全文获取类型
收费全文 | 205871篇 |
免费 | 15400篇 |
国内免费 | 7810篇 |
专业分类
电工技术 | 11270篇 |
技术理论 | 14篇 |
综合类 | 11222篇 |
化学工业 | 35708篇 |
金属工艺 | 10549篇 |
机械仪表 | 12004篇 |
建筑科学 | 16419篇 |
矿业工程 | 4945篇 |
能源动力 | 5854篇 |
轻工业 | 12699篇 |
水利工程 | 3220篇 |
石油天然气 | 11092篇 |
武器工业 | 1348篇 |
无线电 | 25487篇 |
一般工业技术 | 26725篇 |
冶金工业 | 10939篇 |
原子能技术 | 2114篇 |
自动化技术 | 27472篇 |
出版年
2024年 | 882篇 |
2023年 | 3268篇 |
2022年 | 5836篇 |
2021年 | 7936篇 |
2020年 | 5800篇 |
2019年 | 5015篇 |
2018年 | 5421篇 |
2017年 | 6211篇 |
2016年 | 5696篇 |
2015年 | 7301篇 |
2014年 | 9528篇 |
2013年 | 12274篇 |
2012年 | 12232篇 |
2011年 | 13879篇 |
2010年 | 11622篇 |
2009年 | 11463篇 |
2008年 | 10877篇 |
2007年 | 10475篇 |
2006年 | 10862篇 |
2005年 | 9634篇 |
2004年 | 6570篇 |
2003年 | 5780篇 |
2002年 | 5255篇 |
2001年 | 4726篇 |
2000年 | 4871篇 |
1999年 | 5640篇 |
1998年 | 5286篇 |
1997年 | 4354篇 |
1996年 | 3961篇 |
1995年 | 3312篇 |
1994年 | 2769篇 |
1993年 | 2187篇 |
1992年 | 1701篇 |
1991年 | 1277篇 |
1990年 | 1019篇 |
1989年 | 877篇 |
1988年 | 681篇 |
1987年 | 496篇 |
1986年 | 394篇 |
1985年 | 334篇 |
1984年 | 212篇 |
1983年 | 198篇 |
1982年 | 163篇 |
1981年 | 145篇 |
1980年 | 131篇 |
1979年 | 97篇 |
1978年 | 63篇 |
1977年 | 63篇 |
1976年 | 77篇 |
1975年 | 38篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
971.
The fabrication of monolayers composed of nordihydroguaiaretic acid (NDGA), and hybrid films composed of NDGA-flavin adenine dinucleotide (FAD) adsorbed films was performed in neutral aqueous solutions to produce electrochemically active thin films exhibiting one and two redox couples, respectively. An electrochemical quartz crystal microbalance and cyclic voltammetry were used to study the in situ growth of the NDGA and hybrid NDGA/FAD film monolayers. The NDGA modified film electrocatalytically oxidized NADH, ascorbic acid, dopamine, and N2H4 in neutral aqueous solutions. Well-separated voltammetric peaks were observed for dopamine and uric acid mixtures, and also for ascorbic acid and uric acid mixtures using the NDGA/GC modified electrode. When transferred to various aqueous buffered solutions, the two redox couples of the NDGA/FAD hybrid film and their formal potentials were observed to be pH-dependent. The electrocatalytic oxidation and reduction of NADH and NAD+ by a NDGA/FAD hybrid film in neutral aqueous solutions was carried out, and the electrocatalytic oxidation of NADH was performed using a NDGA/FAD hybrid film. 相似文献
972.
MgO/Ni系梯度功能材料的设计与制备 总被引:11,自引:0,他引:11
对MgO/Ni系梯度功能材料(FGM),分别用实验和微观力学模型测定和计算了用于热应力缓和设计的各物性参数。讨论了两种结果之间存在差异的原因。用有限元方法模拟了制备过程中FGM的热应力,得到MgO/Ni系FGM的综合设计准则。按设计结果进一步调整粉末工艺性质,成功地烧制出MgO/Ni系FGM。 相似文献
973.
974.
高冲击玻纤增强聚丙烯的研制与应用 总被引:2,自引:1,他引:2
利用玻璃纤维、SBS橡胶和高密度聚乙烯增韧聚丙烯。增韧后的聚丙烯冲击强度是只用玻纤增强的2倍以上,而其它性能影响较小。 相似文献
975.
