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71.
Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)3) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)3 exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 104 g mol?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)3 has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)3 is 69.6 kJ mol?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry 相似文献
72.
E. E. Mukhin G. T. Razdobarin M. M. Kochergin S. Yu. Tolstyakov V. V. Semenov G. S. Kurskiev K. A. Podushnikova 《Instruments and Experimental Techniques》2008,51(2):220-225
A diagnostic array has been developed for studying the operating modes of the divertor in the ITER tokamak-reactor using the Thomson scattering technique. The aim of this study is to measure the spatial profiles of the electron temperature and density. The structure of the diagnostic setup was selected on the basis of a classical diagnostic geometry and the high-resolution LIDAR system, which provide access to different regions of the divertor plasma. A severe radiation environment, limited access to the plasma in the ITER divertor, and a high-dust environment (the divertor plate erosion material) in the divertor volume pose many problems for performing diagnostics under unique conditions having no analogs in the tokamaks that are now in operation. Different methods for protecting optical surfaces from plasma-enriched deposition are proposed and analyzed. The efficiency of these methods has been demonstrated in bench tests. The concept of laser and detector systems and diffraction polychromators capable of operating at different electron temperatures with a lower limit of 1 eV, has been justified and approved. 相似文献
73.
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75.
Yu. G. Volodin 《Thermal Engineering》2007,54(5):399-402
The results of experimental study of unsteady effects on local heat transfer coefficients caused by abruptly increasing of the gas flow temperature in the inlet section of a cylindrical channel are presented. 相似文献
76.
Heidi Bernas Arie J. Plomp Johannes H. Bitter Dmitry Yu. Murzin 《Catalysis Letters》2008,120(1-2):8-13
The density functional theory (DFT/B3LYP) calculations were applied to investigate the interaction of a Pt6 particle with the ZSM-5 zeolite framework. The electronic structure of the metal particle is strongly affected by the interaction with basic framework oxygens and acid sites of the zeolite support. Adsorption on basic sites (Eads = 6 kcal/mol) favors the formation of the electron enriched metal cluster. Interaction of the platinum cluster with the acid site characterized by stabilization energy of 47 kcal/mol results in oxidation of the metal particle and suppression of Brønsted acidity of the support. The hypothesis is put forward that the oxidized platinum particle can function as an active site for the alkane isomerisation on platinum supported high silica zeolites. 相似文献
77.
S. M. Obraztsov G. A. Birzhevoi Yu. V. Konobeev V. A. Solov'ev O. S. Silkina 《Atomic Energy》2004,96(2):111-116
The results of a computational experiment with a neural-net model simulating the effect of the chemical composition on the plastic properties of ÉP-450 steel are presented. It is shown that computer-aided development of reactor steel with prescribed properties is, in principle, possible. 相似文献
78.
A. V. Zrodnikov G. I. Toshinskii O. G. Grigor'ev Yu. G. Dragunov V. S. Stepanov N. N. Klimov I. I. Kopytov V. N. Krushel'nitskii A. A. Grudakov 《Atomic Energy》2004,97(2):528-533
The results of development work on the SVBR-75/100 modular fast reactor cooled by lead–bismuth coolant are presented. The design is based on the experience gained operating reactors in nuclear-powered submarines. The SVBR-75/100 reactor is inherently safe because of its low power, the chemical inertness and high boiling point of the lead–bismuth coolant, and the integrated basin-type arrangement of the first-loop equipment. This eliminates the conflict between the safety and economic requirements that is characteristic of conventional-type reactors. The lower power makes it possible to build the reactor in a factory and deliver the reactor using any form of transportation to the nuclear power plant site. All safety systems operate passively. Most of these systems are used as normal-operating systems. This creates conditions for multipurpose applications of such reactor modules in developed and developing countries. 相似文献
79.
Age assessment and control of the reliability of the coolant flow-rate measurement system of the RBMK-1500 reactor at the Ignalina nuclear power plant are examined. A statistical analysis is made of the data obtained from measurements of the techanical characteristics of SHADR-32M flow meters. A mathematical model of the aging of flow meters and reliability estimates is constructed. A strategy is developed for replacing SHADR; this strategy makes it possible to support the required relaibility of the entire coolant flow-rate measurement system. 相似文献
80.