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991.
We present a one‐pot method for the synthesis of poly(urethane urea)s (PUUs) with uniform (monodisperse) hard segments that eliminates tedious approaches to control the exothermic nature of isocyanate–amine reaction, is less sensitive to impurities and involves no isolation of intermediates. Reaction of two moles of hexamethylene diisocyanate with one mole of polycaprolactone of various molecular weights under optimum time and temperature led to NCO‐terminated polyurethane prepolymers. Addition of an equimolar quantity of benzoic acid and excess dimethylsulfoxide at ambient temperature produced quantitative yields of PUUs with high molecular weight. The structure of the PUUs was fully characterized using spectroscopic methods and a reasonable mechanism for the reaction sequences was determined via preparation and characterization of a model compound. Dynamic mechanical thermal analysis data confirmed the phase‐separated structure of the PUUs. Evaluation of stress‐strain curves revealed the wide‐ranging mechanical properties depending on soft‐segment molecular weight. Monitoring the remaining weight and molecular weight of polymers incubated in phosphate‐buffered saline showed hydrolytic degradability with rate depending on soft‐segment molecular weight. Also, a preliminary investigation of the interaction of L929 fibroblast cells with the prepared polymers confirmed no cytotoxicity and acceptable cytocompatibility for the PUUs. Copyright © 2010 Society of Chemical Industry 相似文献
992.
Mehdi Esfandyari‐Manesh Mehran Javanbakht Fatemeh Atyabi Alireza Badiei Rassoul Dinarvand 《应用聚合物科学杂志》2011,121(2):1118-1126
This study focus on the effect of the porogenic solvent on the morphology, recognition, and drug release of carbamazepine‐molecularly imprinted polymer nanospheres prepared by precipitation polymerization. The scanning electron microscopy (SEM) images and Brunauer‐Emmett‐Teller (BET) analysis showed that molecularly imprinted polymer (MIP) prepared by acetonitrile exhibited a regular spherical shape at the nanoscale with a high degree of monodispersity, specific surface area of 242 m2 g−1, and pore volume of 1 mL g−1, while those using chloroform and toluene produced irregular polymer particles with low specific surface area and pore volume. MIP prepared by acetonitrile/chloroform (1 : 1, v/v) showed mediator texture properties compared to MIPs obtained by acetonitrile or chloroform. Results from saturation and displacement assays indicated that the imprinted nanospheres with binding capacity of 2.85 (mg CBZ/g polymer) had high specific affinity to CBZ in contrast to nonimprinted nanospheres (1.63 mg CBZ/g polymer). The imprinted nanospheres with 2.4 selectivity factor had good recognition to CBZ than analog template of oxcarbazepine. Moreover, release studies showed that 20% of loaded CBZ was released from the imprinted nanospheres within the initial 6 h, while another 80% of CBZ was released in the following 9 days. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
993.
In this work, a new elastomeric liner was introduced to protect the metal surfaces of storage tanks against corroding materials in petrochemical industries. This new liner was prepared on the basis of EPDM/NR and EPDM/SBR compounds. The elastomeric compounds were cured by using super‐heated water vapor at atmospheric pressure. To increase the rate of curing in these rubber samples, the optimum curing system contained 15 phr sulfur and 1.5 phr mercaptobenzothiazole, 1.5 phr zinc diethyl dithiocarbamate, and 1.8 phr tetramethylthiuram disulfide accelerators. Mechanical tests showed that ultimate tensile strength, elongation at break, and hardness of both polyblend samples were comparable to the SBR/NR blend, which is widely used in the rubber lining of metallic surfaces. In the next step, the chemical resistance of the samples was measured by placing them in a 30 wt % HCl solution. The tensile strength, elongation at break, and weight loss of the samples were measured before and after immersion in HCl. Also, the chemical resistances for EPDM/NR, EPDM/SBR, and SBR/NR samples were qualitatively measured in caustic solution. The cracking, blistering, permeability, and adhesion of the rubber samples to steel surface were observed. Finally, the results showed that EPDM/SBR (70/30) polyblend can be a suitable substitute for conventionally used SBR/NR (50/50) for a successful rubber used to line metallic surfaces. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
994.
Mahdi Shahrokhi Fatemeh Rostami Md Azlin Md Said Saeed Reza Sabbagh Yazdi Syafalni Syafalni 《Water and Environment Journal》2013,27(4):484-494
To increase the performance of a primary sedimentation tank (clarifier), it is essential to have a uniform and calm flow field. The use of suitable baffle configurations may help forming favourable flow field and increase the efficiency of the primary sedimentation tank. To find the proper position and height of a baffle in a rectangular primary sedimentation tank, computational investigations are performed. Also, laboratory experiments are conducted to verify the numerical results, and the measured velocity fields that were by acoustic Doppler velocimeter (ADV) are used. The results of computational investigations performed in the present study indicate that the favourable flow field (uniform in the settling zone) would be enhanced for the case that the baffle position and height provide small circulation regions volume, or the recirculation region forms a small portion of the flow field and dissipate the kinetic energy in the tank. 相似文献
995.
