Copper Ion Cementation in Presence of a Magnetic Field

The effect of an electromagnetic field (EMF) on the rate of copper(II) cementation from copper sulfate solutions on a rotating iron cylinder was investigated. The studied variables were cylinder rotation speed, magnetic field strength, and magnetic field direction. The application of EMF increased the rate of cementation in both parallel and perpendicular direction of the magnetic field where the latter proved to be more effective. The rate of mass transfer under an EMF was found to be more than doubled. The enhancement of copper recovery in presence of the EMF is due to the induced motion of Fe⁺ⁿ in the solution which is limited to a certain range of cylinder rotation speed. The power consumption for cementation of copper could be significantly reduced by utilizing EMF.     

Graphene network enabled high speed electrical actuation of shape memory nanocomposite based on poly(vinyl acetate)

Here strong electroactive shape memory nanocomposites were prepared by incorporating graphene nanoplatelets into poly(vinyl acetate) (PVAc ) through the simple solvent mixing method. TEM and XRD revealed that well exfoliated graphene nanoplatelets formed a continuous network throughout the matrix with a large amount of interconnectedness. Dynamic mechanical analysis showed that the inclusion of graphene significantly improves both glassy and rubbery moduli of the matrix. Furthermore, the prepared nanocomposites demonstrated a marked electrical conductivity up to 24.7 S m^?1 and thereby surprisingly rapid electrical actuation behaviour exhibiting a 100% recovery ratio in 2.5 s. Moreover, PVAc and its nanocomposites displayed scratch self‐healing capability. This work demonstrates that the PVAc /graphene nanocomposites with high modulus and excellent electroactive shape memory performance can be a promising material in many applications such as sensors and fast deployable and actuating devices. © 2016 Society of Chemical Industry     

Performance of Counterflow Microchannel Heat Exchangers Subjected to External Heat Transfer

This article analyzes the effect of external heat transfer on the thermal performance of counterflow microchannel heat exchangers. Equations for predicting the axial temperature and the effectiveness of both fluids as well as the heat transferred between the fluids, while operating under external heating or cooling conditions, are provided in this article. External heating may decrease and increase the effectiveness of the hot and cold fluids, respectively. External cooling may improve and degrade the effectiveness of the hot and cold fluids, respectively. For unbalanced flows, the thermal performance of the microchannel heat exchanger subjected to external heat transfer depends on the fluid with the lowest heat capacity. At a particular number of transfer units (NTU), the effectiveness of both the fluids increased with decrease in heat capacity ratio when the hot fluid had the lowest heat capacity. When the cold fluid had the lowest heat capacity, the effectiveness of both fluids increased with decrease in heat capacity ratio at low values of NTU but at high values of NTU the effectiveness increased with increase in heat capacity ratio. A term called the “performance factor” has been introduced in this article to assess the relative change in effectiveness due to external heat transfer.     

Pd-doped Co nanofibers immobilized on a chemically stable metallic bipolar plate as novel strategy for direct formic acid fuel cells

High contact resistance and corrosion are the main dilemma facing wide application of the metallic bipolar plates. In this study, deposition of thin film from Pd-decorated Co nanofibers on a silicon substrate is introduced as a novel strategy to produce functionalized metallic bipolar plate. The novel active metallic bipolar plate can be prepared by using simple, low cost, high yield and effective technique; electrospinning. The bimetallic nanofibrous film chemically bonds with the silicon substrate due to formation of silicon carbide which leads to merge the deeper nanofibers with the silicon surface. Accordingly, high current density (100 mA cm⁻¹) was obtained when the introduced covered silicon wafer was utilized as anode catalyst for formic acid electrooxidation. Because the bimetallic nanofibers are sheathed in a thin graphite shell, the introduced active bipolar plate reveals very good stability. Overall, the introduced study is opening a new avenue to prepare new class of functionalized metallic bipolar plates.     

Thermal performance of different pond cells under actual climatic conditions in Qatar

Experimental work was undertaken to study the thermal performance of three different pond cells under actual climatic conditions of Qatar. The first cell was an open pond. In the second unit, a finned radiator, painted black, was placed over the pond. In the third cell, the water was contained in a polyethylene bag. Experimental results indicated that the exposed pond cell came out best, when considered in terms of how quickly the temperature of the stored water could be reduced, and how low that temperature could be. The water in the exposed pond was cooled directly (by evaporation and radiation to sky) whereas in the case of the finned radiator cell, heat had to be transferred from the stored water to the radiator, and then from the radiator to the surrounding. In the case of water-in-bag cell, evaporation was eliminated and radiative exchange with the sky was reduced due to the partial transparency of the polyethylene bag (in the infrared region).     

Modeling and simulation of solar pond floor heating system

This paper presents the development of modeling, simulation and analysis of a solar pond floor heating system. The developed computer simulation has been used to study the potential of using such a system under climatic conditions in Jordan. It was found that the solar pond heating system could meet most of the winter season in Jordan with Solar fraction in the range 80–100% for at least 2 months of the season. It must be emphasized that the feasibility of such a system is its utilization in district heating and not for individual households due to the limiting economical factors of high capital cost of the solar pond for small domestic applications.     

Three dimensional energy profile:: A conceptual framework for assessing household energy use

The provision of adequate, reliable, and affordable energy has been considered as a cornerstone of development. More than one-third of the world's population has a very limited access to modern energy services and suffers from its various negative consequences. Researchers have been exploring various dimensions of household energy use in order to design strategies to provide secure access to modern energy services. However, despite more than three decades of effort, our understanding of household energy use patterns is very limited, particularly in the context of rural regions of the developing world. Through this paper, the past and the current trends in the field of energy analysis are investigated. The literature on rural energy and energy transition in developing world has been explored and the factors affecting households' decisions on energy use are listed. The and the factors affecting households' decisions on energy use are listed. The gaps identified in the literature on rural household energy analysis provide a basis for developing an alternative model that can create a more realistic view of household energy use. The three dimensional energy profile is presented as a new conceptual model for assessment of household energy use. This framework acts as a basis for building new theoretical and empirical models of rural household energy use.     

Household cooking fuels and technologies in developing economies

A major energy challenge of the 21^st century is the health and welfare of 2.7 billion people worldwide, who currently rely on burning biomass in traditional household cooking systems. This Special Issue on Clean Cooking Fuels and Technologies in Developing Economies builds upon an IAEE workshop on this subject, held in Istanbul in 2008 ( Foell et al., 2008). It includes several papers from that workshop plus papers commissioned afterwards. The major themes of that workshop and this Special Issue are: