Physical properties of electron beam irradiated poly(vinyl butyral) composites with carbamate,imidazole, and tetrazolium dye

Films of poly(vinyl butyral) composites with triphenyl tetrazolium chloride dye (TTC) and the antioxidant nickel dibutyl dithiocarbamate (NBC) or 2‐mercaptobenzimidazole (MBI) were prepared by the solution casting method using butyl alcohol as a solvent. The effect of various doses of electron beam irradiation (50–200 kGy) on color response, thermal, and mechanical properties were investigated. The color measurements showed that the films of the different composites possessed a high sensitivity to electron beam irradiation, in which the nearly colorless films were changed to deep red color, which can be easily detected by visual observations. In addition, the change in color depends on irradiation dose and the contents of the TTC dye. Moreover, the presence of the antioxidants NBC or MBI has no effect on the development of color. However, PVB/TTC and PVB/TTC/MBI composites showed high regular change in color as a function of irradiation dose. The thermogravimetric analysis used to study the thermal stability indicated that PVB/TTC composites either before or after electron beam irradiation are thermally more stable than neat PVB polymer. The presence of the antioxidants NBC or MBI offered protection to PVB/TTC composites against decomposition or oxidative degradation resulted from irradiation. Blending unirradiated PVB with TTC dye, mixture of TTC and NBC, and mixture of TTC and MBI reduced the tensile strength by 4, 20, and 17% upon blending, respectively. However, the reduction in tensile strength of the entire composite films (～7% based on the initial value) upon exposure to a dose of 50 kGy is acceptable for practical applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4358–4365, 2006     

EVALUATION OF SURFACE FORCE-PORE FLOW AND MODIFIED SURFACE FORCE-PORE FLOW MODELS FOR REVERSE OSMOSIS TRANSPORT

The surface force-pore flow (SF-PF) model of reverse osmosis transport and the extended and modified form (the MD-SF-PF model) have been employed to predict the performance of four aromatic polyamide (FilmTec, FT30)reverse osmosis membranes. The evaluation is based on a comparison of model predictions with experimental data. Dilute sodium chloride-water solution experimental data were used to estimate model parameters. The models are then used to predict flux and separation at various operating pressures and concentrations. Membrane performance (i.e., separation and permeate flux) can be well predicted by the MD-SF-PF model while the SF-PF model predicts the performance for the sodium chloride system less satisfactorily.     

Proactive discovery protocol with security enhancement for D2D communication system

With the increase in mobile traffic and the band-width demand, Device-to-Device (D2D) communication has gained tremendous interest by the researchers, cellular operators and equipment manufacturers. However, D2D communication has been limited to study the converge services at cell edge. D2D users that located outside the cellular network coverage haven’t received enough attention. Some of the problems faced in this case are discovering process of neighbor user equipment (UE) and services, as well as designing suitable and secure protocols for D2D communication. Toward these problems, in this paper, we propose security enhancement for D2D communication based on modified elliptic curve cryptography (MECC), which provides greater efficiency in computational overhead, key sizes and bandwidths for user’s authentication applied on proactive routing protocol for neighbor and service discovery. We study Diffie–Hellman, ElGamal and MECC techniques to improve service of D2D users at cell edge. Results show that the proposed scheme can strength the secrecy with less control overhead and can increase the robustness in a wide range of scenarios for service discovery in D2D networks.

     

Design of a compact dual‐band folded‐waveguide bandpass filter using multilayer waveguide resonators

A novel compact dual‐band bandpass filter based on multilayer folded‐waveguide (FWG) structure is presented in this article.In this design, slots are used to realize direct coupling between adjacent resonators and apertures are adopted to implement cross coupling between non‐adjacent resonators.A new technique of external quality factor of FWG resonator and coupling coefficients between different resonators are studied using full‐wave simulator. In order to demonstrate the proposed technique, a four‐pole dual‐band bandpass filter is designed, fabricated and measured using vector network analyzer. Measurement results which are well agreed with simulation results are presented. Moreover, four‐pole substrate integrated folded waveguide SIFW dual‐band bandpass filter, using two layers of slotted folded waveguide resonators, is demonstrated. The proposed filter has a compact size and it is excellent candidate for the application of wireless communication systems. © 2015 Wiley Periodicals, Inc. Int J RF and Microwave CAE 25:780–788, 2015.     

Emotional Loneliness and Coping Strategies: A Reference to Older Malaysians at Nursing Homes

This article presents an in-depth qualitative study using a phenomenological approach to understand loneliness among elderly individuals in Malaysia. The objective of the study was to understand how the Malaysian elderly perceive and understand social isolation as well as loneliness, with the aim of identifying the factors that cause emotional loneliness among the elderly in nursing homes. In addition, this study also explored their coping strategies when dealing with loneliness. Semi-structured interviews were conducted with ten elderly participants from two different nursing homes in Kuala Lumpur and Selangor with representatives from the three major ethnic groups of Malaysia. Based on the results, there are several factors that cause the elderly to feel lonely – health factors, lack of family ties, and the lack of communication and cognitive factors, such as memory and perception. It was also found that internal (expectations and optimism) and external (work and activities) coping strategies play major roles in overcoming loneliness. In conclusion, some recommendations are made to respective party families and the government to consider when developing plans to help the elderly overcome loneliness, which could strengthen the family and social support system in Malaysia.     

