Use of Turkish huntite/hydromagnesite mineral in plastic materials as a flame retardant

In this study, the flame retardancy properties of huntite/hydromagnesite mineral in plastic compounds were investigated for potential electrical applications. Before the production of composite materials, huntite/hydromagnesite minerals were ground to particle sizes of 10, 1, and 0.1 μm. Phase and microstructural analysis of huntite/hydromagnesite mineral powders were undertaken using XRD and SEM‐EDS preceding the fabrication of the composite materials. The ground minerals with different particle size and content levels were subsequently added to ethylene vinyl acetate copolymer to produce composite materials. After fabrication of huntite/hydromagnesite reinforced plastic composite samples, they were characterized using DTA‐TG, FTIR, and SEM‐EDS. Flame retardancy tests were undertaken as a main objective of this research. The size distribution and the mineral content effects are measured regarding the flame retardancy of the polymer composites It was concluded that the flame retardant properties of plastic composites were improved as the mineral content increased and the size was reduced. POLYM. COMPOS., 31:1692–1700, 2010. © 2010 Society of Plastics Engineers.     

Renewable hydrogen energy regulations,codes and standards: Challenges faced by an EU candidate country

The European Union is one of the most important players in the field of world energy with an integrated and well-organized energy market. However, energy policies in the EU are not sustainable. The EU is the world’s largest importer of fossil fuels and is leading global action in accelerating the transition to renewable energy and low-carbon economy at present. Renewables make the second-largest contribution to domestic energy production after coal.     

Characterization of chemically sprayed CdO films on borate and phosphate glass substrates produced by melt-quenching technique

The properties of substrates used to deposit thin films are an important parameter in thin film production. Instead of using a commercial substrate, in this work, borate and phosphate glasses have been obtained by classic melt-quenching technique to be used as substrates for CdO films. Also, a microscope glass substrate has been used to compare the coating properties by other glass substrates. All films have been produced by Ultrasonic Spray Pyrolysis technique. The substrate temperature has been selected as 275 ± 5 °C. Thicknesses and some optical parameters such as refractive index and extinction coefficient have been determined by spectroscopic ellipsometry. Absorbance and transmittance spectra have been taken by UV/VIS spectrophotometer. Four-probe method has been used to determine the electrical resistivity values of the films. XRD investigations have shown that type of the substrate dramatically affects the characteristics of CdO films. CdO film deposited on phosphate glass substrate has the best structural quality. Atomic Force Microscope has been used to investigate the surface properties and roughness values of the films.     

Thermal,mechanical and water adsorption properties of corn starch–carboxymethylcellulose/methylcellulose biodegradable films

The objective of this study was to investigate the effect of the addition of methylcellulose and carboxymethylcellulose on the thermal, mechanical and water adsorption properties of starch-based films plasticized with glycerol or polyethylene glycol (PEG). Mechanical tests showed that as the methylcellulose and carboxymethylcellulose proportion increased, starch films became more resistant to break, resulting in higher TS values. Besides there has been a positive effect on the elasticity of starch films realized by a considerable increase in E% values. Depending on the plasticizer type, either single or dual glass transitions were seen in DSC thermograms. One glass transition temperature was observed for films plasticized with glycerol, on the contrary, dual glass transitions were detected for PEG plasticized films. This behavior was attributed to the phase separation of the PEG. In addition, the presence of an endothermic peak in the thermograms of PEG plasticized films was taken as another indicator of the phase separation. As a result, it was suggested that PEG was not as compatible as glycerol with the composite polysaccharide matrix and plasticizer type was the main factor that shaped the thermal profiles of the film samples. Water adsorption isotherm data showed that samples displayed nonlinear sorption profile which is typical for hydrophilic films. In all films tested, equilibrium moisture contents, increased almost linearly up to a a_w of 0.65–0.85, beyond where a sharp increase was noted. Adsorption data was adequately fitted by BET and GAB models. Eventually, it can be concluded that film forming properties of starch can be improved by incorporation of methylcellulose and carboxymethylcellulose to the polymer matrix.     

