐ion batteries, the large volumetric expansion seriously damages the integrity of the electrodes and impedes commercial processes. Reasonable electrode design based on adjustable structures of silicon and strong binders prepared by a facile method is still a great challenge. Herein, a three‐pronged collaborative strategy via hollow nanocubes, amorphous Void@SiOx@C, and in situ cross‐linked polyacrylic acid and d ‐sorbitol 3D network binder (c‐PAA‐DS) is adopted to maintain structural/electrode integrality and stability. The all‐integrated c‐PAA‐DS/Void@SiOx@C electrode delivers excellent mechanical property, which is attributed to ductility of the c‐PAA‐DS binder and high adhesion energy between Void@SiOx@C and c‐PAA‐DS calculated by density functional theory. Benefiting from the synergistic effect of accommodation of the hollow structure, protection of outer carbon shell, amorphous Void@SiOx@C, and strong adhesive c‐PAA‐DS binder, c‐PAA‐DS/Void@SiOx@C shows excellent electrochemical performance. Long cycling stability with a reversible capacity of 696 mAh g?1 is obtained, as well as tiny capacity decay after 500 cycles at 0.5 A g?1 and high‐rate performance. The prelithiated Void@SiOx@C||LiNi0.5Co0.2Mn0.3O2 (NCM523) full cell is also assembled and shows a reversible capacity of 157 mAh g?1 at 0.5 C, delivering an excellent capacity retention of 94% after 160 cycles. 相似文献
107.
Fatigue failure is probably the most common type of failure in welded construction. It is usually initiates at a stress concentration area within the structure. The fatigue behavior of non-load carrying cruciform fillet welded joint has been studied extensively using boundary element method. The symmetric boundary element method for multiple cracks problem is derived using Betti's reciprocal theorem in auxiliary fictitious state. High order element is proposed to solve the double integrals. The analysis demonstrates that symmetrical Galerkin boundary element method (SGBEM) can be used effectively for analyzing non-load carrying fillet welded cruciform joints containing any number of surface and embedded cracks. The stress intensity factor and the magnification factors M
k are analyzed. General formulation for this kind of fatigue life estimation is derived for engineering design purpose. The fatigue life estimate results are consistent with the code of practice and those of other researchers. This can provide a good method for engineering design under fatigue loading conditions. 相似文献
108.
提出了基于BP神经网络的车牌自动定位方法。实验表明,由此建立的车牌自动定位模型适角于各类机动车辆,总定位率为99.5%,达到了业务使用的要求。 相似文献
109.
分析了一个基于中国剩余定理的群签名方案,指出此方案并不安全:任何一个群成员或已被撤销的群成员都可以完全攻破此方案。针对该安全缺陷提出了一个改进的新方案。分析表明,该方案不仅可以在不改变其他群成员密钥的情况下有效地增加和撤销群成员,而且具有不可伪造性、防陷害攻击、抗联合攻击等性质。 相似文献
110.
在新一代直流控制保护系统WIN-TDC中,极控、站控和直流保护等核心部分采用了基于64位精简指令集计算机(RISC)、实时操作系统、64位系统总线的工业控制通用平台--SIMATIC-TDC.SIMATIC-TDC的开发环境采用了单一的编程语言,调试软件集成在开发环境中.人机界面采用了通用工控组态软件--WINCC.利用时分复用(TDM)总线技术实现了测量系统的交叉冗余.WIN-TDC已经在澳大利亚的海底电缆直流工程(BASSLINK)中得到了成功的应用. 相似文献