Wenjun Zhang Fangqing Zhang Yafei Zhang Guanghua Chen Xiangliu Jiang 《Diamond and Related Materials》1994,3(11-12)
Highly purified polycrystalline wafers of Zr and Hf were chosen as substrates for diamond deposition by means of the d.c. arc discharge plasma CVD method. Polycrystalline diamond films were formed on both substrates. Scanning electron microscopy and high resolution X-ray diffraction were used to investigate the surface morphology of the diamond films and the composition of the interface layers between the diamond films and substrates. The experiments showed that the transition layer between the diamond films and Zr substrates was ZrC, ZrH and ZrC0.32H1.2. For Hf substrates, in addition to HfC, it is supposed that there were also some hydrides or carbohydrides in the transition layer, because several X-ray reflections appeared which could not be assigned to Hf, HfC or diamond. 相似文献
976.
The presence of wall slip during the flow of polymeric melts has significant ramifications on the melts' processability. In this study, the effects of materials of construction and surface roughness on the wall slip behavior of a linear low density polyethylene were investigated, using capillary flow. Capillaries, constructed from copper, stainless steel, aluminum, and glass, were used. The inner surface roughness of the capillaries were characterized by the employment of a profilometer and scanning electron microscopy. The roughness profiles of copper capillaries were also altered by the employment of chemical etching. Using Mooney's analysis, the wall slip velocity values were determined to be in the range of 0.09 to 1.34 mm/s. The wall slip velocity values were the highest for stainless steel and were negligible for aluminum. The relative work of adhesion values of polyethylene were the smallest for stainless steel and copper and the highest for glass. Overall, the wall slip velocity values increased with decreasing surface roughness of the capillaries and with decreasing work of adhesion. © 1993 John Wiley & Sons, Inc. 相似文献
977.
Hao Liang Zhiqiang Zheng Zengchang Li Jie Xu Biao Chen Hui Zhao Qijin Zhang Hai Ming 《应用聚合物科学杂志》2004,93(2):681-685
A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004 相似文献
978.
Pengbao Lian Qiang Liu Lizhen Chen Cai Cao Jiaxiang Zhao Jianlong Wang 《中国化学工程学报》1982,28(10):2634-2639
In this paper, the solubility of 4-nitroimidazole in twelve pure solvents (toluene, benzene, 1,4-dioxane, acetonitrile, ethyl acetate, acetone, GBL, ethanol, methanol, n-butanol, DMF and NMP) were determined by using the laser monitoring system from 278.15 K to 323.15 K under 101.1 kPa, which are 0.00018-0.00070, 0.00021-0.00073, 0.00034-0.00092, 0.00038-0.00142, 0.00047-0.00120, 0.00126-0.00303, 0.00225-0.00517, 0.00310-0.00724, 0.00467-0.00982, 0.00453-0.01940, 0.01947-0.04652, and 0.04670-0.07452, respectively. At constant temperature, the mole fraction solubility of 4-nitroimidazole were increased as the following order: toluene < benzene < 1,4-dioxane < (ethyl acetate or acetonitrile) < acetone < GBL < ethanol < (methanol or nbutanol) < DMF < NMP, and the solubility of 4-nitroimidazole in (ethyl acetate, acetonitrile) and (methanol, n-butanol) had an intersection point at 297.55 K and 281.85 K, respectively. The solubility of 4-nitroimidazole could be increased with increasing temperature in twelve pure solvents. The ideal model, modified Apelblat equation, polynomial empirical equation, and λh equation were used to correlate the experimental values. The experimental solubility values were employed to calculate the standard dissolution enthalpy, standard dissolution entropy and Gibbs energy. The dissolution of 4-nitroimidazole could be an endothermic process in twelve pure solvents. The determination and fitting solubility of 4-nitroimidazole have important guiding significance for the purification and crystallization of its preparation process. 相似文献
979.
Chen Kou Wei H. Ted Davis Eugenia A. Davis Joan Gordon 《Chemical Engineering Communications》1987,56(1):269-284
A capillary tube model was solved to investigate the influence of mass transfer coefficient, temperature, and front depth on the evaporation rate during the penetrating-front period of water-filled porous media dried in hot air. The results show that increasing the flow rate of the drying air is not so efficient as increasing the sample temperature. Due to attenuating diffusion rate, the rate of liquid front migration decreases with time. The calculations explain the falling rate period behavior of sandstone heated at 121°C. Trends depicted by the model may be useful for the design of heating conditions for drying processes. 相似文献
980.