全文获取类型
收费全文 | 5228篇 |
免费 | 119篇 |
国内免费 | 27篇 |
专业分类
电工技术 | 412篇 |
综合类 | 17篇 |
化学工业 | 1504篇 |
金属工艺 | 136篇 |
机械仪表 | 138篇 |
建筑科学 | 189篇 |
矿业工程 | 1篇 |
能源动力 | 244篇 |
轻工业 | 506篇 |
水利工程 | 19篇 |
石油天然气 | 7篇 |
无线电 | 292篇 |
一般工业技术 | 918篇 |
冶金工业 | 189篇 |
原子能技术 | 214篇 |
自动化技术 | 588篇 |
出版年
2023年 | 30篇 |
2022年 | 59篇 |
2021年 | 96篇 |
2020年 | 52篇 |
2019年 | 63篇 |
2018年 | 75篇 |
2017年 | 63篇 |
2016年 | 112篇 |
2015年 | 79篇 |
2014年 | 151篇 |
2013年 | 321篇 |
2012年 | 188篇 |
2011年 | 307篇 |
2010年 | 258篇 |
2009年 | 280篇 |
2008年 | 316篇 |
2007年 | 262篇 |
2006年 | 203篇 |
2005年 | 220篇 |
2004年 | 178篇 |
2003年 | 162篇 |
2002年 | 166篇 |
2001年 | 106篇 |
2000年 | 96篇 |
1999年 | 97篇 |
1998年 | 108篇 |
1997年 | 74篇 |
1996年 | 74篇 |
1995年 | 55篇 |
1994年 | 81篇 |
1993年 | 70篇 |
1992年 | 57篇 |
1991年 | 76篇 |
1990年 | 54篇 |
1989年 | 77篇 |
1988年 | 65篇 |
1987年 | 39篇 |
1986年 | 73篇 |
1985年 | 56篇 |
1984年 | 53篇 |
1983年 | 57篇 |
1982年 | 60篇 |
1981年 | 47篇 |
1980年 | 42篇 |
1979年 | 41篇 |
1978年 | 41篇 |
1977年 | 28篇 |
1976年 | 28篇 |
1975年 | 18篇 |
1973年 | 17篇 |
排序方式: 共有5374条查询结果,搜索用时 15 毫秒
131.
Takaho Kaneda Toshio Katsura Kanji Nakagawa Hiroshi Makino Masao Horio 《应用聚合物科学杂志》1986,32(1):3151-3176
The polyimides based on 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) described in Part I of this series were dissolved in p-chlorophenol and spun into fibers using a coagulating bath of ethanol. The fibers as spun had in general low tenacities and low moduli, but a heat treatment at 300–500°C under tension produced a remarkable increase in strength and modulus, and fibers with a tensile strength of 26 g/den (3.1 GPa) and an initial modulus higher than 1,000 g/den (120 GPa) could be obtained. Thus, the annealed fibers of polyimides are comparable to aramid fibers in mechanical properties. To heating in air and in the saturated steam, the polyimide fibers showed higher resistance than the aramid fibers. The polyimide fibers surpassed the aramid fibers in resistance to acid treatment and ultraviolet (UV) irradiation, but were inferior in resistance to alkali treatment. The annealed fibers of polyimides displayed distinct X-ray diffraction patterns. The chain repeat distance of 20.5 Å determined on the fibers of polyimide prepared from BPDA and o-tolidine, and 20.6 Å determined on the fibers of polyimide derived from BPDA and 3,4′-diaminodiphenyl ether are reasonable when the dimensions of monomeric units and the shapes of the molecular chains are considered. The X-ray reflections of both polyimide fibers were indexed satisfactorily on the basis of postulated unit cells. 相似文献
132.
Isao Mochida Kenjiro Iwamoto Tsutomu Tahara Yozo Korai Hiroshi Fujitsu Kenjiro Takeshita 《Fuel》1982,61(7):603-609
Reactivities of several coals of different ranks have been examined in degrading extractions with aromatic solvents under apparently non-hydrogenative reaction conditions. Pyrene and A240 pitch liquefied the fusible coals in high yields and the slightly-fusible coals in moderate yields, indicating the importance of fusibility in such liquefaction processes. A240-LS pitch is a powerful solvent for slightly-fusible coals. Considerable amounts of pyridine- or THF-soluble fractions were produced especially with A240-LS pitch. A240 pitch is a better solvent than pyrene for some slightly-fusible coals. However, the extent of depolymerization of liquefied coal, pyridine- or THF-solubility, was definitely inferior. Yields of such fractions are higher for lower-rank coals. The mechanism of coal liquefaction under apparently non-hydrogenative conditions is discussed with emphasis on the stabilization of thermal fragments derived from the coal. 相似文献
133.
