High-Density Frenkel Defects as Origin of N-Type Thermoelectric Performance and Low Thermal Conductivity in Mg3Sb2-Based Materials

Mg₃Sb₂-based intermetallic compounds with exceptionally high thermoelectric performance exhibit unconventional n-type dopability and anomalously low thermal conductivity, attracting much attention to the underlying mechanisms. To date, investigations have been limited to first-principle calculations and thermodynamic analysis of defect formation, and detailed experimental analysis on crystal structure and phonon modes has not been achieved. Here, a synchrotron X-ray diffraction study clarifies that, against a previous view of a simple crystal structure with a small unit cell, Mg₃Sb₂ is inherently a heavily disordered material with Frenkel defects, charge-neutral defect complexes of cation vacancies and interstitials. Ionic charge neutrality preserved in Mg₃Sb₂ is responsible for exotic n-type dopability, which is unachievable for other Zintl phase materials. The thermal conductivity of Mg₃Sb₂ exhibits deviation from the standard T⁻¹ temperature dependency with strongly limited phonon transport due to a strain field. Inelastic X-ray scattering measurement reveals enhanced phonon scattering induced by disorder. The results will draw renewed attention to crystal defects and disorder as means to explore new high-performance thermoelectric materials.     

Development of a novel image intensifier of an amplifiedmetal-oxide semiconductor imager overlaid with electron-bombardedamorphous silicon

We developed a novel image intensifier (II) of an amplified metal-oxide-semiconductor (MOS) imager (AMI) overlaid with electron-bombarded (EB) amorphous silicon (a-Si). The electron bombardment gain (EB gain) was 1500 at an accelerating voltage of 10 kV. Since the multiplication process was free from a phosphorescent screen and a coupling fiber plate as in the conventional II, the resolution was high and the picture quality was good and free from granularity noises, white spots, lag and sticking. As for fatigue of X-ray irradiation, the contrasts of a vertical stripe (Smear) are not detectable and damaged areas in AMI are weak whereas both of those in charge-coupled devices (CCDs) are strong     

Oxidation of Fe (II) in sulfuric acid solutions with dissolved molecular oxygen

The oxidation of Fe(II) with dissolved molecular oxygen was studied in sulfuric acid solutions containing 0.2 mol . dm^-3 FeSO₄ at temperatures ranging from 343 to 363 K. In solutions of sulfuric acid above 0.4 mol . dm^-3, the oxidation of Fe (II) was found to proceed through two parallel paths. In one path the reaction rate was proportional to both [Fe²⁺]² and po₂, exhibiting an activation energy of 51.6 . kJ mol^-1. In another path the reaction rate was proportional to [Fe²⁺]², [SO_4-], and po₂ with an activation energy of 144.6 kJ . mol^-1. A reaction mechanism in which the SO_4- ions play an important role was proposed for the oxidation of Fe(II). In dilute solutions of sulfuric acid below 0.4 mol . dm^-3, the rate of the oxidation reaction was found to be proportional to both [Fe(II)]² and Po₂, and was also affected by [H⁺] and [SO_2- ⁴]. The decrease in [H⁺] resulted in the increase of reaction rate. The discussion was further extended to the effect of Fe (III) on the oxidation reaction of Fe (II).     

Realistic image synthesis of a deformable living thing based on motion understanding

This paper describes a system that can synthesize realistic sequential images of moving goldfish based on the image understanding result of real goldfish. To analyze and synthesize images in real-time, we have constructed a hardware system that consists of 32 paralell transputers with a high-speed visual-data interface called VIT (Visual Interface for Transpputer Network). The system is very flexible and powerful for various types of image processing because it can be extended according to the required computational cost. In the understanding process, we assume that the target object, a goldfish in this case, deforms its shape pliably in 3-D space and moves only in a two-dimensional direction. A modeling, called the Bone-Structured Solid Modeler, which is suitable for representing deformable objects such as living things, plays an important role in the understanding and synthesis processes of the deformable object. Three types of constraints for motion, namely, static, dynamic, and object, are utilized to verify the estimated pose and orientation of the object. In the motion synthesis process, realistic moving images are synthesized by controlling the model employing the motion understanding result. Simulation results are presented to show the effectiveness of the system. The technology discussed in this paper is expected to play a key role in the realization of future visual human interfaces.     

Observation of low-chirp modulation in InGaAs-InAlAs multiple-quantum-well optical modulators under 30 GHz

Modulated light spectra were measured in long-wavelength InGaAs-InAlAs multiple-quantum-well intensity modulators under 30-GHz large-signal modulations. The linewidth broadening factor alpha is determined from the relation between the intensity modulation index and the sideband strength relative to the carrier. The minimum alpha value is estimated to be 0.70 at 1.54 mu m, which is almost the same as the lowest value so far reported in a bulk Franz-Keldysh modulator. This is significantly lower than what is obtained from direct-intensity modulation of injection lasers, making this a useful device for application to high-bit-rate long-haul optical communication systems.<>     

An InGaAs/InAlAs superlattice avalanche photodiode with a gain bandwidth product of 90 GHz

The authors describe the fabrication of an InGaAs/InAlAs superlattice avalanche photodiode with a gain-bandwidth product of 90 GHz. The device is composed of an InGaAs/InAlAs superlattice multiplication region and an InGaAs photoabsorption layer. The effect of the superlattice multiplication region thickness on the gain-bandwidth product was studied. A gain-bandwidth product of 90 GHz was obtained for the device with a multiplication region thickness of 0.52 mu m. Low noise performance is compatible with the high gain-bandwidth product due to improvement of the ionization rate ratio made by introducing a superlattice structure into the multiplication region.<>     

A Real-coded Genetic Algorithm Applied to Optimum Design of a Low Solidity Vaned Diffuser for Diffuser Pinup

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Mechanical properties versus temperature relation of individual phases in Sn-3.0Ag-0.5Cu lead-free solder alloy

The non-homogeneous Sn-3.0Ag-0.5Cu (SAC305) lead-free solder alloy consists of Sn-rich (β-Sn) and eutectic phases. The mechanical properties of these individual phases were demonstrated to be a function of the temperature. The nanoindentation methodology was utilized to examine the mechanical properties at 60 °C, 80 °C, 110 °C, 130 °C, and 150 °C, respectively. It was found that for both Sn-rich phase and eutectic phase, the hardness and Young’s modulus exhibited the dependence on the temperature. Moreover, the creep deformation which occurred at the dwell time of sustained loading was quite sensitive to the prescribed temperature. Basically, the higher temperature resulted in a larger creep deformation. This in turn caused the variable strain rate sensitivity of the individual phases, which was extracted by Mayo-Nix approach. The Sn-rich phase showed larger creep deformation than that of eutectic phase. However, a greater strain rate sensitivity index value was obtained for eutectic phase at the temperature regime (25-130 °C). The derived activity energy implied that for both β-Sn and eutectic phases two rate-controlling processes took place during the creep deformation, in which the transition temperature is around 130 °C.