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71.
72.
Monir Tabatabai Bernd Garska Urs Fischer Norbert Moszner Andreas Utterodt Helmut Ritter 《Polymer International》2012,61(3):407-412
Calix[4]arenes were double alkylated with various alkylhalogenides and the residual OH functions were subsequently dimethacrylated with methacryloyl chloride. The successful synthesis of polymerizable calixarenes was proved using 1H NMR spectroscopy, matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry and differential scanning calorimetry. The polymerization behaviour was confirmed by copolymerization with methacrylic acid methyl ester. Furthermore, the flexural strength, the flexural modulus of elasticity, the exothermic course of the photo‐curing reaction and the polymerization shrinkage of experimental dental filling composites containing the modified calixarenes were evaluated. Copyright © 2012 Society of Chemical Industry 相似文献
73.
Hans Jürgen Grieß Teodor I. Burghelea Helmut Münstedt 《Polymer Engineering and Science》2012,52(3):615-624
An experimental investigation of various flow regimes observed during the extrusion of a polypropylene melt through a flat coat‐hanger die by laser‐Doppler velocimetry (LDV) is presented. LDV measurements of the velocity profiles across the gap of the die at various locations along the die reveal three different extrusion regimes. At small wall shear stresses, the velocity profiles can be fitted by symmetrical curves with the velocities becoming zero at the die walls. These profiles are not uniformly distributed along the die. An increase of the wall shear stress reveals a second flow regime characterized by a uniform distribution of the velocity profiles along the die. As the wall shear stress is increased even further, a third flow regime characterized by wall slip on the glass windows is observed. This flow regime is systematically characterized by measurements of the slip velocities at various temperatures and throughputs. The maximum velocities along the die are taken to assess the uniformity of flow which decisively influences the thickness of the extruded film. By measuring velocity profiles, at different throughput, and temperatures, the conditions for constant velocities along the die were determined. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers 相似文献
74.
Bernd Garska Monir Tabatabai Urs Fischer Norbert Moszner Andreas Utterodt Helmut Ritter 《Polymer International》2012,61(7):1061-1066
We describe the synthesis of 5,11,17,23‐tetra‐tert‐butyl‐25,27‐dioxypropylphosphonic acid‐26,28‐dimethacryloyloxy‐calix [4]arene and 5,11,17,23‐tetra‐tert‐butyl‐25‐oxypropylphosphonic acid‐27‐hydroxy‐26,28‐dimethacryloyloxy‐calix[4]arene starting from para‐tert‐butyl‐calix[4]arene. The complete reaction was proved by matrix‐assisted laser desorption ionization time of flight mass spectrometry and nuclear magnetic resonance spectroscopy. The influence of these compounds on the kinetics of the radical polymerization of methyl methacrylate was shown by dilatometry. Furthermore, the adhesive properties of dental adhesives containing these calix[4]arene derivatives were investigated. Copyright © 2012 Society of Chemical Industry 相似文献
75.
This mini review gives an overview of the synthesis of polyurethanes and polyesters with pendant hydroxyl groups performed mainly in our group. Significant for the synthesis of most of these polymers with hydroxyl‐functional side groups is that no protection groups are needed. This is realised either by generating the OH group during polymer synthesis—demonstrated by the preparation of hydroxyl‐functional polyurethanes from dicarbonate monomers and diamines—or by using catalysts which discriminate between primary and secondary OH groups—demonstrated by the synthesis of hydroxyl‐functional polyesters based on malic acid using scandium triflate as catalyst. In addition, the potential of carbonate couplers for the synthesis of multifunctional polyurethane is presented. The application of such multifunctional polyurethanes as antimicrobial polymers and coatings is briefly discussed. Copyright © 2012 Society of Chemical Industry 相似文献
76.
An experimental investigation of the flow behavior of three polypropylene melts with different molecular structures during extrusion through a coat‐hanger die is presented. Two linear and one long‐chain branched material, rheologically characterized in shear and elongation, were investigated. Using laser–Doppler velocimeter measurements of the velocity profiles across the gap height were performed at five various locations along the die. The uniformity of the velocity distribution along the die has been assessed using the maximum velocities v0 of the corresponding velocity profiles across the gap. The velocity distribution along the die changes with throughput and temperature. Regarding the rheological properties, it was found that the power‐law index of the viscosity as a function of shear rate has a decisive influence on the uniformity of flow but that the pronounced strain hardening in elongation typical of the long‐chain branched polypropylene is not reflected by the velocity distribution along the die. POLYM. ENG. SCI., 2012. © 2012 Society of Plastics Engineers 相似文献
77.
78.
Carina Heisig Jelka Diedenhoven Christopher Jensen Helmut Gehrke Thomas Turek 《化学工程与技术》2020,43(3):484-492
The conversion of bio-based succinic acid (SA) to the value-added chemicals 1,4-butanediol (BDO), γ-butyrolactone (GBL), and tetrahydrofuran (THF) can replace the corresponding petrochemical production routes to achieve a sustainable process. The reaction network for aqueous-phase catalytic hydrogenation of succinic acid over a supported Re-Pd catalyst was identified and the reaction kinetics was determined. With the developed kinetic model, the composition of the product mixture regarding the desired products (BDO, GBL, THF) can be described as a function of educt concentration, temperature, and pressure. The maximum BDO yield was achieved at high pressure and low temperature, while low pressure and high temperature favored GBL and THF production. 相似文献
79.
Novel Positive Allosteric Modulators of µ Opioid Receptor—Insight from In Silico and In Vivo Studies
Damian Bartuzi Ewa Kdzierska Agnieszka A. Kaczor Helmut Schmidhammer Dariusz Matosiuk 《International journal of molecular sciences》2020,21(22)
Opioids are the drugs of choice in severe pain management. Unfortunately, their use involves serious, potentially lethal side effects. Therefore, efforts in opioid drug design turn toward safer and more effective mechanisms, including allosteric modulation. In this study, molecular dynamics simulations in silico and ‘writhing’ tests in vivo were used to characterize potential allosteric mechanism of two previously reported compounds. The results suggest that investigated compounds bind to μ opioid receptor in an allosteric site, augmenting action of morphine at subeffective doses, and exerting antinociceptive effect alone at higher doses. Detailed analysis of in silico calculations suggests that first of the compounds behaves more like allosteric agonist, while the second compound acts mainly as a positive allosteric modulator. 相似文献
80.
Single‐step synthesis of a radically polymerizable 1,1′‐bi‐2‐naphthol derivative for asymmetric catalysis 下载免费PDF全文
A new polymerizable 1,1′‐bi‐2‐naphthol derivative for polymer‐supported catalytic asymmetric synthesis is presented. The synthesis is conducted within a single reaction step, which is a major advantage over other approaches presented in the literature. The ligand‐bearing polymer is prepared through copolymerization with N‐isopropylacrylamide. Preliminary experiments on the utility in catalytic asymmetric alkylation reactions reveal the accessibility and activity of the polymer‐attached catalysts. The stereoselectivity of the reaction is found to be somewhat lower than for reactions performed in the presence of free 1,1′‐bi‐2‐naphthol, and thus requires further optimization. The enantiomeric excess of the reaction products was determined via 1H NMR spectroscopy after chiral derivatization with (R)‐α‐methylbenzyl isocyanate. © 2015 Society of Chemical Industry 相似文献