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71.
Summary Starting with Z-2, 3-diamino-2-butenedinitrile as diamine component the synthesis of the low molecular N,N,O,O-chelate 3.Co and its ligand 3 is optimized. An easy synthesis of the chelate 8.Co covalently bound on macroreticular resins is presented. The chelates 8.Co are the most active heterogenous catalysts for the valence isomerization of quadricyclane to norbornadiene today. 相似文献
72.
73.
Dr. G. Pönisch 《Computing》1987,39(1):1-17
A direct method is described for computing a hysteresis point (double turning point) corresponding to a cusp point of a system ofn nonlinear equations inn variables depending on two parameters. By addition of two equations a minimally extended system ofn+2 nonlinear equations is constructed for which the hysteresis point is an isolated solution. An efficient implementation of Newton's method is presented not requiring evaluations of second derivatives of the original problem. Two numerical examples show the efficiency of theQ-quadratically convergent method. 相似文献
74.
A one-dimensional mesoscopic ring with one input and two output leads acts as a spintronic beam splitter. The spatial degree of freedom, i.e., the presence of two different possible output channels, gets intertwined with the spin direction as a consequence of quantum interference and spin-orbit interaction. We investigate this kind of spatial-spin correlation, and show that the output density operator contains no quantum entanglement in the important special case when the device polarizes a perfectly random input spin state. However, the correlations are in general not purely classical, we also present specific input states with maximal spatial-spin entanglement after the ring. 相似文献
75.
Kunkel Mark A.; Hector Mark A.; Góngora Coronado Elías; Castillo Vales Victor 《Canadian Metallurgical Quarterly》1989,36(3):322
Conducted a study of client expectations of psychological services in Yucatán, Mexico, under the sponsorship of a grant from the Organization of American States. The Expectations about Counseling–Brief form (EAC-B) questionnaire was translated and administered to 488 subjects across age, sex, and experience with psychological services. Subsequent analyses supported the reliability and robustness of the Spanish EAC-B, with factor structure similar to the EAC-B in English. Some relation was found among age, sex, prior counseling experience, and expectations about counseling. Implications of these data for future research and comparison with U.S. subjects are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
76.
We compare two link analysis ranking methods of web pages in a site. The first, called Site Rank, is an adaptation of PageRank to the granularity of a web site and the second, called Popularity Rank, is based on the frequencies of user clicks on the outlinks in a page that are captured by navigation sessions of users through
the web site. We ran experiments on artificially created web sites of different sizes and on two real data sets, employing
the relative entropy to compare the distributions of the two ranking methods. For the real data sets we also employ a nonparametric
measure, called Spearman's footrule, which we use to compare the top-ten web pages ranked by the two methods. Our main result
is that the distributions of the Popularity Rank and Site Rank are surprisingly close to each other, implying that the topology
of a web site is very instrumental in guiding users through the site. Thus, in practice, the Site Rank provides a reasonable
first order approximation of the aggregate behaviour of users within a web site given by the Popularity Rank. 相似文献
77.
Ohne Zusammenfassung
VDI 相似文献
78.
79.
Mark Sherman Jonathan Rosenberg Ann Marks Jaap Akkerhuis 《Computer Standards & Interfaces》1991,11(3):177-182
Many advanced document systems provide a formatting mechanism called ‘style sheets’ Style sheets provide a great deal of flexibility in describing a document's format, and allow easy maintenance of different house styles for a collection of documents. In this paper, we describe the basics of general style sheet systems, argue that successful document interchange must include the exchange of style sheet information, and evaluate ODA's style mechanism against this requirement. 相似文献
80.
Summary A group of new polyimides has been prepared by solution condensation of 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine containing pendant NMe2 units and various dianhyrides in N-methylpyrrolidone (NMP). The tridentate (N-N′-N) pydim ligands were prepared by Schiff-base condensation of 2,6-diacetylpyridine and 4-dimethylaminoaniline in the presence of formic acid as catalyst. These polymers were investigated for their extraction capabilities for Zn(II), Mn(II), Cu(II), Cd (II) and Ni(II) and at different pH. Under different conditions enhanced selectivity was observed. Up to 98% quantitative recoveries were observed for all metals. 相似文献