Bending-Torsion Response of Rib-Reinforced Cantilever Plates

The objective of this paper is to present the feasibility of applying Vlasov's theory of thin walled bars to model the behavior of rib-reinforced cantilevered plates. A simple analytical model based on Vlasov's theory is presented and validated against experimental results. It is shown that the presented theoretical method is simple and sufficiently accurate to be used as a design tool. The presented approach is also valid for plates fabricated from composite materials.     

When cognitive exertion does not yield cognitive gain: Toward an informational explanation of learned helplessness.

This study tested a new information-processing explanation of learned helplessness that proposes that an uncontrollable situation produces helplessness symptoms because it is a source of inconsistent, self-contradictory task information during problem-solving attempts. The flow of such information makes hypothesis-testing activity futile. Prolonged and inefficient activity of this kind leads in turn to the emergence of a state of cognitive exhaustion, with accompanying performance deficits. In 3 experiments, Ss underwent informational helplessness training (IHT): They were sequentially exposed to inconsistent task information during discrimination problems. As predicted, IHT was associated with subjective symptoms of irreducible uncertainty and resulted in (a) performance deterioration on subsequent avoidance learning, (b) heightened negative mood, and (c) subjective symptoms of cognitive exhaustion. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Scandium(III) Triflate‐Catalyzed anti‐Markovnikov Hydrothiolation of Functionalized Olefins

Scandium(III) triflate promoted highly selective addition of thiols to functionalized olefins under mild conditions. The addition follows anti‐Markovnikov regioselectivities, which are unusual for Lewis acids‐catalyzed hydrothiolation. This reaction marks broad functional groups tolerance, which opens a beneficial synthetic route to functionalized and biologically active thio‐compounds. This method is broadly applicable and offers a simple work‐up in the green manner.

     

A comprehensive study of soft magnetic materials based on FeSi spheres and polymeric resin modified by silica nanorods

A novel soft magnetic composite (SMC) based on spherical FeSi particles precisely covered by hybrid phenolic resin was designed. The hybrid resin including silica nano-rods chemically incorporated into the phenolic polymer matrix was prepared by the modified sol–gel method. A chemical bridge connecting silica nano-rods with the base polymeric net was verified by FTIR, ¹³C and ²⁹Si NMR spectroscopy, whereas the shape and size of silica nano-rods were determined by TEM. It is shown that the modification of polymeric resin by silica nano-rods generally leads to the improved thermal and mechanical properties of the final samples. The hybrid resin serves as a perfect insulating coating deposited on FeSi particles and the core–shell particles can be further compacted by standard powder metallurgy methods in order to prepare final samples for mechanical, electric and magnetic testing. SEM images evidence negligible porosity, uniform distribution of the hybrid resin around FeSi particles, as well as, dimensional shape stability of the final samples after thermal treatment. The hardness, flexural strength and density of the final samples are comparable to the sintered SMCs, but they simultaneously exhibit much higher specific resistivity along with only slightly lower coercivity and permeability.     

Charge transfer and partial pinning at the contacts as the origin of a double dip in the transfer characteristics of graphene-based field-effect transistors

We discuss the origin of an additional dip other than the charge neutrality point observed in the transfer characteristics of graphene-based field-effect transistors with a Si/SiO2 substrate used as the back-gate. The double dip is proved to arise from charge transfer between the graphene and the metal electrodes, while charge storage at the graphene/SiO2 interface can make it more evident. Considering a different Fermi energy from the neutrality point along the channel and partial charge pinning at the contacts, we propose a model which explains all the features observed in the gate voltage loops. We finally show that the double dip enhanced hysteresis in the transfer characteristics can be exploited to realize graphene-based memory devices.     

Electrical properties of anisotype n-CdO/p-Si heterojunctions

An n-CdO/p-Si heterojunction is fabricated by the deposition of a thin cadmium-oxide film with n-type conductivity onto a polished polycrystalline p-Si wafer by the spray-pyrolysis technique. The I-V characteristics of the heterostructure are measured at different temperatures. It is established that the current through the investigated heterostructure at the forward bias 3kT/e < V < 0.5 V is formed by tunneling-recombination processes with the participation of surface states at the CdO/Si interface and at V > 0.5 V, by tunneling through the space-charge region. The dominant mechanisms of current transport at reverse bias are the Frenkel-Pull emission and tunneling with the participation of energy levels formed by surface states.     

Synchronizations in Team Automata for Groupware Systems

Team automata have been proposed in Ellis (1997) as a formal framework for modeling both the conceptual and the architectural level of groupware systems. Here we define team automata in a mathematically precise way in terms of component automata which synchronizeon certain executions of actions.At the conceptual level, our model serves as a formal framework in whichbasic groupware notions can be rigorously defined and studied.At the architectural level, team automata can be used as building blocksin the design of groupware systems.     

The linear landscape of external contextual languages

The class of external contextual languages isstrictly included in the class of linear languages. A reason for the strict inclusion in linear languages is that external contextual grammars generate languages in the exhaustive way: each sentential form belongs to the language of a grammar. In this paper we study the effect of adding various squeezing mechanisms to the basic classes of exhaustive contextual grammars. We obtain in this way a characterization of linear languages and a whole landscape of sublinear families. By restricting the contexts to be one-sided (only left-sided or only right-sided) we obtain a characterization of regular languages — here the subregular landscape reduces to two families.     

Structure and electrochemical reactivity of new sulphur–silicon podands adsorbed on silver or gold surfaces

By the self-assembly monolayer (SAM) organization, three new podands belonging to silylpropanethiols have been tested as to their ability to form nanolayers protecting the noble metal surface (gold or silver) and to form complexes with monovalent metal cations on the metal surfaces. The stable self-assembled chemisorbed layers, providing protection to metal surface against electrooxidation and capable of blocking propylene carbonate (PC) electroreduction and Li electrodeposition were produced. Reflection-absorption infrared spectroscopy (RAIRS) indicated cleavage of the S–H bond upon adsorption of species 1–3 with the formation of S–Ag bonds on the metal surface. By cyclic voltammetry, it was found that the primary adsorbate formed on a Au electrode at E _ad (between −0.2 and −1.2 V vs. SCE) underwent reductive desorption at E < −1.3 V vs. SCE. The structures of 1–3 and their complexes with Na⁺ cations on the Ag surfaces were calculated and visualized by the AM1d semi-empirical method.