ZK60和ZK60-1.0Er镁合金热压缩变形和加工图

采用Gleeble-1500D热模拟试验机对ZK60和ZK60-1.0Er镁合金进行了热压缩实验,分析了合金在温度为160~420℃,应变速率为0.0001~1.0s-1条件下的流变应力变化特征。结果表明:两种镁合金在热压缩过程中的流变应力随变形温度的降低和应变速率的升高而增加,在流变应力达到峰值后随即进入稳态流变;稀土Er的加入使得平均变形激活能珚Q值由183kJ/mol降到153kJ/mol,应力指数n值由6提高到8;发生动态再结晶的临界应力σc值随变形温度升高和应变速率降低而降低,在420℃/1.0s-1高温高应变速率时,稀土Er的加入使得ZK60镁合金发生动态再结晶的临界应力值σc由76MPa降到50MPa。通过动态模型构建热加工图并结合金相组织观察可知:稀土Er的加入缩小了ZK60镁合金的热加工失稳区,增加了热加工安全区的功率耗散效率峰值η_(max),由35%增大到45%,促进了动态再结晶晶粒的形核,但抑制了再结晶晶粒的长大。     

Partikelform und Porosität von biogenen Pyrolysekoksen

Char particles from pyrolyzed biomass vary in particle size and shape. On average, the particles are more elongated the larger their size. The average size‐specific elongation is almost alike for all investigated samples, i.e. independent from their source material and process. The particle collectives cannot be characterized accurately with classical particle size distributions, which assume spherical particle shape. Accounting for their shape, they can be described more accurately with particle size distributions that are based on an ellipsoid model. The high bulk porosity is mainly attributed to the spaces between particles.     

Production and Characterization of Peptide Antibodies to the C-Terminal of Frameshifted Calreticulin Associated with Myeloproliferative Diseases

Myeloproliferative Neoplasms (MPNs) constitute a group of rare blood cancers that are characterized by mutations in bone marrow stem cells leading to the overproduction of erythrocytes, leukocytes, and thrombocytes. Mutations in calreticulin (CRT) genes may initiate MPNs, causing a novel variable polybasic stretch terminating in a common C-terminal sequence in the frameshifted CRT (CRTfs) proteins. Peptide antibodies to the mutated C-terminal are important reagents for research in the molecular mechanisms of MPNs and for the development of new diagnostic assays and therapies. In this study, eight peptide antibodies targeting the C-terminal of CRTfs were produced and characterised by modified enzyme-linked immunosorbent assays using resin-bound peptides. The antibodies reacted to two epitopes: CREACLQGWTE for SSI-HYB 385-01, 385-02, 385-03, 385-04, 385-07, 385-08, and 385-09 and CLQGWT for SSI-HYB 385-06. For the majority of antibodies, the residues Cys¹, Trp⁹, and Glu¹¹ were essential for reactivity. SSI-HYB 385-06, with the highest affinity, recognised recombinant CRTfs produced in yeast and the MARIMO cell line expressing CRTfs when examined in Western immunoblotting. Moreover, SSI-HYB 385-06 occasionally reacted to CRTfs from MPN patients when analysed by flow cytometry. The characterized antibodies may be used to understand the role of CRTfs in the pathogenesis of MPNs and to design and develop new diagnostic assays and therapeutic targets.     

某型柴油机连杆断裂原因分析

首先从理论上分析了某型柴油机连杆在大端的螺纹孔处断裂的原因,接着从加工工艺上找出了连杆大端螺纹孔的薄弱环节,然后通过连杆疲劳试验,验证了连杆大端螺纹孔的薄弱环节导致连杆断裂,最后提出了加工以及质量管理的改进建议。     

基于改进遗传算法的继电保护一体化图形 拼接厂站最优布局

继电保护整定计算在电力系统广泛采用分布式整定计算模式,在继电保护整定计算模型拼接中,图形拼接部分存在着接线混乱的问题。深入研究了一体化继电保护图形拼接的特点,结合厂站电压等级,提出了基于改进遗传算法的继电保护一体化图形拼接方法。为了提高图形拼接的效率,采用按电压等级分层寻优的方式确定最优厂站布局。最后通过实际算例验证了该方法的快速性及有效性。     

