Liquid Pool Copolymerization of Propylene/1‐Butene with a MgCl2‐Supported Ziegler‐Natta Catalyst

Summary: Liquid pool propylene/1‐butene copolymerizations were carried out in a batch reactor with a high activity Ziegler‐Natta catalyst system. Experimental runs were performed to evaluate the effect of the 1‐butene content on the crystallinity and melt temperature of the polymer resins. According to the results, 1‐butene can be significantly incorporated into the polymer chain at high polymerization rates over the whole range of copolymer compositions, leading to a decrease in the melting temperature (T_m) of the polymer, when compared to the poly(propylene) homopolymer, allowing for reduction of the sealing initiation temperature. It was observed by GPC and MFI measurements that the average molecular weights and the polydispersity index of the copolymer significantly decreased when compared to the ones obtained from poly(propylene). Despite high polymerization rates, polymer particles with good morphological features were produced in all cases. It was also observed that the absence of an external electron donor led to low crystallinity values for both the poly(propylene) homopolymer and for copolymers with different fractions of 1‐butene, when compared to literature values frequently reported for polymer resins based on 1‐butene and propylene. The obtained results indicate that a family of bulk propylene/1‐butene copolymer grades can be successfully developed for packaging and film applications.

Surface morphology and molecular weight distribution (deconvoluted into Schulz‐Flory distributions) of the propylene/1‐butene copolymer.     

A practical assessment of risk-averse approaches in production lot-sizing problems

ABSTRACT

This paper presents an empirical assessment of four state-of-the-art risk-averse approaches to deal with the capacitated lot-sizing problem under stochastic demand. We analyse two mean-risk models based on the semideviation and on the conditional value-at-risk risk measures, and alternate first and second-order stochastic dominance approaches. The extensive computational experiments based on different instances characteristics and on a case-study suggest that CVaR exhibits a good trade-off between risk and performance, followed by the semideviation and first-order stochastic dominance approach. For all approaches, enforcing risk-aversion helps to reduce the cost-standard deviation substantially, which is usually accomplished via increasing production rates. Overall, we can say that very risk-averse decision-makers would be willing to pay an increased price to have a much less risky solution given by CVaR. In less risk-averse settings, though, semideviation and first-order stochastic dominance can be appealing alternatives to provide significantly more stable production planning costs with a marginal increase of the expected costs.     

A Comprehensive Mixed-Mode Time-Domain Load- and Source-Pull Measurement System

We present a novel test set devised for nonlinear balanced device characterization using load-pull techniques. The system is capable of measuring the voltage and current waveforms at the calibration reference planes while independently tuning the device under test (DUT) source and load differential- and common-mode terminations. The test set is designed to address present and future large-signal multiport measurement needs, easing the characterization task while developing new multiport active devices.      

A Novel Calibration Algorithm for a Special Class of Multiport Vector Network Analyzers

A new error model for a special class of multiport vector network analyzers (VNAs) is presented in this paper. This model can be applied to multiport network analyzers with noncomplete reflectometers, i.e., when the measurement of the incident waves at each port is not always available. The method used to compute the error coefficients proposed here is based on a compact and easy formulation. This method is an extension of the already existing general theory for complete reflectometer multiport network analyzers. Furthermore, the new error model generalizes the theory for three-sampler two-port VNAs. The proposed model has been tested against the complete reflectometer one and exhibits the same accuracy level.     

Mechanical Behavior and Biodegradation of Poly(ε-caprolactone)/Starch Blends with and without Expansor

Summary The use of biodegradable polymers has provided an alternative to the problem of polymer-based products discarded in the environment. Poly(ε-caprolactone) (PCL) is a biodegradable polymer that has been used industrially, but it is very expensive. Starch is a potentially useful material for biodegradable plastics because of its natural abundance and low cost. The aim of this work was to examine the effect of adding azodicarbonomide (ADC) as an expansor to blends of PCL with corn starch. Different proportions, of ADC (0.1%, 0.2% and 0.3%, w/w) were added to pure PCL and to PCL/starch (50/50) blends and their properties were studied. Biodegradable blends of PCL with starch had a higher density than PCL alone and the addition of ADC reduced the density of the materials. The incorporation of starch increased the water absorption and ADC did not significantly alter this property. The incorporation of starch into PCL reduced the tensile strength and the elongation at break; ADC enhanced these reductions and also decreased the Young’s modulus of PCL. SEM showed that blends prepared with starch were immiscible, had a homogeneous dispersion of starch, and poor interfacial adhesion. The addition of ADC resulted in cells in the interior of the polymers. The 50/50 PCL/starch blends biodegraded faster than PCL, and ADC had no significant influence on the biodegradation of the blends but inhibited the biodegradation of PCL.     

Chitosan microcapsules: Methods of the production and use in the textile finishing

Biopolymeric chitosan is considered a promising encapsulating agent for textile applications due to its biocompatibility, lack of toxicity, antibacterial activity, high availability, and low cost. After cellulose, it is nature's most important organic compound. Also, chitosan has unique chemical properties due to its cationic charge in solution. Microencapsulation technologies play an important role in protecting the trapped material and in the durability of the effect, controlling the release rate. The application of chitosan microcapsules in textiles follows the current interest of industries in functionalization technologies that give different properties to products, such as aroma finish, insect repellency, antimicrobial activity, and thermal comfort. In this sense, methods of coacervation, ionic gelation, and LBL are presented for the production of chitosan-based microcapsules and methods of textile finishing that incorporate them are presented, bath exhaustion, filling, dry drying cure, spraying, immersion, and grafting chemical. Finally, current trends in the textile market are identified and guidance on future developments.     

Fluid-structure interaction study of the start-up of a rocket engine nozzle

The aim of this paper is to analyze the aeroelastic processes developed during the starting phase of a rocket engine via a coupling fluid/structure code. This analysis gives a better understanding of the behavior of the structure as the shock waves propagate inside the engine nozzle. The gasdynamics Euler equations are solved for the fluid and constitutive linear elastic solid assuming large displacements and rotations with no material damping is adopted for the structure. The coupling of each subproblem is carried out with a Gauß-Seidel algorithm over the fluid and structure states. For the fluid problem an ALE (Arbitrary Lagrangian-Eulerian) formulation is used. It allows us to define a reference system following the moving boundaries while the structure is deformed. The code is validated with a study of the flutter phenomena that may occur when a supersonic compressible fluid flows over a flat solid plate. Regarding the rocket engine ignition problem, a modal analysis of the structure is performed in order to analyze the eigenfrequency shifts when considering the coupling with the fluid flow.