Con(dif)fused voice to convey secret: a dual-domain approach

Owing to the rapid development and advancements in the field of networks and communication, sharing of multimedia contents over insecure networks has becom     

Synthesis and phase stability of precursor derived HfO2/Si-C-N-O nanocomposites

Hafnium alkoxide modified polysilazane was synthesized by the drop-wise addition of hafnium tetra(n-butoxide) to polysilazane. The solid state thermolysis (SST) temperature and the ceramic yield for both the polysilazane and modified polysilazane were determined by performing thermogravimetry. Fourier transform infrared spectroscopy was performed to understand the polymer to ceramic conversion as well as the bonding characteristics of the ceramics. The modified polymer after crosslinking was subjected to SST at 800 °C at a constant heating rate of 5 °C/min for a dwell time of 2 h in atmospheric ambience. From the X-ray diffractograms, the as-thermolysed ceramics were observed to remain X-ray amorphous and on heat-treatment resulted in the crystallization of tetragonal hafnia. However, on heat-treatment at 1500 °C, reverse phase transformation from tetragonal to monoclinic hafnia was observed. Raman spectroscopy and transmission electron microscopy were employed to further understand the phase evolution. The thermal stability and the influence of amorphous matrix on the coarsening of HfO₂ were also evaluated.     

Performance and emission characteristics of diesel engine operated on plastic pyrolysis oil with exhaust gas recirculation

The objective of this research was to study the performance and emission characteristics of using waste plastic pyrolysis oil in diesel engine without any engine modification. The engine used in this study is a four-stroke single-cylinder naturally aspirated diesel engine (compression ignition). In the present work, the engine fuelled with blends of diesel fuel (DF) with plastic oil in the ratio of 90:10 (blend10%), 80:20 (blend20%), 70:30 (blend30%), and 50:50 (blend50%) are experimentally measured the efficiencies and emissions, analysed the performance, and compared results with that of DF.     

Impact of interfacial solubility on penetration of metals into dielectrics and the mechanism of failure

Copper solubility in low-k dielectrics has been shown to be a major factor in decreasing the useful lifetime of an interconnect. A number of groups have shown experimentally that increased surface oxygen concentration, increased moisture content in the dielectric, and an increase in interfacial copper concentration from chemical–mechanical polishing all contribute to accelerated failure. Here, we assumed that all these processes led to an increase in the solubility of metal at the SiO₂/metal. We systematically varied the value of the interfacial solubility, C_e over a wide range and showed that the solubility strongly affects the distribution of copper and the local electric field within the dielectric. This changes the mechanism by which failure occurs from one where copper must penetrate all the way through the dielectric to one where copper penetration is limited to a thin layer near the surface. The solubility levels required to alter the failure mechanism, 10²⁶–10²⁷ atoms/m³, are within the realm of possibility and have been reported in the context of fabricating Cu-SiO₂ resistive switching elements for memory applications.     

Interdiffusion study in the Pd–Pt system

Interdiffusion, intrinsic, tracer and impurity diffusion coefficients are calculated in the Pd–Pt system. Interdiffusion coefficients are more or less insensitive to composition change. Activation energy varies in the range of 324–353 kJ/mol. Impurity diffusion coefficients calculated in this study and available tracer diffusion coefficients in pure elements indicate that Pd has higher diffusion rate compared to Pt in pure Pd, whereas, both the elements have similar diffusion rates in Pt. Kirkendall marker experiments indicate that Pd has much higher diffusion rate in Pd3.5at.%Pt compared to Pt.     

Plug-load densities for energy analysis: K-12 schools

Benchmarking plug-load densities is essential to bypass arbitrary and/or incorrect inputs used in building energy analysis. As more building simulationists play a decision-making role for the design team, they tend to lean on building energy standards and guidelines for preliminary inputs such as plug-load densities. It is necessary for building energy standards and rating systems to implement plug-load density benchmarks to reward design teams in their efforts to reduce plug-load energy use. Using case study buildings, this paper establishes benchmark plug-load densities for K-12 schools under two new categories – classrooms with computers and classrooms without computers. Eighteen K-12 schools including 9 elementary, 2 middle, and 7 high schools are assessed for actual plug-load densities. For the same case study buildings, four existing approaches – NREL, COMNET, ASHRAE 90.1-1989, and Title-24 are evaluated for plug-load densities. Results show under- and over-estimation of plug-load densities over actual densities. The development of benchmark for K-12 schools will pave way for instituting targets for trimming plug-load densities in new and retrofit building projects.     

Friction Buttering: A New Technique for Dissimilar Welding

This work offers a fresh perspective on buttering, a technique often considered for fusion welding of dissimilar metals. For the first time, buttering was attempted in solid state using friction deposition. Using this new “friction buttering” technique, fusion welding of two different dissimilar metal pairs (austenitic stainless steel/borated stainless steel and Al-Cu-Mg/Al-Zn-Mg-Cu) was successfully demonstrated. The results show that friction buttering can simplify a tough dissimilar welding problem into a routine fusion welding task.