回火温度对高碳钢断裂韧性的影响

研究了回火温度对高碳钢断裂韧性及其他力学性能的影响。利用紧凑拉伸试样测量其平面应变断裂韧度,扫描电镜(SEM)观察回火后的组织演变规律及断裂韧度试样断口形貌。结果表明:随着回火温度的升高,马氏体逐渐分解消失,从过饱和α固溶体中析出的碳化物数量逐渐增多并发生聚集长大,强度和硬度下降,塑性、断裂韧性和冲击韧性上升。位错强化和固溶强化作用减弱是试验钢强度降低、韧性升高的主要原因。     

基于组合峰值功率测试的锂离子电池性能评价方法

电池峰值功率和能量对提高电动汽车电机输出能力和续航里程有重要的理论意义和实用价值,是评价锂离子电池性能的重要参数.为解决复合脉冲和日本电动汽车协会标准(JEVS)峰值功率测试方法在放电低端和充电高端易达到截止电压的问题,提出了一种混合脉冲功率特性(HPPC)测试和反向传播(BP)神经网络相结合的峰值功率测试方法,在保证准确率的条件下快速获得放电低端和充电高端的峰值功率值.在此基础上,建立了一种以比能量和比功率为核心的电池性能评价体系,提出了基于德尔菲法确定权重系数的电池综合性能评价方法,为快速准确选择电池提供依据.     

适应于光伏电站主变压器的差动保护工作模

光伏电站主变压器产生的合闸涌流,经过电流互感器（current transformer,CT）传变后,其二次谐波比会有所提高,若同时发生区内故障,光伏逆变器的短路电流会带来额外高含量的二次谐波,这将导致主变压器差动保护在涌流闭锁期间无法及时切除故障。根据主变压器差动电流基波与二次谐波的相位差变化特征,提出一种防止保护拒动的工作模式,甄别出涌流闭锁过程中的故障发生时刻,并依据涌流与区内故障时的二次谐波比差异,及时提高故障时刻定值,以避免保护闭锁。借助PSCAD/EMTDC软件,验证故障定值选取后差动电流的二次谐波比变化和保护动作情况,结果表明,所提光伏电站主变压器差动保护工作模式区分性能优异,能够可靠切除涌流过程中发生的区内故障。     

不同硅铝比Hβ沸石对二甲苯异构体吸附动力学的研究

通过静态吸附实验,测定了常温下对二甲苯和间二甲苯在不同硅铝比(SiO2与Al2O3的摩尔比)Hβ沸石上的吸附动力学数据。实验结果表明,Hβ沸石对对二甲苯和间二甲苯的平衡吸附量均随对二甲苯和间二甲苯初始浓度的增加而升高,相同条件下对二甲苯在Hβ沸石上的吸附量和吸附速率均大于间二甲苯;对二甲苯/间二甲苯在硅铝比为25和280及全硅Hβ沸石上的平衡分离系数分别为4.1,1.7,1.6,硅铝比为25的Hβ沸石吸附分离对二甲苯/间二甲苯的效果最好。对二甲苯在Hβ沸石上的吸附过程符合二级吸附动力学方程,间二甲苯在Hβ沸石上的吸附动力学数据与颗粒内扩散模型有较好的相关性。     

Study of the Li insertion into V2O5 films deposited by CVD onto various substrates

Vanadium oxide films were synthesised by chemical vapour deposition (CVD) from pure of triisopropoxyvanadium oxide (VO(OC₃H₇)₃) and oxygen as precursors. The influence of the substrate on the crystallinity of the vanadium oxide films was studied before and after annealing at 500 °C. On mica substrates, as-deposited film was composed of crystalline V₂O₅ as revealed by XRD. On Pt, Ti, stainless steel, glass and F-doped SnO₂ substrates, an annealing procedure was required to get V₂O₅. SEM investigations have clearly evidence V₂O₅ plates but the kinetics growth seems to be strongly dependent on the nature of the substrate. The insertion/extraction of Li⁺ into the host structure was investigated in 1 M LiClO₄-PC with annealed V₂O₅ films deposited on Ti, Pt and stainless steel substrates. The best electrochemical performances were obtained in the potential range 3.8–2.8 V versus Li/Li⁺ with V₂O₅ films deposited onto stainless steel substrate: the reversible capacity reaches after subsequent cycles was about 115 mAh g⁻¹ (rate C/23). In a wider potential range (between 3.8 and 2.2 V versus Li/Li⁺), V₂O₅ deposited onto Ti substrate exhibited the higher electrochemical performances (220 mAh g⁻¹ for a rate of C/23).