Penetration of nanoparticles through fibrous filters perforated with defined pinholes

This paper presents experimental data for penetration of nanoparticles in the 4–30 nm size range through fibreglass filters perforated with defined pinholes at 5 and 15 cm/s. Results show that, when the filter is damaged, penetration increases with decreasing particle diameter. This lower performance is more significant for filters with high airflow resistance. A model explaining the experimental data has been designed based on balanced, laminar airflow inside the pinhole; these conditions were confirmed by detailed study. The experimental points agreed very closely with this model.     

Clinical Determination of Dry Body Weight

While nephrologists wait for the ideal, non invasive, inexpensive, precise, and reproducible tool to evaluate extracellular volume (ECV), they need to exert their clinical acumen in the quest of that holy grail, dry weight (DW). Estimation of DW using a clinical approach based on blood pressure (BP) and ECV is feasible and reliable as shown by successful experiences in various dialysis modes over more than three decades. But a need still exists to resolve difficulties associated with accurate assessment of BP (methods and circumstances of measurement, and the confounding effects of antihypertensive drugs) and ECV (evaluation of weight changes unrelated to ECV, lack of specificity and sensitivity of clinical symptoms, lag time, confusion in terminology). An essential point in clinical assessment of DW is that a normal BP is at the same time the target and the crucial index of DW achievement. For this reason, a trialand‐error “probe” process has to be used at intervals to make sure that the dry weight target point is correctly estimated. The various “non clinical” methods proposed for dry weight assessment increase the complexity and the cost of hemodialysis. They are, in the present state of things, more clinical research than practice tools. They do not replace clinical judgment.     

Simulated annealing for maximum a posteriori parameter estimationof hidden Markov models

Hidden Markov models are mixture models in which the populations from one observation to the next are selected according to an unobserved finite state-space Markov chain. Given a realization of the observation process, our aim is to estimate both the parameters of the Markov chain and of the mixture model in a Bayesian framework. We present an original simulated annealing algorithm which, in the same way as the EM (expectation-maximization) algorithm, relies on data augmentation, and is based on stochastic simulation of the hidden Markov chain. This algorithm is shown to converge toward the set of maximum a posteriori (MAP) parameters under suitable regularity conditions     

Nonlinear Modeling of Flexible Cable Loads on Large Sheaves

Stress analysis of the components of a sheave used to transfer loads between the lift span and counterweight in a movable span bridge is investigated. Stress analysis is a requirement for properly designing such sheaves. Modeling of the mechanism of load transfer from the wire ropes to the sheave is accomplished in three ways: (1) the traditional manner using a uniform pressure distribution; (2) using a varying pressure distribution developed from belt/pulley theory; and (3) using the finite-element method with nonlinear contact elements between the wire rope and the sheave. Internal stresses in the sheave are calculated using uniform distributed pressure and a varying pressure distribution. It is determined that the load distribution on the sheave from the wire ropes is precisely the same for the nonlinear contact analysis and the belt/pulley analysis. The internal stress analysis results show that the traditional, uniformly distributed load representation is less conservative than the more realistic belt/pulley load representation. A methodology is developed that can be utilized to more accurately model the load transfer representation without the complexity of nonlinear analyses.     

Experimental characterization of the chaotic dynamics of cohesionless particles: application to a V-blender

So far, most of the investigations of the dynamics of granular material in blenders have been done in 2D tumblers due to the current lack of accurate measurement methods for the investigation of complex 3D flows. However, recent advances in the field of non-intrusive methods have paved the way to the characterization of the chaotic dynamics in 3D blenders. This work aims to present such an analysis in the case of a V-blender using radioactive particle tracking (RPT). Special attention is given to the chaotic properties of mixing by performing a time-series analysis of the position of a single tracer in motion in this blender. An original investigation of the mixing properties is also presented. More generally, this work shows that the mixing properties of a blender can be characterized by using tools of dynamical systems theory through a time-series analysis of data obtained from non-intrusive measurements.     

Extraction of Finite Element Basis Functions From the Cellular Topology of Meshes

This paper is devoted to the presentation of a simple but powerful topological approach for the computation of basis functions involved in the expression of finite element interpolants. It deals with the so-called nodal and edge elements but similar considerations can be made for the construction of facet ones. All standard cells are treated including pyramids.     

