Calculated effects of backscattering on skin dosimetry for nuclear fuel fragments

The size of hot particles contained in nuclear fallout rangesfrom 10 nm to 20 µm for the worldwide weapons fallout.Hot particles from nuclear power reactors can be significantlybigger (100 µm to several millimetres). Electron backscatteringfrom such particles is a prominent secondary effect in betadosimetry for radiological protection purposes, such as skindosimetry. In this study, the effect of electron backscatteringdue to hot particles contamination on skin dose is investigated.These include parameters such as detector area, source radius,source energy, scattering material and source density. The Monte-CarloNeutron Particle code (MCNP4C) was used to calculate the depthdose distribution for 10 different beta sources and variousmaterials. The backscattering dose factors (BSDF) were thencalculated. A significant dependence is shown for the BSDF magnitudeupon detector area, source radius and scatterers. It is clearlyshown that the BSDF increases with increasing detector area.For high Z scatterers, the BSDF can reach as high as 40 and100% for sources with radii 0.1 and 0.0001 cm, respectively.The variation of BSDF with source radius, source energy andsource density is discussed.     

The effects of acetate ions (CH3COO) on electrochemical behavior of copper in chloride solutions

The corrosion behavior of copper has been investigated in presence of acetate ions, at various temperatures in highly corrosive chloride solution. For this aim, potentiodynamic and EIS (electrochemical impedance spectroscopy) measurements were used. Corrosion rates have been determined by extrapolating the polarization curves. The role of temperature, ionic species and the effect of oxide film formation have been interpreted in aspect of anodic and cathodic processes rate. Thermodynamical properties ΔG (free enthalpy), ΔH (enthalpy), ΔS (entropy) and E_a (activation energy) values have been evaluated with help of current–potential measurement results. The experimental results showed that acetate ions have decreased the corrosion rate of copper in chloride containing solutions of pH 8.5. It was also shown that the acetate ions could provide protection behavior at elevated temperatures. The changes in thermodynamic properties showed that acetate ions formed stable and protective complex which physically adsorbed on the surface. The ΔG value decreased and E_a values increased in presence of acetate ions.     

Dispersion of chitosan on perlite for enhancement of copper(II) adsorption capacity

Chitosan coated perlite beads were prepared by drop-wise addition of slurry, made of chitosan dissolved in oxalic acid and perlite, to an alkaline bath (0.7 M NaOH). The beads that contained 32% chitosan enhanced the accessibility of OH and amine groups present in chitosan for adsorption of copper ions. The experiments using Cu(II) ions were carried out in the concentration range of 50-4100 mg/L (0.78-64.1 mmol/L). Adsorption capacity for Cu(II) was pH dependent and a maximum uptake of 104 mg/g of beads (325 mg/g of chitosan) was obtained at pH 4.5 when its equilibrium concentration in the solution was 812.5 mg/L at 298 K. The XPS and TEM data suggested that copper was mainly adsorbed as Cu(II) and was attached to amine groups. The adsorption data could be fitted to one-site Langmuir adsorption model. Anions in the solution had minimal effect on Cu(II) adsorption by chitosan coated perlite beads. EDTA was used effectively for the regeneration of the bed. The diffusion coefficient of Cu(II) onto chitosan coated beads was calculated from the breakthrough curve and was found to be 2.02 x 10(-8) cm(2)/s.     

Removal of Cr(VI) from aqueous solutions using agricultural waste 'maize bran'

Novel biosorbent 'maize bran' has been successfully utilized for the removal of Cr(VI) from aqueous solution. The effect of different parameters such as contact time, sorbate concentration, pH of the medium and temperature were investigated and maximum uptake of Cr(VI) was 312.52 (mgg(-1)) at pH 2.0, initial Cr(VI) concentration of 200mgL(-1) and temperature of 40 degrees C. Effect of pH showed that maize bran was not only removing Cr(VI) from aqueous solution but also reducing toxic Cr(VI) into less toxic Cr(III). The sorption kinetics was tested with first order reversible, pseudo-first order and pseudo-second order reaction and it was found that Cr(VI) uptake process followed the pseudo-second order rate expression. Mass transfer of Cr(VI) from bulk to the solid phase (maize bran) was studied at different temperatures. Different thermodynamic parameters, viz., DeltaG degrees , DeltaH degrees and DeltaS degrees have also been evaluated and it has been found that the sorption was feasible, spontaneous and endothermic in nature. The Langmuir and Freundlich equations for describing sorption equilibrium were applied and it was found that the process was well described by Langmuir isotherm. Desorption studies was also carried out and found that complete desorption of Cr(VI) took place at pH of 9.5.     

