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71.
Mi-Hwa Baek Won-Chae Jung Ji-Won Yoon Ji-Sook Hong Young-Seak Lee Jeong-Kwon Suh 《Journal of Industrial and Engineering Chemistry》2013,19(2):469-477
The influences of heat-treatment temperature and activation time on the properties of TiO2 supported on spherical activated carbon (TiO2/SAC) were investigated. Nano-sized TiO2 was dispersed on the spherical activated carbon with the size of 10–30 nm. Some anatase phase of TiO2 was transformed to rutile phase of TiO2 with an increase of heat-treatment temperature. All of the TiO2/SAC photocatalysts had microporous structure, with the mesopore volume increasing over an activation time of 6 h. The TiO2/SAC photocatalysts obtained at activation times of 6 h and 9 h were observed synergistic effects between adsorption and photocatalysis in the removal of humic acid. 相似文献
72.
Hye-Ju Jung Ji-Sook Hong Jeong-Kwon Suh 《Journal of Industrial and Engineering Chemistry》2013,19(4):1325-1330
There have been many studies on the use of photocatalysts as an advanced oxidation process (AOP) to oxidize and degrade organic-based contaminants. This research group has previously reported a production process of Ti based spherical activated carbon and the characteristics of the product. This paper further examines the process of fenton oxidation and the process of Ti-spherical carboneous material (Ti-SCM) photolysis to evaluate their respective advantages and disadvantages. Non-biodegradable humic acid (HA) was chosen for the purpose of the study to observe the degradation. It is demonstrated that fenton oxidation is fast and efficient in a low organic viscous solvent. Ti-SCM is not greatly affected by variation of the pH level and the process is also fast and efficient. Moreover, the process's retention rate of catalysts and its reusability were greater than that of fenton oxidation, which required pH balancing and produced sludge. 相似文献
73.
Among various Cu/ZnO/ZrO2 catalysts with the Cu/Zn ratio of 3/7, the one with 15 wt.% of ZrO2 obtains the best activity for methanol synthesis by hydrogenation of CO. The TPR, TPO and XPS analyses reveal that a new copper oxide phase is formed in the calcined Cu/ZnO/ZrO2 catalysts by the dissolution of zirconium ions in copper oxide. In addition, the Cu/ZnO/ZrO2 catalyst with 15 wt.% of ZrO2 turns out to contain the largest amount of the new copper oxide phase. When the Cu/ZnO/ZrO2 catalysts is reduced, the Cu2+ species present in the ZrO2 lattice is transformed to Cu+ species. This leads to the speculation that the addition of ZrO2 to Cu/ZnO catalysts gives rise to the formation of Cu+ species, which is related to the methanol synthesis activity of Cu/ZnO/ZrO2 catalyst in addition to Cu metal particles. Consequently, the ratio of Cu+/Cu0 is an important factor for the specific activity of Cu/ZnO/ZrO2 catalyst for methanol synthesis. 相似文献
74.
Dong Jin Suh Tae-Jin Park Jong Ho Sonn Hyoung-Yong Han Jong-Choo Lim 《Korean Journal of Chemical Engineering》2000,17(1):101-104
Aerogels of titania, zirconia, niobia, and silica were prepared by CO2 supercritical drying of the corresponding alcogels. Their porous texture could be modified by further aging of the alcogels.
This kind of textural modification was found to be different according to the nature of the metal precursor and sol-gel conditions.
This paper was presented at the 8th APCChE (Asia Pacific Confederation of Chemical Engineering) Congress held at Seoul between
August 16 and 19, 1999. 相似文献
75.