Canadian Total Diet Study in 1998: pesticide levels in foods from Whitehorse, Yukon, Canada, and corresponding dietary intake estimates.

The Canadian Total Diet Study is a national survey to determine the level of chemical contaminants in the Canadian food supply. Food samples were collected from Whitehorse, Yukon, supermarkets as part of the study in 1998. Whitehorse was chosen as a sampling centre, despite its small population (n = 19,000), to determine if residue levels were different in foods available in northern communities relative to levels observed in previous studies in the more populated south. Foods were prepared as for consumption before pesticide residue analysis. Residue levels observed in most foods were similar to levels observed in samples from previous surveys from southern Canadian cities. Malathion and DDE (1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene), a transformation product of DDT (1,1,1-trichloro-2,2-bis(p-chlorophenyl(ethane), were the two most frequently detected compounds (26.4 and 25.8%, respectively). The majority of pesticides, however, had a detection frequency of < 5%. In general, pesticides in food composites were well below maximum residue limits established in the Canadian Food and Drug Regulations. Chlorpropham and captan had the highest dietary intakes (2.16 and 1.94 micrograms (kg body weight-day)-1, respectively), based on the results from Whitehorse. No dietary intakes above the acceptable daily intakes, however, were observed for any of the 39 pesticides investigated in any age-sex category, where an acceptable daily intake has been proposed.     

Sooting tendencies of primary reference fuels in atmospheric laminar diffusion flames burning into vitiated air

In this study, the sooting tendencies of primary reference fuels (PRFs) are measured in term of yield sooting indices (YSIs) in methane diffusion flames doped with the vapors of PRFs. The present paper represents an incremental advance complementing the original methodology prescribed by McEnally and Pfefferle. The influence of both PRF formulation and CO₂ dilution of the coflowing air on the YSIs is also assessed. The diffusion flames burning in a coflowing oxidizer stream are established over the Santoro’s burner and vapor of the liquid fuel to be investigated is injected into the fuel stream. Laser extinction measurements are performed to map the two-dimensional field of soot volume fraction in the flame. For the pure liquid hydrocarbons investigated, i.e., n-hexane, n-heptane, isooctane, and benzene, the YSI reported in the original paper by McEnally and Pfefferle quantitatively predict the sooting propensities, measured here at much higher dopant concentrations. The present study therefore extends the consistency of the YSI methodology on the Santoro’s burner. For blends of n-heptane and isooctane, the sooting tendency of doped flames exhibits regular and monotonic trends and decreases with increasing n-heptane mole fraction or CO₂ dilution. Interestingly, the evolution of YSI with the isooctane mole fraction exhibits a strong similarity for varying CO₂ mole fraction. A quadratic least-squares fit is then derived, providing a phenomenological model of YSI as a function of both isooctane mole fraction in the fuel stream and CO₂ mole fraction in the oxidizer. A non-negligible cross effect of PRF formulation and CO₂ dilution on YSI is revealed. The method elaborated within the framework of the present paper could be extended to surrogate fuels. This would help develop a comprehensive database and empirical correlations that could predict the sooting propensities of different surrogate fuels, therefore their potentially mitigationed soot production through control of fuel composition and/or exhaust gas recirculation. This database would also be useful for the validation of CFD simulations incorporating sophisticated model of soot production.     

New insights into the peculiar behavior of laminar burning velocities of hydrogen–air flames according to pressure and equivalence ratio

Hydrogen is a clean and energetic fuel, and its oxidation mechanism is a subset of the oxidation mechanisms of all hydrocarbons. Therefore, the validation of the available kinetic schemes is of great importance. In the current study, experimental measurements of laminar flame speeds and modeling studies were performed for H₂–air premixed flames over a wide range of equivalence ratios (0.5–4.0) and pressures (0.2–3 bar). The large scale in mixture and thermodynamic conditions allows a better understanding of the peculiar behavior of hydrogen flame speeds with pressure. Two very recent detailed chemical kinetic mechanisms for hydrogen combustion were selected. Excellent agreement was observed between calculations and experimental results, confirming the validity of the kinetic schemes selected. The kinetic analyses performed allow proposing an explanation for the nonmonotonic variation of hydrogen/air flame speed with pressure observed in the experiments.