Online coupling of gas chromatography to nuclear magnetic resonance spectroscopy: method for the analysis of volatile stereoisomers

The identification of volatile cis/trans-stereoisomers was accomplished by employing a hyphenated GC-NMR system. The chromatographic and spectroscopic conditions were optimized with respect to the (1)H NMR detection. A special processing technique was developed to handle the recorded NMR spectra in the gas phase with very low sample amounts. The processed stopped-flow (1)H NMR spectra of the investigated chromatographic peaks unequivocally revealed the structure of the corresponding compounds.     

Potassium-selective electrodes with stable and geometrically well-defined internal solid contact based on nanoparticles of polyaniline and plasticized poly(vinyl chloride)

Solid contact potassium-selective electrodes with the internal ion-to-electron transduction layer composed of plasticized poly(vinyl chloride) (PVC) and 2-20% (m/m) of polyaniline (PANI) nanoparticles, with the mean particle size of 8 nm, have been studied in this paper. UV-vis measurements in pH buffer solutions between pH 0 and 12 show that the electrically conducting emeraldine salt (ES) form of PANI has exceptionally good pH stability. Membranes of PANI nanoparticles were mainly in the ES form even at pH 12, in contrast to electrochemically prepared PANI(Cl) films, which are converted completely to the nonconducting form already at pH 6. Long-term UV-vis measurements with the PANI membranes in contact with aqueous buffer solution at pH 7.5 showed no degradation of the ES form. The PANI nanoparticles are homogenously mixed in the PVC-based solid contact (SC) layer. Only the uppermost part of the SC layer is to a minor extent dissolved in the outer potassium-selective PVC membrane. This enabled the preparation of geometrically well-defined inner SC layers, thus improving the reproducibility of the solid contact electrodes and resulting in good mechanical strength between the inner and outer membranes.     

A tool for safety evaluations of road improvements

Road safety impact assessments are requested in general, and the directive on road infrastructure safety management makes them compulsory for Member States of the European Union. However, there is no widely used, science-based safety evaluation tool available. We demonstrate a safety evaluation tool called TARVA. It uses EB safety predictions as the basis for selecting locations for implementing road-safety improvements and provides estimates of safety benefits of selected improvements. Comparing different road accident prediction methods, we demonstrate that the most accurate estimates are produced by EB models, followed by simple accident prediction models, the same average number of accidents for every entity and accident record only. Consequently, advanced model-based estimates should be used. Furthermore, we demonstrate regional comparisons that benefit substantially from such tools. Comparisons between districts have revealed significant differences. However, comparisons like these produce useful improvement ideas only after taking into account the differences in road characteristics between areas. Estimates on crash modification factors can be transferred from other countries but their benefit is greatly limited if the number of target accidents is not properly predicted. Our experience suggests that making predictions and evaluations using the same principle and tools will remarkably improve the quality and comparability of safety estimations.     

Authentication of Particulate Air Samples by Aerosol

A method was developed for the protection of aerosol filters against tampering that can be applied to any particulate sampler. In this method, tagged particles are dispersed into the sampled aerosol volume by liquid atomization to guarantee homogeneous distribution of the tag and deposition into the filter matrix. The tagged aerosols are collected insitu, together with the sampled dust particles. The tag can be measured in different ways. This feature can be used for self protection of the method. The authentication of the individual filters is preserved through the lifetime of the filter sample. Long-term field tests of the equipment indicate reliable performance.     

Application of CFD (Fluent) to LNG spills into geometrically complex environments

