Experimental Analysis of Pressure Drop and Laminar to Turbulent Transition for Gas Flows in Smooth Microtubes

The results of numerical and experimental works dealing with the behavior of gas flow through microchannels are by no means univocal, sometimes agreeing with the classical correlations and other times contradicting them. It is now agreed upon that the effects due to both rarefaction and compressibility must be accounted for. In addition, the experimental works have demonstrated that sometimes compressibility and rarefaction effects can be coupled in microchannels: because these two actions contrast each other, the scatter of the friction factor data for gaseous flows is remarkably large. This paper is aimed at determining the friction factor for commercial short and long Peek microtubes with nominal internal diameters between 300 and 100 μ m and values of the length-to-diameter ratio, L/D, ranging between 167 and 5000. Nitrogen flows inside the microtubes, with a maximum value of the supply pressure equal to 10 bar. Very low Knudsen numbers (Kn < 0.001) are considered in order to uncouple the rarefaction effects from the compressibility effects. The role of the minor losses related to the inlet and outlet of the test section and of the gas compressibility on the friction factor are analyzed and discussed in order to draw their limit of significance in microchannels. In addition, the effects of the gas compressibility and of the L/D ratio on the critical Reynolds number for which the laminar to turbulent transition takes place will be analyzed and discussed by comparing the experimental results with the other data published in the literature.     

Atomic‐Resolution Structure of a Class C β‐Lactamase and Its Complex with Avibactam

β‐Lactamases (BLs) are important antibiotic‐resistance determinants that significantly compromise the efficacy of valuable β‐lactam antibacterial drugs. Thus, combinations with BL inhibitor were developed. Avibactam is the first non‐β‐lactam BL inhibitor introduced into clinical practice. Ceftazidime–avibactam represents one of the few last‐resort antibiotics available for the treatment of infections caused by near‐pandrug‐resistant bacteria. TRU‐1 is a chromosomally encoded AmpC‐type BL of Aeromonas enteropelogenes, related to the FOX‐type BLs and constitutes a good model for class C BLs. TRU‐1 crystals provided ultrahigh‐resolution diffraction data for the native enzyme and for its complex with avibactam. A comparison of the native and avibactam‐bound structures revealed new details in the conformations of residues relevant for substrate and/or inhibitor binding. Furthermore, a comparison of the TRU‐1 and Pseudomonas aeruginosa AmpC avibactam‐bound structures revealed two inhibitor conformations that were likely to correspond to two different states occurring during inhibitor carbamylation/recyclization.     

Effect of nanoparticles on heat capacity of nanofluids based on molten salts as PCM for thermal energy storage

In this study, different nanofluids with phase change behavior were developed by mixing a molten salt base fluid (selected as phase change material) with nanoparticles using the direct-synthesis method. The thermal properties of the nanofluids obtained were investigated. These nanofluids can be used in concentrating solar plants with a reduction of storage material if an improvement in the specific heat is achieved. The base salt mixture was a NaNO₃-KNO₃ (60:40 ratio) binary salt. The nanoparticles used were silica (SiO₂), alumina (Al₂O₃), titania (TiO₂), and a mix of silica-alumina (SiO₂-Al₂O₃). Three weight fractions were evaluated: 0.5, 1.0, and 1.5 wt.%. Each nanofluid was prepared in water solution, sonicated, and evaporated. Measurements on thermophysical properties were performed by differential scanning calorimetry analysis and the dispersion of the nanoparticles was analyzed by scanning electron microscopy (SEM). The results obtained show that the addition of 1.0 wt.% of nanoparticles to the base salt increases the specific heat of 15% to 57% in the solid phase and of 1% to 22% in the liquid phase. In particular, this research shows that the addition of silica-alumina nanoparticles has a significant potential for enhancing the thermal storage characteristics of the NaNO₃-KNO₃ binary salt. These results deviated from the predictions of the theoretical model used. SEM suggests a greater interaction between these nanoparticles and the salt.     