Ozonization of various amides was carried out as a model reaction for the degradation of polyamides with ozone. N-alkylamides and N,N-dialkylamides were found to be reactive compared with those amides which have no alkyl group on the nitrogen atom, and it was suggested that ozone attacks preferentially N-methylene or N-methyl group of amides in the first step of ozonization. 相似文献
134.
One-pot polymerization of polyimide from 3,3′,4,4′-biphenyl tetracarboxylic dianhydride (BPDA) and 4,4′-oxydianiline (ODA) was examined. The equilibrium in the polyimide with water was examined in detail in p-chlorophenol solution during the polymerization. The equilibrium constant was expressed by log K = 1.50 + 1433 (1/T). The polymerization reaction is exothermic. The molecular weight increased with decrease of temperature. © 1996 John Wiley & Sons, Inc. 相似文献
135.
Addition of [FeII(MeCN)24+(ClO−4)2 to solutions of hydrogen peroxide in dry acetonitrile (MeCN) catalyzes a rapid disproportionation of H2O2 via the initial formation of an adduct, [FeII(HOOH)↔Fe(O)(OH2)]2+, which oxidizes a second H2O2 to dioxygen. This intermediate also cleanly oxidizes substituted hydrazines, alcohols, aldehydes, and thioethers by a two-electron process. The products for these H2O2 oxidations are consistent with those that result from catalase- and some peroxidase-catalyzed processes. In the same aprotic medium (MeCN) anhydrous FeIIICl3 catalyzes the demethylation of N,N-dimethylaniline, the epoxidation of olefins, and the oxidative cleavage of 1-phenyl-1,2-ethanediol (and other 1,2-diols) by hydrogen peroxide. A mechanism is proposed in which an initial Lewis acid-base interaction of FeIIICl3 with H2O2 generates a highly electrophilic FeIII-oxene species as the reactive intermediate. For each class of substrate the products closely parallel those that result from their enzymatic oxidation by cytochrome P-450. Because of (a) the close congruence of products, (b) the catalytic nature of the FeIIICl3/H2O2 reaction mimic, and (c) the similarity of the dipolar aprotic solvent (acetonitrile) to the proteinaceous lipid matrix of the biomembrane, the form of the reactive intermediate may be the same in each case. This is in contrast to the prevailing view that cytochrome P-450 acts as a redox catalyst to generate an Fe(V)-oxo species or an Fe(IV)-oxo cation radical as the reactive intermediate. 相似文献
136.
Tomoyo Okumura Kenya Sonobe Asami Ohashi Harumi Watanabe Katsushi Watanabe Hiroshi Oyamada Masaaki Aramaki Toshiaki Ougizawa 《Polymer Engineering and Science》2020,60(7):1699-1711
Simultaneous one-pot syntheses of PA66 and HAp were carried out by extracting H2O and CO2 from PA66 monomers and HAp raw materials, respectively, resulting in the formation of a polyamide (PA) 66-hydroxyapatite (HAp) nanocomposite. During the process, a spherical nano-sized HAp particle was precipitated following dissolution of micro-sized CaHPO4・2H2O. The PA66 monomers were subsequently adsorbed onto the generated HAp product. Some of the adsorbed PA66 monomers formed a bound polymer on HAp, and an increase in the adhesiveness of the PA66-HAp interface was observed as the polymerization progressed. During this process, the synthesis of a nanocomposite from a micro-sized raw material and creation of an autonomous strong interface between the matrix and filler was achieved. In addition, the shape of the resultant HAp was controllable and could be modified to needle shape by the addition of F− and Mg2+ ions to the raw material. HAp could also be changed to plate shape via octa-calcium phosphate (OCP). Notably, during the synthesis, the filler shape of the nanocomposite could be controlled to 0D (particle), 1D (needle), and 2D (plate). 相似文献
137.
