A correlation for thermal conductivity of liquid n-alkanes based on the Vogel-Tammann-Fulcher-Hesse equation

This paper demonstrates that thermal conductivity of liquid paraffin hydrocarbons of different molecular weights can be correlated properly and conveniently using the Vogel-Tammann-Fulcher-Hesse equation. This approach is advantageous for applications of practical importance because it leads to a simpler effective correlation with fewer empirically determined parameters while providing twice better accuracy than a previous empirical correlation utilizing cubic-polynomial equations. This is illustrated by analyzing and correlating the thermal conductivity data of several liquid n-alkanes.     

Neutron Cross Section and Emission Spectra Calculations of Na Nucleus

Flibe (Li₂BeF₄) and Flinabe (LiFNaFBeF₂) are molten salt which are used as a first wall and blanket in advanced power extraction. Since they have low vapor pressure at high temperature and don’t pollute plasma. Moreover, they are used as a coolant material due to their high thermal cycling capacity. There are lots of benefits of using liquid wall such as reducing cost, increasing the reactor power and extending the life time of first steel wall. Being in Flinabe (LiFNaFBeF₂) molten salt, ²³ Na is also considered as a coolant material in fast reactors. Therefore, the reaction including neutron and ²³ Na is getting important. In this study, the cross section calculations of neutron induced reactions for ²³ Na were performed. Using pre-equilibrium and equilibrium models, excitation functions of ²³ Na(n,p)²³ Ne, ²³ Na(n,d)²² Ne, ²³ Na(n,α)²⁰ F, ²³ Na(n,2n)²² Na reactions and ²³ Na(n,xα), ²³ Na(n,xn) emission spectrums were calculated. We calculated alpha emission spectrum obtained when ²³ Na nuclei projectiled with 14.1 MeV neutrons and also neutron emission spectrum emitted when ²³ Na nuclei was bombardment with 14.6 MeV neutrons.     

Numerical research of cavitation on Francis turbine runners

Francis turbines, as other hydraulic turbines, are custom-designed for nominal operating conditions specific to each power plant. However, they may need to be operated at off-design flow conditions because of variable reservoir levels and flowrates. Operating the turbine at off-design points can cause cavitation. Four cavitation types can be observed on Francis turbine runners. These are leading edge, travelling bubble, draft tube swirl and inter-blade vortex cavitation. They may cause erosion, reduction in efficiency, vibration, instability of operation and noise. Runner blades must be designed taking the flow characteristics into account for design conditions to prevent cavitation. Cavitation limits for the off-design points must also be determined. In this study, the runner geometry of an actual hydroelectric power plant that was designed and implemented in 1960s, is redesigned with the help of the state of the art computational fluid dynamics techniques for cavitation free operation. The cavitation limits for the off-design points are also determined.     

Dielectric Properties of Coronene Film Deposited onto Silicon Substrate by Spin Coating for Optoelectronic Applications

Silicon - To determine the electrical modulus, dielectric properties, and ac conductivity of Coronene semiconductor layer, we have produced Al/Coronene/n-Si structure by using the thermally...     

Structural,electrical, and electromagnetic properties of cotton fabrics coated with polyaniline and polypyrrole

In this study, the structural, electrical, and electromagnetic properties of cotton fabrics coated with polyaniline (PAni) and polypyrrole (PPy) were investigated and compared. For the aims, anilin and pyrrole were used as monomers, and in situ polymerization on cotton fabric by chemical oxidative polymerization was performed. After production, the structural properties of the fabrics were determined with Fourier transform infrared spectroscopy and X‐ray diffraction. In addition, ultraviolet (UV) permeability, tensile strength, colorfastness, and electrical and electromagnetic measurements of the fabric samples were carried out. The resistance values of the cotton fabrics coated with PAni and PPy were found to be 350 and 512 Ω, respectively. The average electromagnetic shielding efficiency and average absorption values of the cotton fabrics coated with PAni were determined to be 3.8 dB and 48%, respectively, and these values for the cotton fabrics coated with PPy were 6 dB and 50%, respectively. Consequently, a significant difference was not observed between the resistance values and electromagnetic parameters of the fabrics coated with PAni and PPy, although the intact textile characteristics of the fabric coated with PPy were protected and improved, whereas the characteristics of the fabric coated with PAni were inferior. Moreover, we first report that the fabrics coated with conductive polymers had excellent UV‐protection properties. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Conducting copolymers of polytetrahydrofuran and their electrochromic properties