S. Mahmood Sadat Noori Kumars Ebrahimi Abdol‐Majid Liaghat Abdol‐Hossein Hoorfar 《Water and Environment Journal》2013,27(1):10-19
The main aim of this study has been to assess the spatially variability of groundwater level at different climatic periods. The study area is Saveh‐Nobaran aquifer in Iran. First, using two drought indices, different climatic periods in the region including wet, normal and dry during 1993–2003 were recognized. Second, with the use of measured elevations of the water table, experimental semivariograms (spherical, exponential and Gaussian) were constructed that characterize the spatial variability of the measured groundwater levels. Groundwater levels were interpolated by four different geostatistical methods. RMSE, MAE and R 2 were calculated to determine the best method. The R 2 coefficient obtained from kriging, cokriging, TPSS and IDW methods were 0.95, 0.97, 0.89 and 0.83, respectively. Cokriging method was used to create groundwater‐level maps, including maximum, average and minimum water levels for each climatic period. The results obtained from geostatistical analysis showed that groundwater depth varies spatially in different climatic conditions. 相似文献
996.
In this part of the sequel we develop a continuum representation of the pressure fluctuation time series p(t) for a fluidized bed (FB), analyzed in part I, by using stochastic methods based on the Markov processes. It is shown that the data may be represented by Markov series with a Markov time scale tM that is estimated based on the data. Using the relation between the Markov processes and the Kramers–Moyal (KM) expansion that is a continuum equation that involves, in principle, an infinite number of coefficients, we represent the pressure fluctuation time series by a KM expansion. However, since the third and higher-order coefficients of the expansion are very small, the KM expansion reduces to a Fokker–Planck (FP) equation that represents p(t) in terms of a drift and a diffusion coefficients that are computed based on the data. The FP equation is, in turn, equivalent to a Langevin equation, which is used to reconstruct the data, i.e. generate the time series that mimic, in a statistical sense, the original data. Thus, the Langevin equation may also be used to make probabilistic predictions for the future values of the pressure over time scales that are of the order of the Markov time scale tM. The accuracy of the reconstructed series and, hence, their continuum representation, is demonstrated. We also compute the frequency of level-crossing at a given level α, i.e. the relative frequency (probability) of occurrence of the event defined, for two times ti−1 and ti, by, , where P(x) is the probability of the event. Thus, yields the frequency that a given pressure fluctuation level may be expected. The average time that one should wait in order to observe the pressure at a given level again is also computed. The two quantities may be particularly important for modeling of the FBs. A relation is presented between the drift and diffusion coefficients of the FP equation and the Hurst exponent that has previously been used to describe the pressure fluctuation time series in terms of self-affine stochastic distributions. 相似文献
997.
Saeedeh Faghih Haghani A. Sadighzadeh A. Talaei A. A. Zaeem S. M. Sadat Kiai A. Heydarnia V. Damideh 《Journal of Fusion Energy》2013,32(4):480-487
Mather type plasma focus device with the bank energy of 115 kJ (40 kV, 144μF) was studied for induced activity of N-13; a short-lived radioisotope β+ emitter with 511 keV of gamma rays and has a half-life of t1/2 = 9.93 min through 12C (d, n)13N nuclear reaction. N-13 radioisotope is used in Positron Emission Tomography (PET) for imaging and treatment. In this paper endogenous production of 13N is considered. It is shown by adding 3–4 % CH4 to the chamber, the induced activity of N-13 has increased about 4 %. Our study is representative of producing 106 ? 109 Bq induced activity of this SLR in IR-MPF-100 device. 相似文献
998.
Calculations of decay rates of an excited atom embedded in a dispersive and dissipative plasma medium are presented in this paper. The usual expression for decay rate of an initially excited atom in dipole approximation is given by Fermi’s golden rule. The electric field correlation function is related to the imaginary part of the potential Green’s function along with the fluctuation of dissipation theorem and Kubo’s formula. Using the Green’s function technique offers possibilities of closed function representations. It is applicable to evaluate the decay rate of an excited atom that allows us to understand the particular structure of the vacuum state of the electromagnetic field. In this paper, the decay rate of an excited atom in dispersive and dissipative media is estimated. 相似文献
999.
Scientometrics - This study explores the diachronic evolution of doctoral dissertation writing in terms of interactive and interactional metadiscourse at three time intervals of 1966, 1986, and... 相似文献
1000.
Cheng-An Wang Hamou Sadat Vital Ledez Denis Lemonnier 《International Journal of Thermal Sciences》2010,49(12):2282-2288
A meshless method is presented to solve the radiative transfer equation in complex 2D and 3D geometries. In order to avoid numerical oscillations, the even parity formulation of the discrete ordinates method is used. A moving least squares approximation meshless method is used to solve the second order partial differential equations. Prediction results of radiative heat transfer problems obtained by the proposed method are compared with reference in order to assess the correctness of the present method. 相似文献