神农大酒店地源热泵空调系统技术方案分析

为了提高地源热泵空调系统的能效比并降低地源热泵空调系统地埋换热器的换热器面积,减小系统投资,对神农大酒店地源热泵空调系统采用不同技术方案,从系统热负荷、全年不平衡热负荷、冷却水流量、系统能效比等几方面进行理论分析,经综合比较,采用冷热一体机与热水机串联+冷却塔辅助散热的复合式系统方案优于其他方案。但此方案受制于目前市场上冷热一体机的冷凝器和热水机蒸发器的循环水流通截面积不相等,引起流动阻力增加,影响使用效果。因此开发出冷热一体机的冷凝器和热水机蒸发器的循环水流通截面积相等的产品,是科研工作者和生产厂家要解决的首要问题。     

基于液压驱动的数控机床上下料 机械手的设计与研究

针对数控机床自动化生产线的工件上下料,设计了机械手的手腕部位和执行手爪的齿轮式机械结构。采用液压控制系统控制机械手的3个执行机构运动,其中,垂直手臂的上升、下降采用垂直升降液压缸,手腕部位的前伸、后缩采用水平伸缩液压缸,执行手爪的夹紧、张开采用柱塞液压缸。对机械手的力学性能进行分析与计算,证明机械手装置简单可靠,具备抓取、搬运30 kg工件的能力。通过对PLC控制系统的设计,使机械手达到了生产线上工件自动上下料的功能要求。     

聚乙烯薄膜的氟化研究

为了改善聚乙烯薄膜材料表面的反应性能,对聚乙烯薄膜进行了氟化改性研究。在恒定的温度下,通过改变氟化反应的压强参数值,制备了氟化薄膜改性样品,并采用红外光谱和扫描电镜等对样品进行分析,以探究聚乙烯薄膜氟化的较佳条件。研究结果表明,在氟化温度为60℃,且以氮气为保护气的条件下,进行130,220 mPa压力下的递进氟化,能较好地实现聚乙烯薄膜表面的羧化和氟化改性,提高聚乙烯薄膜表面的反应能力。     

Mo、Ni含量与Ti(C,N)基金属陶瓷组织和性能之间的关系

本文研究了Mo、Ni含量对Ti（C，N）基金属陶瓷组织和性能的影响．结果表明，Mo、Ni含量对组织和性能有很大影响，化学成分决定了组织和性能．     

油田站外单管集油辅助工艺对比

为了解决部分油井无法单管输送的问题,采用PIPESIM模拟软件对不同含水率、不同集输半径和不同产液量油井的集输管线进行计算分析,同时结合各油田单管集输设计经验,得出中质原油站外系统单管集油工艺改造的技术界限,而对于达不到技术界限的油井,可以通过辅助措施实现单管集油,通过对比电磁加热器、空气源热泵、管道内置电伴热、井口气电加热器、油井保温隔热油管、地热、太阳能光热技术及井口加药等单管辅助措施的原理及工艺特点,最终确定在不同工况条件下的辅助单管集输措施,为油田站外单管集输工艺选择和优化提供了理论依据。     

蓖麻油-马来酸酐-苯乙烯双功能润滑油添加剂的合成

传统石油基润滑油添加剂对环境的不利影响,使可生物降解的植物油基润滑油添加剂成为研究热点。以蓖麻油(CO)、马来酸酐(MAH)、苯乙烯(ST)为原料,偶氮二异丁腈(AIBN)为引发剂,甲苯为溶剂,合成了蓖麻油-马来酸酐-苯乙烯共聚物(PCMAS)。通过红外光谱(FT-IR)、核磁共振氢谱(¹H NMR)表征了蓖麻油-马来酸酐-苯乙烯共聚物的结构,采用凝胶渗透色谱(GPC)测定了聚合物的相对分子质量及其多分散性指数,采用热重分析研究了聚合物的热稳定性,并对聚合物作为润滑油降凝剂和黏度指数改进剂的性能进行了评价。结果表明：当单体质量比m(CO)∶m(MAH)∶m(ST)=1.0∶0.2∶1.2、引发剂AIBN含量占总单体的0.5%(质量分数)、反应时间4 h、反应温度90℃时,共聚物收率为68.39%,其数均相对分子质量为0.348×10⁵,多分散性指数为4.77。将蓖麻油-马来酸酐-苯乙烯共聚物添加到润滑油馏分(350～395℃)中,可降低润滑油的凝点,并提高其黏度指数。蓖麻油-马来酸酐-苯乙烯共聚物可作为一种具有降凝增黏双重功能的润滑油添加剂。     