Taizo Sano Masamichi Tsuji Nobuyuki Gokon Hiroshi Kaneko Yutaka Tamaura 《Journal of the American Ceramic Society》2000,83(10):2509-2514
Oxygen uptake and release of (Li,Mn) ferrite [LMF; (Li0.60 Mn1.20 Fe1.20 )1−δ O4 ; δ= 0.007 to 0.033] was investigated concerning the relations between redox reactions of ferrite and cation migration. Mössbauer spectroscopy and X-ray diffractometry showed that some of the Li+ and Fe3+ ions migrated from the A sites to the B sites of the spinel-type structure and Mn4+ ions migrated from the B sites to the A sites during oxygen uptake at 573 K. The cation-deficient LMF formed by the oxygen uptake released oxygen molecules in He gas only at 660 K. The cation migration during the oxygen release was in the opposite direction of the movement during oxygen uptake at 573 K. 相似文献
138.
Yttria-ceria-doped tetragonal zirconia (Y,Ce)-TZP)/alumina (Al2 O3 ) composites were fabricated by hot isostatic pressing at 1400° to 1450°C and 196 MPa in an Ar–O2 atmosphere using the fine powders prepared by hydrolysis of ZrOCl2 solution. The composites consisting of 25 wt% Al2 O3 and tetragonal zirconia with compositions 4 mol% YO1.5 –4 mol% CeO2 –ZrO2 and 2.5 mol% YO1.5 –5.5 mol% CeO2 –ZrO2 exhibited mean fracture strength as high as 2000 MPa and were resistant to phase transformation under saturated water vapor pressure at 180°C (1 MPa). Postsintering hot isostatic pressing of (4Y, 4Ce)-TZP/Al2 O3 and (2.5Y, 5.5Ce)-TZP/Al2 O3 composites was useful to enhance the phase stability under hydrothermal conditions and strength. 相似文献
139.
Hiroyuki Sumi Akio Takemura Mikio Kajiyama Yasunori Hatano Bunichiro Tomita Hiroshi Mizumachi 《The Journal of Adhesion》1992,38(3):173-184
Power feed copolymers were synthesized using styrene and n-butyl acrylate through non-uniform feeding emulsion polymerization. Poly(vinyl alcohol) (PVA) was used as a protective colloid, onto which vinyl monomers were grafted. Power feed copolymer had a very broad glass transition temperature compared with random copolymer, even if grafting and/or crosslinking were introduced to the system. This tendency was almost the same as the non-grafted power feed copolymer where only low molecular weight surfactant was used.
Adhesive joint strengths of power feed copolymers were evaluated compared with random copolymers. In the case of usual linear power feed copolymer, the adhesive joint strengths were not higher than those of random copolymer, which was considered to be due to the lower film strengths of the power feed copolymer. Power feed copolymer having grafting showed slightly higher adhesive joint strengths over a wide range of temperatures than random copolymer. When crosslinking was introduced to the system, power feed copolymer showed much higher adhesive joint strengths over a wide temperature range. 相似文献
Adhesive joint strengths of power feed copolymers were evaluated compared with random copolymers. In the case of usual linear power feed copolymer, the adhesive joint strengths were not higher than those of random copolymer, which was considered to be due to the lower film strengths of the power feed copolymer. Power feed copolymer having grafting showed slightly higher adhesive joint strengths over a wide range of temperatures than random copolymer. When crosslinking was introduced to the system, power feed copolymer showed much higher adhesive joint strengths over a wide temperature range. 相似文献
140.
Tomoo Yamamura Tomonori Mori Ki Chul Park Yasuhiko Fujii Hiroshi Tomiyasu 《The Journal of Supercritical Fluids》2009,51(1):43-49
Catalytic reduction gasification in the presence of ruthenium(IV) dioxide (RuO2) in supercritical water was used to decompose intractable biomass. The gasification of model biomass samples (glucose, cellulose, and heterocyclic compounds), and low-purity biomass samples obtained from a paper-recycling facility (paper sludge) and from a sewage treatment plant (sewage sludge) were studied. In clear contrast to another catalysts, the RuO2 catalyst completely gasified cellulose to produce mainly hydrogen, methane, and carbon dioxide under various conditions (e.g., 673 K at 30 MPa and 773 K at 50 MPa). As for heterocyclic compounds, nitrogen compounds did not deactivate the RuO2 catalyst; the gasification of carbazole proceeded completely. Furthermore, paper sludge was almost completely decomposed in supercritical water with RuO2 at 723 K. 相似文献