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81.
82.
Time-correlations as a contrast mechanism in scanning-tunneling-microscopy-induced photon emission 总被引:1,自引:0,他引:1
We have developed an experimental technique based on scanning-tunneling microscope (STM) which permits to record simultaneously topography, STM-induced photon emission and a map of two-photon auto-correlations for time resolutions down to the sub-nanosecond range. In the case of a gold surface at air, we show that the tip-induced luminescence exhibits a photon-bunching phenomenon at a 10-ns time scale which depends both on bias and on local topography. The photon bunching was exclusively observed at specific bumps of the surface. 相似文献
83.
The image‐based inertial impact (IBII) test has shown promise for measuring properties of composites at strain rates where existing test methods become unreliable due to inertial effects (> 102 s?1 ). Typically, the IBII tests are performed with a single camera, and therefore, to use surface measurements for material property identification, it is necessary to assume that the test is two‐dimensional. In this work, synchronised ultra‐high‐speed cameras are used to quantify the relevance of this assumption when nonuniform, through‐the‐thickness loading is applied to interlaminar samples. Initial experiments revealed that an angular misalignment of approximately 1° between the impact faces of the waveguide and projectile created a bending wave that propagated along the sample behind the axial pulse. Even under these conditions, consistent measurements of stiffness were made by assuming a linear distribution of the behaviour through‐the‐thickness. When the misalignment was reduced to 0.2°, the effects on single‐sided measurements were significantly reduced. The two alignment cases were compared to show that three‐dimensional loading had a small effect on stiffness identification (approximately 5% bias) relative to failure stress (approximately 30% bias). This study highlights the importance of impact alignment for reliable characterisation of the interlaminar failure stress and was used to establish guidelines for diagnosing loading issues from single‐sided measurements. 相似文献
84.
Satya M. Muddamsetty Désiré Sidibé Alain Trémeau Fabrice Mériaudeau 《Multimedia Tools and Applications》2018,77(5):5461-5474
Visual saliency is an important research topic in the field of computer vision due to its numerous possible applications. It helps to focus on regions of interest instead of processing the whole image or video data. Detecting visual saliency in still images has been widely addressed in literature with several formulations. However, visual saliency detection in videos has attracted little attention, and is a more challenging task due to additional temporal information. A common approach for obtaining a spatio-temporal saliency map is to combine a static saliency map and a dynamic saliency map. In our work, we model the dynamic textures in a dynamic scene with local binary patterns to compute the dynamic saliency map, and we use color features to compute the static saliency map. Both saliency maps are computed using a bio-inspired mechanism of human visual system with a discriminant formulation known as center surround saliency, and are fused in a proper way. The proposed model has been extensively evaluated with diverse publicly available datasets which contain several videos of dynamic scenes, and comparison with state-of-the art methods shows that it achieves competitive results. 相似文献
85.
A (Triphenylphosphine)Silver (I) Complex as a New Performance Additive in Free‐Radical Photopolymerization under Air 下载免费PDF全文
Pauline Sautrot‐Ba Nicolas Bogliotti Arnaud Brosseau Julie Bourgon Pierre‐Emmanuel Mazeran Jacques Lalevée Fabrice Morlet‐Savary Davy‐Louis Versace 《大分子材料与工程》2018,303(8)
Unusual photochemical properties of an Ag(I)‐derived complex, i.e., bis[(µ‐chloro)bis(triphenylphosphine)silver (I)] ([Ag](PPh3)) are demonstrated when used in free‐radical photopolymerization reactions: i) [Ag](PPh3) can act as an innovative photoinitiating system when associated with a commercial type I photoinitiator 2,2‐dimethoxy‐2‐phenylacetophenone to overcome the oxygen inhibition effect during the free‐radical photopolymerization of acrylate monomers, thus accelerating the kinetics of polymerization under air; ii) silver‐based nanoparticles can be in situ generated under air, thus leading to new antibacterial coatings which prevent the growth of Escherichia coli and Staphylococcus aureus after few hours of incubation. 相似文献
86.