Sharp V‐notches in viscoplastic solids: Strain energy rate density rule and fracture toughness

Different from Neuber's rule or Glinka's energy method which are always adopted to characterize the notch tip field under elastoplastic condition, in this paper, the strain energy rate density (SERD) rule is used for viscoplastic materials. In particular, based on the definition of generalized notch stress intensity factor (G‐NSIF) for sharp V‐notch in viscoplastic solids, the concept of SERD for sharp V‐notch in viscoplastic solids is presented. Subsequently, by taking as a starting point the SERD, the averaged strain energy density (SED) for sharp V‐notch in viscoplastic solids is derived with integration of time. The fracture toughness relation between sharp V‐notch specimens and crack specimen in viscoplastic materials is given based on the transformation of SERD. A numerical approach is presented to compute the SERD and SED based on finite element method. Some crucial comments on the G‐NSIF have been discussed. Some typical solutions for SERD and SED for sharp V‐notched specimens are investigated.     

Giant Magnetoresistance in a Molecular Thin Film as an Intrinsic Property

The magnetic, thin‐film structural, conductivity, and magnetoresistance properties of [Ni(quinoline‐8‐thiolate)₂] ([Ni(qt)₂]) are studied. The conducting and magnetoresistance properties are studied in single crystals and in evaporated thin films through deposition on an interdigitated electrode array. Non‐linear conductivity interpreted through a space‐charge limited conduction mechanism with charges injected from the electrodes is observed. Under applied magnetic field, the material displays giant negative magnetoresistance above 50% at 2 K in both single crystals and in evaporated thin films. The effect can still be observed at 200 K and is interpreted in terms of a double exchange mechanism with the shape of the curve determined by the magnetic anisotropy. The unique observation of giant magnetoresistance (GMR) as an intrinsic effect in an evaporated thin film of paramagnetic molecules opens up new possibilities in organic spintronics.     

Coexistence of Grain‐Boundaries‐Assisted Bipolar and Threshold Resistive Switching in Multilayer Hexagonal Boron Nitride

The use of 2D materials to improve the capabilities of electronic devices is a promising strategy that has recently gained much interest in both academia and industry. However, while the research in 2D metallic and semiconducting materials is well established, detailed knowledge and applications of 2D insulators are still scarce. In this paper, the presence of resistive switching (RS) in multilayer hexagonal boron nitride (h‐BN) is studied using different electrode materials, and a family of h‐BN‐based resistive random access memories with tunable capabilities is engineered. The devices show the coexistence of forming free bipolar and threshold‐type RS with low operation voltages down to 0.4 V, high current on/off ratio up to 10⁶, and long retention times above 10 h, as well as low variability. The RS is driven by the grain boundaries (GBs) in the polycrystalline h‐BN stack, which allow the penetration of metallic ions from adjacent electrodes. This reaction can be boosted by the generation of B vacancies, which are more abundant at the GBs. To the best of our knowledge, h‐BN is the first 2D material showing the coexistence of bipolar and threshold RS, which may open the door to additional functionalities and applications.     

MARTe at FTU: The new feedback control

Keeping in mind the necessities of a modern control system for fusion devices, such as modularity and a distributed architecture, an upgrade of the present FTU feedback control system was planned, envisaging also a possible reutilization in the proposed FAST experiment [1]. For standardization and efficiency purposes we decided to adopt a pre-existent ITER-relevant framework called MARTe [2], already used with success in other European Tokamak devices [3]. Following the developments shown in [4], in this paper we report on the structure of the new feedback system, and how it was integrated in the current control structure and pulse programming interface, and in the other MARTe systems already in FTU: RT-ODIN [5] and the ECRH and LH [6] satellite stations. The new feedback system has been installed in the FTU backup station (known as “Feedback B”), which shares the input signals with the actual feedback system, in order to simplify the validation and debug of the new controller by testing it in parallel with the current one. Experimental results are then presented.     

Investigation of gas diffusion layer compression by electrochemical impedance spectroscopy on running polymer electrolyte membrane fuel cells

Two gas diffusion layers based on the same carbon cloth substrate, produced by an Italian Company (SAATI), and coated with microporous layers of different hydrophobicities, were assembled in a polymer electrolyte membrane fuel cell and its performances assessed. For comparison the cell mounting the carbon cloth without microporous layer was also tested. The membrane electrode assembly was made of Nafion^® 212 with Pt load 0.3/0.6 mg cm⁻² (anode/cathode). The cell testing was run at 60 °C and 80 °C with fully humidified air (100%RH) and 80%RH hydrogen feedings. The assembly of gas diffusion layers and membrane with electrodes was compressed to 30% and 50% of its initial thickness. For each configuration polarization and power curves were recorded; in order to evaluate the role of different GDLs, AC impedance spectroscopy of the running cell was also performed.The higher compression ratio caused the worsening of cell performances, partially mitigated when the operating temperature was raised to 80 °C. The presence of the microporous layer onto the carbon cloth resulted extremely beneficial for the operations especially at high current density; moreover, it sensibly reduces the high frequency resistance of the overall assembly.     