Carbon nanotube-nanocrystal heterostructures fabricated by electrophoretic deposition

Alternating layer, carbon nanotubes-nanocrystal composite films, comprising multi-walled carbon nanotubes (MWCNTs) and iron oxide (Fe(3)O(4)) nanocrystals, have been fabricated via electrophoretic deposition (EPD) on stainless steel and gold substrates. Low field-high current and high field-low current EPD schemes were integrated to produce the composite films. The low field-high current EPD approach produced porous mats from an aqueous suspension of the MWCNTs, while the high field-low current EPD approach produced tightly packed nanocrystal films from a dispersion of the nanocrystals in hexane. Large electric fields applied during the nanocrystal EPD and strong van der Waals interactions among the nanocrystals facilitated the formation of tightly packed nanocrystal films atop the MWCNT mats to create CNT mat-nanocrystal film composites. The surface coverage and homogeneity of the nanocrystal films improved with repeated deposition of the nanocrystals on the same mat. The assembly of nanotube mats on top of the CNT mat-nanocrystal film composite confirmed the feasibility of multilayered CNT mat-nanocrystal film heterostructures suitable for a range of devices. Scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques were employed to characterize the surface coverage, homogeneity, and topology of these composite films.     

Photometric reconstruction of a dynamic textured surface from just one color image acquisition

Textured surface analysis is essential for many applications. We present a three-dimensional recovery approach for real textured surfaces based on photometric stereo. The aim is to be able to measure the textured surfaces with a high degree of accuracy. For this, we use a color digital sensor and principles of color photometric stereo. This method uses a single color image, instead of a sequence of gray-scale images, to recover the surface of the three dimensions. It can thus be integrated into dynamic systems where there is significant relative motion between the object and the camera. To evaluate the performance of our method, we compare it on real textured surfaces to traditional photometric stereo using three images. We thus show that it is possible to have similar results with just one color image.     

Coating of LaCoO3 thin film with sol-gel dip coating method

LaCoO3 thin film was coated on Al2O3 single crystal by sol-gel route. Appropriate composition of precursors, chelating agents and the solvent put together into a flask and magnetically stirred on a magnetic stirrer. After having the red transparent solution, it was stirred for 12 hours before coating. Ultrasonically cleaned substrate is dipped into the solution and taken immediately into vertical furnace which is preheated at 550 degrees C. A dense amorphous film is coated on the substrate. Fired amorphous films are annealed at temperature between 900 degrees C and 1000 degrees C for 20 minutes in the air. Then coated film was characterized by means of XRD, AFM, and SEM. Conductivity of the film was measured to be -0.1819 for 881 degrees C for the log sigma value by assuming the thickness as     

Bacterial synthesis of copper/copper oxide nanoparticles

A bacterial mediated synthesis of copper/copper oxide nanoparticle composite is reported. A Gram-negative bacterium belonging to the genus Serratia was isolated from the midgut of Stibara sp., an insect of the Cerambycidae family of beetles found in the Northwestern Ghats of India. This is a unique bacterium that is quite specific for the synthesis of copper oxide nanoparticles as several other strains isolated from the same insect and common Indian mosquitoes did not result in nanoparticle formation. By following the reaction systematically, we could delineate that the nanoparticle formation occurs intracellularly. However, the process results in the killing of bacterial cells. Subsequently the nanoparticles leak out as the cell wall disintegrates. The nanoparticles formed are thoroughly characterized by UV-Vis, TEM, XRD, XPS and FTIR studies.     

Features of the growth of nitride layers in the self-propagating high-temperature synthesis of chromium nitrides

The formation of product layers during combustion of a chromium powder in nitrogen under a pressure of 1–10 MPa is studied. It is shown that nitride Cr₂N forms continuous protective layers, whereas during the formation of CrN, the product layer is partially destroyed. Strength properties of chromium nitrides were determined by the indentation method with a diamond indenter. CrN has a lower strength and higher brittleness compared with Cr₂N, which can explain the above phenomenon.