为了研究硅光电倍增器(SiPM)在低温下能否正常工作,选取了两种典型的SiPM,通过液氮制冷方式,对SiPM在不同温度下的反向伏安特性进行了研究.结果显示,不同SiPM的过偏压范围(VB~Vb)随温度的变化差别很大,并且微量水蒸气凝结仅对未封装的SiPM伏安特性的Vb~VB段有明显影响.分析实验结果得出,SiPM正常工作电压的范围在很大程度上受到衬底材料中缺陷和陷阱浓度的影响.在低温下工作的SiPM,要求其衬底材料中缺陷和陷阱的浓度更低.在进行SiPM的低温应用和测量时,应密切监视偏压加在Vb~VB区间时,器件的电流是否有变化,而不能只观察击穿之前SiPM的漏电情况. 相似文献
87.
den Hertog MI Rouviere JL Dhalluin F Desré PJ Gentile P Ferret P Oehler F Baron T 《Nano letters》2008,8(5):1544-1550
Silicon nanowires (NW) were grown by the vapor-liquid-solid mechanism using gold as the catalyst and silane as the precursor. Gold from the catalyst particle can diffuse over the wire sidewalls, resulting in gold clusters decorating the wire sidewalls. The presence or absence of gold clusters was observed either by high angle annular darkfield scanning transmission electron microscopy images or by scanning electron microscopy. We find that the gold surface diffusion can be controlled by two growth parameters, the silane partial pressure and the growth temperature, and that the wire diameter also affects gold diffusion. Gold clusters are not present on the NW side walls for high silane partial pressure, low temperature, and small NW diameters. The absence or presence of gold on the NW sidewall has an effect on the sidewall morphology. Different models are qualitatively discussed. The main physical effect governing gold diffusion seems to be the adsorption of silane on the NW sidewalls. 相似文献
88.
Larpent C Cannizzo C Delgado A Gouanvé F Sanghvi P Gaillard C Bacquet G 《Small (Weinheim an der Bergstrasse, Germany)》2008,4(6):833-840
A simple synthesis of polymer core-dendrimer shell nanoparticles (NPs) in the 15-20-nm-diameter range is presented. Amine-terminated polypropyleneimine (PPI) dendrimers DAB-dendri-(NH(2))(4) and DAB-dendri-(NH(2))(16) (DAB4 and DAB16) are covalently attached to the surface of primary polystyrene-based NPs bearing reactive chlorobenzyl groups produced by microemulsion polymerization in the presence of a cationic surfactant. The grafting readily proceeds under mild conditions and leads to translucent aqueous suspensions of core-shell-type NPs with a high density of peripheral amine groups that have been characterized relative to their size and chemical composition. The dendritic shell acts as a protective ionizable outer layer and provides an improvement of the colloidal stability in neutral and acidic media. The metal-binding capacity of the PPI dendrimers is retained, and spectrophotometric titrations show that the dendrimer-grafted NPs can trap a large number of Cu(2+) ions (more than 900 Cu per NP-DAB16). These properties make them potentially valuable templates for the elaboration of hybrid nanomaterials. The reactivity of the external amine groups is used to link covalently azobenzene chromophores (disperse Red 1 residues) through aza-Michael addition in aqueous suspension. This simple method gives access to colored NPs with high dye contents in the outer layer (up to 1000-1500 dye molecules per NP), which indicates that dendrimer-functionalized NPs are valuable building blocks for the construction of multifunctional nanomaterials. 相似文献
89.
The mass transfer of nonretained, high-molecular-weight polystyrene standards in a chromatographic column packed with 4-microm-diameter silica particles for SEC (average pore size 80 A) and eluted with tetrahydrofuran was investigated. The HETPs of nine polystyrene standards (MW 560, 760, 1780, 3680, 6400, 13,200, 19,300, 31,600, and 90,000) and of ethylbenzene were measured by the method of moments. These HETPs were accounted for by a general HETP equation previously derived for the mass transfer of low-molecular-weight compounds in RPLC (Gritti, F.; Guiochon, G. Anal. Chem. 2006, 78, 5329.). The best fit between the experimental and the theoretical HETPs allowed the estimation of the internal restricted diffusion coefficients of the polymers. The internal diffusion coefficients of the polystyrene standards were also measured, using the peak parking method. Both methods give comparable results and show that the restriction diffusion coefficient gammapKD decreases linearly with increasing logarithm of the polymer mass, from 0.56 for Log MW = 2.0 to 0 for Log MW = 4.8. Interestingly, the C term or limit slope of the high-velocity branch of the HETP curve passes through a maximum (highest mass-transfer resistance) for a polymer mass of 10 kDa. This maximum is well accounted for by the theoretical expression of the trans-particle mass-transfer contribution. 相似文献
90.
A dual-rotating-retarder polarimeter was used to determine the six measurable observables of the first hyperpolarizability tensor. Calibration of such an instrument requires a reference sample dedicated to wavelength conversion. We calibrated our experimental setup by using a quartz-plate sample in a two step procedure: at first the first retarder then the second one. The retardance and ellipticity angle of both retarders were estimated by minimizing a chi(2) function. We estimated the standard deviation of each parameter from noise spreading and performed this calibration procedure for two experimental case studies, i.e., two angular positions of the quartz sample. 相似文献