Water‐soluble urethane acrylate ionomers containing dimethylolpropionic acid (DMPA) were synthesized, changing the molecular components, and their ultraviolet (UV) coating properties were studied. It was found that the UV coating properties of the urethane acrylate ionomer films were very dependent on the molecular weight of the soft segment, the type of the diisocyanate, and the amount of neutralization. In general observations, the cured films displayed much improved mechanical properties, compared with conventional urethane acrylate film not containing ionic groups. The main reason for the improved film properties seemed to be attributed to the presence of ionic groups in the network. In dynamic mechanical analysis, two distinct glass transition temperatures, corresponding to the ionic hard domains and soft domains, were detected at high content of ionic groups. This suggested that the urethane acrylate network be composed of two phases. Consequently, the ionic hard domains formed by the phase separation from crosslinked network could act as a reinforcing filler, which possibly explains the improved film properties of the urethane acrylate ionomer films. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 1853–1860, 2000 相似文献
76.
Cheol Ho Lee Sang Wook Kim Jin Ho Nam Kwang S. Suh 《Polymer Engineering and Science》2000,40(4):857-862
Effects of particle size of Al(OH)3 (ATH) filler on electrical properties of ethylene propylene diene terpolymer (EPDM)/ATH compounds were studied. It was found that tracking and erosion resistance of EPDM/ATH compounds decreased while dielectric properties and 90°C water resistance were improved with the increase of particle size. Homocharge accumulates in the compounds, which increases first and then decreases with the increase of particle size. This was explained by the change of particle‐to‐particle distance due to filler size. 相似文献
77.
78.
79.
Seulah Lee Yeon Ji Suh Seonguk Yang Dong Geun Hong Akihito Ishigami Hangun Kim Jae-Seoun Hur Seung-Cheol Chang Jaewon Lee 《International journal of molecular sciences》2021,22(4)
Oxidative stress, mitochondrial dysfunction, and neuroinflammation are strongly associated with the pathogenesis of Parkinson’s disease (PD), which suggests that anti-oxidative and anti-inflammatory compounds might provide an alternative treatment for PD. Here, we evaluated the neuroprotective effects of evernic aid (EA), which was screened from a lichen library provided by the Korean Lichen Research Institute at Sunchon National University. EA is a secondary metabolite generated by lichens, including Ramalina, Evernia, and Hypogymnia, and several studies have described its anticancer, antifungal, and antimicrobial effects. However, the neuroprotective effects of EA have not been studied. We found that EA protected primary cultured neurons against 1-methyl-4-phenylpyridium (MPP+)-induced cell death, mitochondrial dysfunction, and oxidative stress, and effectively reduced MPP+-induced astroglial activation by inhibiting the NF-κB pathway. In vivo, EA ameliorated MPTP-induced motor dysfunction, dopaminergic neuronal loss, and neuroinflammation in the nigrostriatal pathway in C57BL/6 mice. Taken together, our findings demonstrate that EA has neuroprotective and anti-inflammatory effects in PD models and suggest that EA is a potential therapeutic candidate for PD. 相似文献
80.
Geometric error measurement of spiral bevel gears using a virtual gear model for STEP-NC 总被引:1,自引:0,他引:1
S. H. Suh E. S. Lee H. C. Kim J. H. Cho 《International Journal of Machine Tools and Manufacture》2002,42(3)
Geometric error measurement is required to evaluate the grade of the manufactured gears. Due to the complexity of the spiral bevel gear, direct measurement with the physical part has been conducted in a very limited way. In this paper, we present an indirect measurement based on the virtual gears model (VGM), obtained by NUBS fitting of the surface points measured by CMM (coordinate measuring machine). By comparing the VGM with CAD model (soft-master model), various errors such as tooth profile error and tooth trace error can be automatically measured. The developed method is simple and robust without requiring a special measuring device, and hence it can be applied for the industrial practice as a means for measuring the tooth profile and tooth trace errors which cannot be measured by the conventional method. Further, the model-based method can be incorporated on the advanced CNC controller based on the new CAM–CNC interface scheme of STEP-NC [STEP (standard for transfer and exchange of product model data) based data model for CAM and CNC interface] as an on-line inspection module. Algorithmic details together with experimental validation results are given. 相似文献