Determining the best type of heat exchangers for heat recovery

It is a common problem to choose the most appropriate heat exchanger configuration for heat recovery. In this study, a new model has been developed for determining the area and type of the most appropriate waste heat recovery heat exchanger for maximum net gain. A non-dimensional E number has been defined based on known technical and economic parameters such as the life-time, unit area cost of the heat exchanger, lower heating value of the fuel, overall heat transfer coefficient of heat exchanger, boiler efficiency, operation time per year, heat exchanger effectiveness, ratio of heat capacities, annual variation of the temperature of fluids supplied to the heat exchanger and present worth factor. The non-dimensional E numbers has been demonstrated in graphical forms as a function of NTU and ratio of heat capacities and corresponding heat exchanger area giving maximum net gain can easily be obtained from these graphs. The best heat exchanger type and its area can be determined comparing net gains or effectiveness of heat exchangers at NTU_max. Application of the new method has been given with a case study as a sample calculation.     

Some physical properties of copper oxide films: The effect of substrate temperature

In this work, copper oxide films were deposited at different substrate temperatures of 200, 250, 300 and 350 ± 5 °C by ultrasonic spray pyrolysis technique and the effect of substrate temperature on the structural, surface, optical and electrical properties of the films was presented. The film structures were studied by X-ray diffraction (XRD). To obtain information about structural properties in detail, the grain size (D), dislocation density (δ) and lattice parameters (a = b = c for cubic structure) for preferential orientations were calculated. The surface properties and elemental analyses were characterised using scanning electron microscopy and energy dispersive X-ray spectroscopy, respectively. Optical properties of the films were analyzed by transmission, linear absorption coefficient and reflection spectra, and the optical method was used to determine the band gaps of the films. The current–voltage values were measured with two-probe technique, and the electrical conductivities were calculated. Consequently, it was determined that substrate temperature has a strong effect on the structural, surface, optical and electrical properties of copper oxide films.     

Transient and steady-state natural convection heat transfer from a heated horizontal concrete cylinder

In refrigeration systems, it is possible to reduce energy consumption (compressor power) and increase COP by decreasing the condensation temperature. Decreasing the condensation temperature can be achieved either by increasing the overall heat transfer coefficient or heat transfer surface area of the condenser. Usually, the radiuses of condenser tubes of domestic refrigerators are quite smaller than the critical radius. Thus, the radius can be increased up to the critical radius by coating the bare condenser tube to increase heat transfer. On the other hand, refrigerators operate discontinuously depending on the ambient temperatures. Coating material stores some of the heat during the working period and continues heat transfer during the off period so that the condenser continues transferring heat while the compressor is not working. Storage effect depends on the specific heat and density of the coating material. Transient and steady-state natural convection heat transfer from a heated horizontal cylinder covered with concrete layer by molding is studied experimentally and numerically to determine the effects of the parameters considered above. The copper and the concrete test cylinders used in the experimental study have a length of 1 m and outer diameter of 9.45 mm and 68.5 mm respectively. The ambient and copper cylinder surface temperatures varied between 20 °C÷30 °C and 30 °C÷50 °C respectively. Constant heat flux was applied to bare and concrete cylinders. Transient heat transfer experiments were performed when bare, and concrete cylinders were reached to steady state condition. Heat transfer rates under transient conditions from bare and concrete horizontal cylinders were compared and heat transfer enhancement was determined. Based on the experimental data average Nusselt numbers were calculated and compared with the well known correlations. Also temperature distributions obtained from numerical simulations were very close to the experimental data. The effect of the decrease in the temperature of the inner copper cylinder surface (condensation temperature) on COP was investigated considering an ideal Carnot refrigeration cycle. It is found that the enhancement in COP of a Carnot refrigeration cycle is 35.7% under transient condition.     

A novel hybrid method for better evaluation: Evaluating university instructors teaching performance by combining conventional content analysis with fuzzy rule based systems

Even though engineering and applied sciences deal with numerical data, they have successfully implemented fuzzy logic by using fuzzy rule based (FRB) systems by verbalizing data. On the other hand, social sciences such as sociology, education and physiology transform verbal type data into numerical values by using Likert type scale. Despite the fact that fuzzy set theory deals with verbal data very powerfully, social science fields in general have avoided to implement it to their verbal data up until now. One of the most active research areas in education field which generates verbal data is student evaluation of teaching (SET) questionnaires which are related to Total Quality Management applications in most of the competitive universities in the world. In this paper, we propose a novel hybrid method, which combines conventional content analysis (CCA) method and FRB systems and this new hybrid method is more suitable for the verbal data obtained from SET questionnaires. This novel CCA-FRB (conventional content analysis based fuzzy rule based systems) method uses a sample of 138 junior students from Gazi University in Turkey to implement the proposed method.