Thermally activated giant piezoelectricity and enhanced interface elastic strain-mediated magnetoelectric coupling

Perovskite materials with compositions in the vicinity of the steep morphotropic phase boundary (MPB) exhibit various intriguing properties including giant piezoelectricity and large dielectric constant. Aside from composition, the phase configuration of the perovskites is also strongly related to the ambient temperature. Here, we report a giant piezoelectricity of 10 980 pm/V at 93°C in the 0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃ (PMN-PT) single crystals which is more than five times larger than that at room temperature. The enhanced piezoelectricity can be attributed to the instability of the thermally induced tetragonal phase which can be converted to the orthorhombic phase by the external electric field in the <011> oriented single crystal. The transverse piezoelectricity has been investigated by measuring the electric-field-dependent ferromagnetic resonance (FMR) field in the CoFeB/PMN-PT magnetoelectric (ME) heterostructures. The ME coupling coefficient has been increased from 49.3 to 476 Oe cm/kV as temperature increased from 25 to 90°C. The findings reveal that both longitudinal and transverse piezoelectricity in the PMN-PT single crystals can be greatly enhanced by proper setting of ambient temperature, indicating an effective route for the design of strain-mediated tunable devices with ultralow driving voltage.     

Sintering parameter optimization of Tb3Al5O12 magneto-optical ceramics by vacuum sintering and HIP post-treatment

Transparent terbium aluminum garnet (TAG) ceramics were achieved by the vacuum sintering plus HIP post-treating from the coprecipitated TAG nanoparticles. The influences of vacuum sintering temperature and sintering aid TEOS on the optical quality of the TAG ceramics were studied. The results show that with the increase of sintering temperature, the optical quality of TAG ceramics is improved gradually, and the in-line transmittance of the TAG ceramics treated at 1720°C for 20 hours under vacuum and then HIP post-treated at 1700°C for 3 hours under 200 MPa argon gas is 81.6% at 1064 nm. The sintering additive TEOS can improve the optical quality of TAG ceramics and inhibit the valence state change of Tb³⁺ ions to Tb⁴⁺ during the annealing process. The Verdet constant of the TAG ceramics at 632.8 nm is about −178 rad·T⁻¹·m⁻¹ at room temperature, which is 1.3 times that of the commercial TGG crystals (−134 rad·T⁻¹·m⁻¹).     

Bismuth-activated,narrow-band,cyan garnet phosphor Ca3Y2Ge3O12:Bi3+ for near-ultraviolet-pumped white LED application

Herein, a novel Bi³⁺-activated Ca₃Y₂Ge₃O₁₂ (CYGO) narrow-band cyan-emitting phosphor was synthesized. It can be excited from 320–420 nm, and the strongest excitation peak is located at 370 nm, which is suitable for current near-ultraviolet (NUV) chips perfectly. The full width at half maximum is at 52 nm. By analyzing the crystal structure of the sample, we infer that the Bi³⁺ ions replace the Y³⁺ site to form a highly symmetrical BiO₆ octahedron. The time-resolved photoluminescence (TRPL) spectra of CYGO: Bi³⁺ reveal that the only a single emission center exists in the host lattice. A warm white light–emitting diode (WLED) device with a low correlated color temperature (3148 K) and a high color rendering index (90.2) was fabricated by using the as-prepared sample, and the significant thermal stability of CYGO: Bi³⁺ guarantees its potential application in WLEDs. It is verified that the structure with only one crystallographic Y site for Bi³⁺ dopant occupation and highly symmetrical and dense structure is conducive to realize narrow-band emission, which will provide experience for researchers to explore more Bi³⁺-activated phosphors used for high-end lighting.     

Multiple Venting Behavior of Inner Dust Explosions

Combustion, Explosion, and Shock Waves - Explosion venting experiments of corn starch are carried out in a small-scale container. With the help of a high-speed camera and a pressure sensor, an...