Recent discussions on the fate of LNG spills into impoundments have suggested that the commonly used combination of SOURCE5 and DEGADIS to predict the flammable vapor dispersion distances is not accurate, as it does not account for vapor entrainment by wind. SOURCE5 assumes the vapor layer to grow upward uniformly in the form of a quiescent saturated gas cloud that ultimately spills over impoundment walls. The rate of spillage is then used as the source term for DEGADIS. A more rigorous approach to predict the flammable vapor dispersion distance is to use a computational fluid dynamics (CFD) model. CFD codes can take into account the physical phenomena that govern the fate of LNG spills into impoundments, such as the mixing between air and the evaporated gas. Before a CFD code can be proposed as an alternate method for the prediction of flammable vapor cloud distances, it has to be validated with proper experimental data. This paper describes the use of Fluent, a widely-used commercial CFD code, to simulate one of the tests in the "Falcon" series of LNG spill tests. The "Falcon" test series was the only series that specifically addressed the effects of impoundment walls and construction obstructions on the behavior and dispersion of the vapor cloud. Most other tests, such as the Coyote and the Burro series, involved spills onto water and relatively flat ground. The paper discusses the critical parameters necessary for a CFD model to accurately predict the behavior of a cryogenic spill in a geometrically complex domain, and presents comparisons between the gas concentrations measured during the Falcon-1 test and those predicted using Fluent. Finally, the paper discusses the effect vapor barriers have in containing part of the spill thereby shortening the ignitable vapor cloud and therefore the required hazard area. This issue was addressed by comparing the Falcon-1 simulation (spill into the impoundment) with the simulation of an identical spill without any impoundment walls, or obstacles within the impoundment area.     

Evidence for unpinned magnetic flux vortices above theIctransition in the 2223-phase high-Tcsuperconductor

A similarity in the dc voltage-current (V-I) curves for both direct and alternating transport currents is used to propose that unpinned flux vortices are generated above theI _ctransition for dc transport currents, when Abrikosov flux vortices begin to penetrate the superconductor. Two methods can be used to give a dc voltage drop for an ac transport current: (1) if there is a slight dc offset voltage in the ac current which favors vortex loop collapse as in a traditional dcI _ctest, or (2) if an asymmetric transverse magnetic field is present which favors vortex loop collapse for current in one direction over the reverse direction.     

The National Ignition Facility and Industry

The mission of the National Ignition Facility is to achieve ignition and gain in inertial confinement fusion targets in the laboratory. The facility will be used for defense applications such as weapons physics and weapons effects testing, and for civilian applications such as fusion energy development and fundamental studies of matter at high temperatures and densities. The National Ignition Facility construction project will require the best of our construction industries and its success will depend on the best products offered by hundreds of the nation's high technology companies. Three-fourths of the construction costs will be invested in industry. This article reviews the design, cost and schedule, and required industrial involvement associated with the construction project.     

Discovering functional and inclusion dependencies in relational databases

We consider the problem of discovering the functional and inclusion dependencies that a given database instance satisfies. This technique is used in a database design tool that uses example databases to give feedback to the designer. If the examples show deficiencies in the design, the designer can directly modify the examples. the tool then infers new dependencies and the database schema can be modified, if necessary. the discovery of the functional and inclusion dependencies can also be used in analyzing an existing database. the problem of inferring functional dependencies has several connections to other topics in knowledge discovery and machine learning. In this article we discuss the use of examples in the design of databases, and give an overview of the complexity results and algorithms that have been developed for this problem. © 1992 John Wiley & Sons, Inc.     

Microscopic studies of the influence of technological conditions on technical parameters of photopolymer flexographic plates

The quality of printing plates is one of the important factors influencing the accuracy of flexographic printed copies. The essential technological parameters determining the quality of flexographic plates comprise the dot gain, resolution, and profile of the printing elements. In this work, these parameters were studied using stereoscopic microscopy. These studies enabled us to determine the effect of technological parameters of photochemical preparation of flexographic plates on their resolution, tone transfer characteristics, and the profile of printing elements. It has been found that the quality of flexographic plates depends on the time of the preliminary and the main exposure of the photopolymer plates, the time of solvent washout, and the washout brushes height.     

A Posteriori Estimates Using Auxiliary Subspace Techniques

A posteriori error estimators based on auxiliary subspace techniques for second order elliptic problems in \(\mathbb {R}^d\ (d\ge 2)\) are considered. In this approach, the solution of a global problem is utilized as the error estimator. As the continuity and coercivity of the problem trivially leads to an efficiency bound, the main focus of this paper is to derive an analogous effectivity bound and to determine the computational complexity of the auxiliary approximation problem. With a carefully chosen auxiliary subspace, we prove that the error is bounded above by the error estimate up to oscillation terms. In addition, we show that the stiffness matrix of the auxiliary problem is spectrally equivalent to its diagonal. Several numerical experiments are presented verifying the theoretical results.