MPARM: Exploring the Multi-Processor SoC Design Space with SystemC

Technology is making the integration of a large number of processors on the same silicon die technically feasible. These multi-processor systems-on-chip (MP-SoC) can provide a high degree of flexibility and represent the most efficient architectural solution for supporting multimedia applications, characterized by the request for highly parallel computation. As a consequence, tools for the simulation of these systems are needed for the design stage, with the distinctive requirement of simulation speed, accuracy and capability to support design space exploration. We developed a complete simulation platform for a MP-SoC called MP-ARM, based on SystemC as modelling and simulation environment, and including models for processors, the AMBA bus compliant communication architecture, memory models and support for parallel programming. A fully operating linux version for embedded systems has been ported on this platform, and a cross-toolchain has been developed as well. Our MP simulation environment turns out to be a powerful tool for the MP-SOC design stage. As an example thereof, we use our tool to evaluate the impact on system performance of architectural parameters and of bus arbitration policies, showing that the effectiveness of a particular system configuration strongly depends on the application domain and the generated traffic profile.Luca Benini received the B.S. degree (summa cum laude) in electrical engineering from the University of Bologna, Italy, in 1991, and the M.S. and Ph.D. degrees in electrical engineering from Stanford University in 1994 and 1997, respectively. He is an associate professor in the department of electronics and computer science in the University of Bologna. He also holds visiting researcher positions at Stanford University and the Hewlett-Packard Laboratories, Palo Alto, CA.Dr. Benini’s research interests are in all aspects of computer-aided design of digital circuits, with special emphasis on low-power applications, and in the design of portable systems. He is co-author of the book: Dynamic Power management, Design Techniques and CAD tools, Kluwer 1998.Dr. Benini is a member of the technical program committee for several technical conferences, including the Design Automation Conference, the International Symposium on Low Power Design and the International symposium on Hardware-Software Codesign.Davide Bertozzi received the B.S. degree in electrical engineering from the University of Bologna, Bologna, Italy, in 1999.He is currently pursuing the Ph.D. degree at the same University and is expected to graduate in 2003. His research interests concern the development of SoC co-simulation platforms, exploration of SoC communication architectures and low power system design.Alessandro Bogliolo received the Laurea degree in electrical engineering and the Ph.D. degree in electrical engineering and computer science from the University of Bologna, Bologna, Italy, in 1992 and 1998.In 1995 and 1996 he was a Visiting Scholar at the Computer Systems Laboratory (CSL), Stanford University, Stanford, CA.From 1999 to 2002 he was an Assistant Professor at the Department of Engineering (DI) of the University of Ferrara, Ferrara, Italy. Since 2002 he’s been with the Information Science and Technology Institute (STI) of the University of Urbino, Urbino, Italy, as Associate Professor. His research interests are mainly in the area of digital integrated circuits and systems, with emphasis on low power and signal integrity.Francesco Menichelli was born in Rome in 1976. He received the Electronic Engineering degree in 2001 at the University of Rome “La Sapienza”. From 2002 he is a Ph.D. student in Electronic Engineering at “La Sapienza” University of Rome.His scientific interests focus on low power digital design, and in particular in level tecniques for low power consumption, power modeling and simulation of digital systems.Mauro Olivieri received a Master degree in electronic engineering “cum laude” in 1991 and a Ph.D. degree in electronic and computer engineering in 1994 from the University of Genoa, Italy, where he also worked as an assistant professor. In 1998 he joined the University of Rome “La Sapienza”, where he is currently associate professor in electronics. His research interests are digital system-on-chips and microprocessor core design. Prof. Olivieri supervises several research projects supported by private and public fundings in the field of VLSI system design.