Living polytetrahydrofuran (PTHF) was terminated with sodium thiophene methonate to yield a polymer with a thiophene group at one end. Copolymerizations of PTHF with pyrrole and thiophene were achieved in water‐p‐toluene sulfonic acid and acetonitrile‐tetrabutylammonium tetrafluoroborate (TBAFB) solvent‐electrolyte couples via constant potential electrolyses. Characterizations of the samples were performed by NMR, cyclic voltammetry, FT‐IR, thermal analyses, and scanning electron microscopy. Electrical conductivities were measured by the four‐probe technique. PTHF/PTh film that was deposited on ITO‐glass in a dichloromethane‐TBAFB solvent‐electrolyte couple was found to exhibit electrochromic behavior and it electrochemically switches between blue oxidized and red reduced states. Optical analyses were carried out to investigate the electronic structure of PTHF/PTh electrochromic copolymer. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1014–1023, 2005     

Improving reinforcement learning by using sequence trees

This paper proposes a novel approach to discover options in the form of stochastic conditionally terminating sequences; it shows how such sequences can be integrated into the reinforcement learning framework to improve the learning performance. The method utilizes stored histories of possible optimal policies and constructs a specialized tree structure during the learning process. The constructed tree facilitates the process of identifying frequently used action sequences together with states that are visited during the execution of such sequences. The tree is constantly updated and used to implicitly run corresponding options. The effectiveness of the method is demonstrated empirically by conducting extensive experiments on various domains with different properties.     

Preparation and characterization of La0.8Sr0.2Ga0.83Mg0.17O3 electrolyte by polyol method for solid oxide fuel cells

Perovskite type La_0.8Sr_0.2Ga_0.83Mg_0.17O₃ powders were prepared via simple polyol method for the first time in literature. Obtained material was characterized by using XRD, SEM, Impedance Spectroscopy and density measurements. Pure LSGM powders were achieved after heat treatment at 1100 °C for 12 h. 87% relative density was obtained after pressing of these powders under 1 MPa and sintering at 1250 °C for 12 h. Average particle size was calculated as 1.77–2.4 μm from SEM micrographs. Overall conductivity of the LSGM pellet was found to be 0.0014 S/cm at 850 °C with impedance analysis and showed that the preparation process needs improvements.     

Microfoaming of flax and wood fibre reinforced polypropylene composites

Natural and wood fibre reinforced plastics as a relatively new group of environmental friendly materials have been extensively applied in interior, building applications and in the automobile industry. Among others, natural and wood fibre reinforced foamed polymer materials are of high significance because of the possibility of their reducing the density of automotive components which have a cellular structure. However, the properties of these materials have not been fully investigated and described. Microcellular composites of polypropylene containing natural and wood fibre was prepared using an injection moulding process. In the present work, the manufacturing technology of natural and wood fibre reinforced polymer microfoams was developed and the influence of fibre and microvoid content on its property spectrum was systematically investigated. The forming of microvoids and the degree of foaming related to the variation of the processing parameters in connection with manufacture technology was characterised. Measurement of density, cell size, tensile and flexural properties of the prepared composites was carried out. The cell structure is dependent on flow direction of foaming. The density of microfoamed wood fibre-PP composites was reduced by about 24% and decreased by as much as 0.77 g/cm³.Light microscopy showed that the cells are circular and it was also observed that the maximum cell sizes are between 10–50 μm. Water absorption and scanning electron microscopy of the composites were also investigated. Considering the experimental results, it can be deduced that the microcellular composites exhibit a possible combination of relatively good engineering properties and lower density for different technical applications.