Tuning of shear thickening behavior and elastic strength of polyvinylidene fluoride via doping of ZnO-graphene

ZnO rice like nonarchitects are grafted on the graphene carbon core via a rapid microwave synthesis route. The prepared grafted systems are characterized via XRD, SEM, RAMAN, and XPS to examined the structural and morphological parameters. Zinc oxide grafted graphene sheets (ZnO-G) are further doped in β-phase of polyvinylidene fluoride (PVDF) to prepare the polymer nanocomposites (PNCs) via mixed solvent approach (THF/DMF). β-phase confirmation of PVDF PNCs is done by FTIR studies. It is observed that ZnO-G filler enhances the β-phase content in the PNCs. Non-doped PVDF and PNCs are further studied for rheological behavior under the shear rate of 1–100 s⁻¹. Doping of ZnO-G dopant to the PVDF matrix changes its discontinuous shear thickening (DST) behavior to continues shear thickening behavior (CST). Hydrocluster formation and their interaction with the dopant could be the reason for this striking DST to CST behavioral change. Strain amplitude sweep (10⁻³% -10%) oscillatory test reveals that the PNCs shows extended linear viscoelastic region with high elastic modulus and lower viscous modulus. Effective shear thickening behavior and strong elastic strength of these PNCs present their candidature for various fields including mechanical and soft body armor applications.     

Phase Evolution and Densification Behavior of Nanocrystalline Multicomponent High Entropy Alloys During Spark Plasma Sintering

In the current study, the phase evolution of multicomponent equiatomic CoCrCuFeNi, CoCuFeNi, CoCrCuNi, and CoCrFeNi alloys synthesized by mechanical alloying (MA) followed by annealing was studied. From the phase evolution studies, CoCrFeNi, CoFeMnNi, CoCuFeNi, and CoFeNi were chosen to correlate the densification together with phase evolution during spark plasma sintering (SPS). MA resulted in a major face centered cubic (fcc) phase and a minor body centered cubic (bcc) phase in Cr-containing alloys, and a single fcc phase in all other alloys. After SPS, CoFeMnNi and CoFeNi remained as single fcc phase. However, CoCuFeNi transformed to two fcc phases, and CoCrFeNi had a major fcc phase with minor sigma phase. From densification studies, it was evident that CoCrFeNi showed delayed densification, albeit maximum final densification in comparison to other alloys. This behavior was attributed to distinctly different phase evolution in CoCrFeNi during SPS as compared to other alloys. Detailed phase evolution studies were carried out on CoCrFeNi by annealing the powders at different temperatures followed by conventional x-ray diffraction (XRD) and in situ high-temperature XRD of mechanically alloyed powders. The results obtained from the annealing and in situ high-temperature XRD studies were correlated with the densification and alloying behavior of CoCrFeNi alloy.     

Investigation of Microstructures,Mechanical Properties of AZ91E Hybrid Composite Reinforced with Silicon Carbide and Fly Ash

Silicon - In this study, the stir casting processing technique was used to produce the AZ91E hybrid composite reinforced with Silicon Carbide (SiC) and Fly ash (FA) particles in different weight...     

Microstructural evolution in liquid metal processed Al-alloy/SiCp composites

Al-Zn-Mg/SiC_P composites processed by a liquid metal processing (stir casting) technique have been microstructurally characterised in the as-cast and extruded conditions. Uniform distribution of SiC_P is observed with few defects, such as particle clusters, which are due to partial wetting and associated gas porosity. The constituent particles are associated with SiC_P although their composition remains unaffected compared with the control alloy. Hot extrusion of the composite using a shear type die showed banding of particles in the extruded direction with 9 vol. % composite. Such defects however, are not predominant in 18% SiC_P extruded composites. The presence of Mg₂Si is detected at the particle matrix interface as well as in the matrix.     

Carbon-based TiO2-x heterostructure nanocomposites for enhanced photocatalytic degradation of dye molecules

Application of brown titanium dioxide (TiO_2-x) and its modified composite forms in the photocatalytic decomposition of organic pollutants in the environment is a promising way to provide solutions for environmental redemption. Herein, we report the synthesis of effective and stable TiO_2-x nanoparticles with g-C₃N₄, RGO, and multiwalled carbon nanotubes (CNTs) using a simple hydrothermal method. Among all the as-synthesized samples, excellent photocatalytic degradation activity was observed for RGO-TiO_2-x nanocomposite with high rate constants of 0.075 min^?1_, 0.083 min^?1 and 0.093 min^?1 for methylene blue, rhodamine-B, and rosebengal dyes under UV–Visible light irradiation, respectively. The altered bandgap (1.8 eV) and the large surface area of RGO-TiO_2-x nanocomposite impacts on both absorption of visible light and efficiency of photogenerated charge electron (e^?)/hole (h⁺) pair separation. This resulted in enhanced photocatalytic property of carbon-based TiO_2-x nanocomposites. A systematic study on the influence of different carbon nanostructures on the photocatalytic activity of brown TiO_2-x is carried out.     

