THE SIZE EFFECT OF MICROSTRUCTURAL IMPLICATIONS OF THE WEAKEST LINK MODEL

Abstract— CT specimens made of a reactor pressure vessel steel were loaded at—40°C until final failure occurred by cleavage fracture. The samples of J _lcl values obtained in these tests are analysed using the weakest link model. The size effect observed with specimens of different thicknesses is compared with the predictions of the weakest link model. A formula is derived for the distribution of the locations of fracture origins which have been determined for almost all specimens with a scanning electron microscope. The distribution of the size of the "weak spots" is calculated from the distribution of the fracture origins using two different models for the stress field ahead of the crack tip. These fractographic results and the J _lcl data confirm the basic ideas of the weakest link model. The deviations observed between the quantitative predictions of the weakest link model and the data can partly be explained by the change in the stress state ahead of the crack tip caused by a change in the specimen thickness.     

Water Affinity to Epitaxial Graphene: The Impact of Layer Thickness

The sensitivity to water vapour of one‐, two‐, and three‐layer epitaxial graphene (1, 2, and 3LG) is examined in this study. It is unambiguously shown that graphene's response to water, as measured by changes in work function and carrier density, is dependent on its thickness, with 1LG being the most sensitive to water adsorption and environmental concentration changes. This is furthermore substantiated by surface adhesion measurements, which bring evidence that 1LG is less hydrophobic than 2LG. Yet, surprisingly, it is found that other contaminants commonly present in ambient air have a greater impact on graphene response than water vapor alone. This study indicates that graphene sensor design and calibration to minimize or discriminate the effect of the ambient, in which it is intended to operate, are necessary to insure the desired sensitivity and reliability of sensors. The present work will aid in developing models for realistic graphene sensors and establishing protocols for molecular sensor design and development.     

Microfluidic push-pull probe for scanning electrochemical microscopy

This paper presents a microfluidic push-pull probe for scanning electrochemical microscopy (SECM) consisting of a working microelectrode, an integrated counter/reference electrode and two microchannels for pushing and pulling an electrolyte solution to and away from a substrate. With such a configuration, a droplet of a permanently renewed redox mediator solution is maintained just at the probe tip to carry out SECM measurements on initially dry substrates or in microenvironments. For SECM imaging purposes, the probe fabricated in a soft polymer material is used in a contact regime. SECM images of various gold-on-glass samples demonstrate the proof-of-concept of a push-pull probe for local surface activity characterization with high spatial resolution even on vertically oriented substrates. Finite element computations were performed to guide the improvement of the probe sensitivity.     

Modeling the decay of ammonium oxidizing bacteria

A bench-scale sequencing batch reactor was used to study factors affecting the endogenous decay of the ammonium oxidizing biomass (AOB) in different operating conditions. AOB decay was very sensitive to oxygen concentration, and increased up to 0.4 d⁻¹ for oxygen concentration of 7 mg O₂ L⁻¹. The decay in anaerobic conditions was shown to be very low (0.03 d⁻¹) when compared to literature data.The effect of nitrite and nitrate on AOB decay was also studied. The correlation was quite weak suggesting that both nitrate and nitrite absence had little impact on decay which is contrary to what is typically assumed in some of the existing process models. A simple expression for the decay of AOB was proposed, calibrated and validated using the results of batch kinetic tests and of the continuous sequencing batch reactor monitoring.     

Projection or Persuasive Press? Contrary Effects of Personal Opinion and Perceived News Coverage on Estimates of Public Opinion

This study explores the effects of personal opinion and perceived media content on individuals' assessments of public opinion, as well as the curious phenomenon that, although people perceive public agreement with their own point of view, they tend to see press coverage as disagreeable. One hypothesis, based on theories of projection of personal opinion, predicts that people will see public opinion as much like their own, but a contrary outcome is suggested by 2 interrelated hypotheses, the hostile media effect and the persuasive press inference. Data were collected on 4 issues from a large, representative national sample and provided evidence for all 3 effects. Projection received the most consistent support, but findings indicate that this assimilation effect can be substantially offset by media coverage seen as both disagreeable and influential.