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41.
42.
In this study, we aimed to develop an efficient synthesis and photopolymerization of acrylated methyl ricinoleate (AMR) for biomedical applications. During the first step of the synthesis, methyl ricinoleate (MR) and boric acid were esterified via azeotropic distillation in toluene. Afterward, MR–boric acid ester was acrylated with acrylic acid at 165 °C via a boric acid ester acidolysis reaction. The bulk photopolymerization of AMR was performed in the presence of the photoinitiator 2,2-dimethoxy-2-phenyl acetophenone (DMPA) under 365 nm UV irradiation. Even with the use of 0.4% DMPA, a 35% monomer conversion was achieved within 30 min. Moreover, AMR, the plant-oil-based monomer, was also copolymerized with N-isopropyl acrylamide to obtain thermoresponsive hydrogels on the glass surface for biomedical applications. The synthesized materials were characterized by Fourier transform infrared (FTIR) spectroscopy, 1H-NMR spectroscopy, and thermal characterization via thermogravimetric analysis (TGA) and differential scanning calorimetry techniques. The surfaces were characterized by FTIR and Energy Dispersive X-ray (EDS) spectroscopy. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47969. 相似文献
43.
Emergencies, and efforts to address them, create disruptions to local and global supply chains and surges in demand of emergency resources, which substantially affect global production. Reconfigurable manufacturing systems are promising solutions to improve flexibility and to reduce the effort needed to adapt supply chains and production networks to fit a perturbed environment. This paper proposes a method for coordination of reconfigurable manufacturing resources from multiple enterprises to structure ad-hoc production networks for critical products required in emergencies. Network optimization models and interaction algorithms are integrated to evolve the production network through synchronous machine-level and network-level reconfiguration driven by data. 相似文献
44.
Necati
zkan Cüneyt Oysu Brian J. Briscoe Ismail Aydin 《Journal of the European Ceramic Society》1999,19(16):748-2891
This paper is concerned with a number of means of characterising the rheological properties of a ceramic paste. The intrinsic flow behaviour of the paste, during upsetting, is studied experimentally by using multi coloured paste samples, as well as by a finite element numerical computation. The flow behaviour of the paste is approximated by an elasto-viscoplastic material constitutive model and implemented by using an established finite element code. The material flow properties, which are necessary for the implementation of the numerical model, were obtained using the squeeze film and hardness indentation test configurations. The flow fields generated by the simulation are shown to be a good accord with the experimental observations. The experimental procedure for selecting the material parameters which are necessary for the implementation of the numerical model is described. The accuracy of the numerical method described is also evaluated by comparing the simulation results with experimental data obtained from the net upsetting force against the imposed relative displacement behaviour and the flow visualisation of deformed coloured layers. In these respects, a comparison of the finite element model predictions and the experimental results demonstrates a good mutual agreement. 相似文献
45.
46.
A.E. Ersundu G. Karaduman M. Çelikbilek N. Solak S. Aydin 《Journal of the European Ceramic Society》2010,30(15):3087-3092
The stability of δ-TeO2 phase was studied in binary TeO2–WO3, TeO2–CdO and ternary TeO2–WO3–CdO glasses. The samples were prepared by heating high purity powder mixtures of TeO2, WO3 and/or CdO to 800 °C in a platinum crucible with a closed lid, holding for 30 min and quenching in water bath. Differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques were used to characterize the thermal, phase and microstructural properties of the δ-TeO2 phase. The addition of CdO into the tellurite glasses increased the stability range of the δ-TeO2 phase up to higher temperature values and expanded the compositional δ-TeO2 formation range. The formation of δ-TeO2 phase in the binary systems was observed for samples containing 5–10 mol% WO3 and 5–15 mol% CdO. However, for the ternary TeO2–WO3–CdO system the formation of δ-TeO2 phase was determined in a wider compositional range. 相似文献
47.
The effects of calcium carbonate (CaCO3) particle size on the fusion and rheological behaviors of rigid poly(vinyl chloride) (PVC) composites prepared in a Haake torque rheometer were investigated by means of torque data recorded during processing. Increasing the number of particles in the same blend volume by decreasing the particle size resulted in increasing frictional forces. This increase led in turn to increased fusion torque and decreased fusion time and temperature. The power‐law‐index values of the composites increased with decreasing particle size except for 25‐nm CaCO3. The viscosities of all composites were found to decrease with shear rate; therefore, high pseudoplasticity was observed. At a particular rotor speed, viscosity of the composites decreased with decreasing particle size except for 25‐nm CaCO3. The overall results showed that the particle size of CaCO3 altered the fusion characteristics and rheological behavior of PVC. J. VINYL ADDIT. TECHNOL., 2010. © 2010 Society of Plastics Engineers 相似文献
48.
Yasar Andelib Aydin 《应用聚合物科学杂志》2021,138(18):50339
Composite adsorbent films with amine and hydroxyl functionalities were synthesized from chitosan (CS), polyvinyl alcohol (PVA), and amine-modified carbon nanotubes (a-MWCNT) by solvent casting method. Weight proportions of CS to PVA and weight percent of a-MWCNT were optimized to achieve highest chromate removal capacity. Structural characteristics of the composites were investigated using scanning electron microscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, and thermal gravimetric analysis. Accordingly, incorporation of a-MWCNT to CS/PVA structure resulted in the generation of nanochannels, which enhanced adsorption capacity. Moreover, the composite comprising 0.4% wt. a-MWCNT provided over 99% of Cr (VI) removal from 50 mg L−1 Cr (VI) solution within five minutes of contact time. Redlich–Peterson and Radke–Prausnitz isotherm models provided the highest conformity to adsorption data. Maximum chromate sorption capacity of CS/PVA/a-MWCNT composite film was determined as 134.2 mg g−1 being 172% higher than that of CS/PVA. Regeneration was best achieved in 1.0 M NaOH and the composite was shown to retain at least 70% of its original capacity after five consecutive adsorption–desorption cycles. 相似文献
49.
50.
Gokhan Kilic Erkan Ilik Shams A.M. Issa Bashar Issa M.S. Al-Buriahi U. Gokhan Issever Hesham M.H. Zakaly H.O. Tekin 《Ceramics International》2021,47(13):18517-18531
Different samples of xTeO2.(25-y)B2O3.zV2O5.yYb2O3 (or TBVY) new glass material were synthesized by the classical melt-quenching method. Structural, optical, physical, and thermal analyses of the synthesized glasses were performed in addition to Monte Carlo simulation to test radiation shielding properties. The results showed that increasing ratios of Yb2O3 (y = 0.0, 0.5, 1.0, and 1.5 mol%) produced monotonic density values of the synthesized glasses ranging from 4.70058 g cm?3 to 5.01038 g cm?3. XRD and FTIR analyses were used to confirm the glass structure of all samples. Optical transmittance and absorption parameters varied almost monotonically with increasing ratios of Yb2O3 indicating the ability to predict and control these properties using Yb2O3 additive. Furthermore, simulated radiation interaction parameters, such as attenuation coefficients and half-value layer, exhibited well-behaved dependence on the concentration ratio of the Yb2O3 additive. This approach to glass material synthesis demonstrate the useful synergetic effect of combining structural, optical, and radiation characteristics. 相似文献