Solar hydrogen generation from organic substance using earth abundant CuS–NiO heterojunction semiconductor photocatalyst

This work explores the critical role of NiO co-catalyst assembled on the surface of a CuS primary photocatalyst which effectively improves interface properties and enhances solar-to-hydrogen production by prolonging lifetime of photo-excitons generated at the CuS surface. The nanoscale CuS/NiO heterojunction is formulated using hydrothermal and wet impregnation methods. The resultant CuS/NiO composite shows optical absorbance between 380 and 780 nm region. The type-II energetic structure formed at CuS/NiO heterojunction facilitates rapid charge separation and as a result, the CuS/NiO composite exhibits 13 folds higher photocatalytic water splitting performance than CuO and NiO. The champion CuO/NiO photocatalyst is first identified by screening the catalysts using a preliminary water splitting test reaction under natural Sunlight irradiation. After the optimization of the catalyst, it was further explored for enhanced photocatalytic hydrogen production using different organic substances dispersed in water (alcohols, amine and organic acids). The champion CuS/NiO catalyst (CPN-2) exhibited the photocatalytic hydrogen production rate of 52.3 mmol h^?1.g^?1_cat in the presence of lactic acid-based aqueous electrolyte and, it is superior than hydrogen production rate obtained in the presence of other organic substances (triethanolamine, glycerol, ethylene glycol, methanol) tested under identical experimental conditions. These results indicate that the energetic structure of CuS/NiO photocatalyst is favorable for photocatalytic oxidation or reforming of lactic acid. The oxidation of lactic acid contributes both protons and electrons for enhanced hydrogen generation as well as protects CuS from photocorrosion. The modification of surface property and energetic structure of CuS photocatalyst by the NiO co-catalyst improves photogenerated charge carrier separation and in turn enhances the solar-to-hydrogen generation efficiency. The recyclability tests showed the potential of CPN-2 photocatalyst for prolonged photocatalytic hydrogen production while continuous supply of lactic acid feedstock is available.     

Morphological exploration of chemical vapor–deposited P-doped ZnO nanorods for efficient photoelectrochemical water splitting

Photoelectrochemical (PEC) water splitting is beneficial and has received attractive attention due to a greater potential to generate hydrogen and oxygen from water by using plentiful solar light to solve the problem of energy crisis. Various active semiconductor materials are used in PEC water splitting applications. Nevertheless, in past decades, most of the researchers suggested that titanium oxide (TiO₂) is the best photoanode for this type of applications. Now, Zinc oxide (ZnO) is considered a perfect substitution to TiO₂ due to its comparable energy band structure and superior photogenerated electron transfer rate. In this study, bare and phosphorous-doped ZnO nanorods were successfully developed on fluorine-doped tin oxide-coated glass (FTO) substrate by chemical vapor deposition. X-ray diffraction (XRD) pattern authenticated hexagonal structure formation with strong diffraction peak of (101), which showed that ZnO nanorods were perfectly developed along c axis. The optical and morphological properties were analyzed by UV–Vis and scanning electron microscopy images. The energy-dispersive X-ray spectra demonstrated that doping agent phosphorous was present in ZnO nanorods. The PEC properties of the developed ZnO nanorods were further investigated and obtained results suggested that a small amount of phosphorous-doped ZnO nanorods enhances their PEC performance.     

Assessment of the performance of different compost models to manage urban household organic solid wastes

The environmental, cultural, socio-economic and political conditions of each community greatly affect the municipality’s effort and decision-making in managing household wastes. Composting at home can be used as a sound method of SWM, can manage the waste at source itself thereby can increase their recycling. And vermicomposting is a viable and completely feasible option at household level, provided it is acceptable to family members to handle the worms and to remove worm-casts subsequently. In this regard, the present paper gives a methodological framework for assessing the management of urban household organic wastes using different compost models to influence the actual efficiency and effectiveness of a municipality’s collection and management services. The current study also deals with the challenges of solid waste management with a focus on the segregation of compostable wastes from the non-compostable ones and their composting, recycling or disposal. The non-compostable wastes can be left for recycling and re-use by the concerned authorities. The composting behavior and the efficiency of different compost models have been dealt with, and it is concluded that vermicomposting model is the best option. Urban residents can be educated to vermicompost not only their entire kitchen wastes but also garden wastes to reduce the burden on the municipal councils.     

迎向更环保的明天：半导体让汽车更环保

低价位新车打入印度汽车市场，印度的汽车总数将于2012年超过4000万辆。空气质量已成为印度政府关注的首要课题，而针对省油引擎管理系统的重要性，     

Personalized email management at network edges

A new technique for managing and disseminating Web-based email prefetches messages and generates dynamic pages, displaying them at the network edge. Compared to other popular Web-based email servers, the prefetching and caching emails (PACE) prototype shows an improved performance with respect to user-perceived latency. Additionally, PACE'S centralized neural-network-based personalized spam filter will filter spam and viruses at the server's origin, thus saving bandwidth. Another major concern for users is the email accounts being clogged with spam. Spam filters can be classified as server-side or client-side. Server-side filters are integrated with email servers and filter out spam at the server end.