Mass spectrometric immunoassay and MRM as targeted MS-based quantitative approaches in biomarker development: Potential applications to cardiovascular disease and diabetes

Type 2 diabetes mellitus (T2DM) is an important risk factor for cardiovascular disease (CVD)—the leading cause of death in the United States. Yet not all subjects with T2DM are at equal risk for CVD complications; the challenge lies in identifying those at greatest risk. Therapies directed toward treating conventional risk factors have failed to significantly reduce this residual risk in T2DM patients. Thus newer targets and markers are needed for the development and testing of novel therapies. Herein we review two complementary MS-based approaches—mass spectrometric immunoassay (MSIA) and MS/MS as MRM—for the analysis of plasma proteins and PTMs of relevance to T2DM and CVD. Together, these complementary approaches allow for high-throughput monitoring of many PTMs and the absolute quantification of proteins near the low picomolar range. In this review article, we discuss the clinical relevance of the high density lipoprotein (HDL) proteome and Apolipoprotein A-I PTMs to T2DM and CVD as well as provide illustrative MSIA and MRM data on HDL proteins from T2DM patients to provide examples of how these MS approaches can be applied to gain new insight regarding cardiovascular risk factors. Also discussed are the reproducibility, interpretation, and limitations of each technique with an emphasis on their capacities to facilitate the translation of new biomarkers into clinical practice.     

Toward an efficient and scalable feature selection approach for internet traffic classification

There is significant interest in the network management and industrial security community about the need to identify the “best” and most relevant features for network traffic in order to properly characterize user behaviour and predict future traffic. The ability to eliminate redundant features is an important Machine Learning (ML) task because it helps to identify the best features in order to improve the classification accuracy as well as to reduce the computational complexity related to the construction of the classifier. In practice, feature selection (FS) techniques can be used as a preprocessing step to eliminate irrelevant features and as a knowledge discovery tool to reveal the “best” features in many soft computing applications. In this paper, we investigate the advantages and disadvantages of such FS techniques with new proposed metrics (namely goodness, stability and similarity). We continue our efforts toward developing an integrated FS technique that is built on the key strengths of existing FS techniques. A novel way is proposed to identify efficiently and accurately the “best” features by first combining the results of some well-known FS techniques to find consistent features, and then use the proposed concept of support to select a smallest set of features and cover data optimality. The empirical study over ten high-dimensional network traffic data sets demonstrates significant gain in accuracy and improved run-time performance of a classifier compared to individual results produced by some well-known FS techniques.     

Interleaving Guidance in Evolutionary Multi-Objective Optimization

In this paper, we propose a framework that uses localization for multi-objective optimization to simultaneously guide an evolutionary algorithm in both the decision and objective spaces. The localization is built using a limited number of adaptive spheres （local models） in the decision space. These spheres axe usually guided, using some direction information, in the decision space towards the areas with non-dominated solutions. We use a second mechanism to adjust the spheres to specialize on different parts of the Paxeto front by using a guided dominance technique in the objective space. Through this interleaved guidance in both spaces, the spheres will be guided towards different parts of the Paxeto front while also exploring the decision space efficiently. The experimental results showed good performance for the local models using this dual guidance, in comparison with their original version.     

Interfacial Connections between Organic Perovskite/n+ Silicon/Catalyst that Allow Integration of Solar Cell and Catalyst for Hydrogen Evolution from Water

The rapidly increasing solar conversion efficiency (PCE) of hybrid organic–inorganic perovskite (HOIP) thin-film semiconductors has triggered interest in their use for direct solar-driven water splitting to produce hydrogen. However, application of these low-cost, electronic-structure-tunable HOIP tandem photoabsorbers has been hindered by the instability of the photovoltaic-catalyst-electrolyte (PV+E) interfaces. Here, photolytic water splitting is demonstrated using an integrated configuration consisting of an HOIP/n⁺silicon single junction photoabsorber and a platinum (Pt) thin film catalyst. An extended electrochemical (EC) lifetime in alkaline media is achieved using titanium nitride on both sides of the Si support to eliminate formation of insulating silicon oxide, and as an effective diffusion barrier to allow high-temperature annealing of the catalyst/TiO₂-protected-n⁺silicon interface necessary to retard electrolytic corrosion. Halide composition is examined in the (FA_1-xCs_x)PbI₃ system with a bandgap suitable for tandem operation. A fill factor of 72.5% is achieved using a Spiro-OMeTAD-hole-transport-layer (HTL)-based HOIP/n⁺Si solar cell, and a high photocurrent density of −15.9 mA cm⁻² (at 0 V vs reversible hydrogen electrode) is attained for the HOIP/n⁺Si/Pt photocathode in 1 m NaOH under simulated 1-sun illumination. While this thin-film design creates stable interfaces, the intrinsic photo- and electro-degradation of the HOIP photoabsorber remains the main obstacle for future HOIP/Si tandem PEC devices.     

Feature Selection for Detecting ICMPv6-Based DDoS Attacks Using Binary Flower Pollination Algorithm

Internet Protocol version 6 (IPv6) is the latest version of IP that goal to host 3.4 × 10³⁸ unique IP addresses of devices in the network. IPv6 has introduced new features like Neighbour Discovery Protocol (NDP) and Address Auto-configuration Scheme. IPv6 needed several protocols like the Address Auto-configuration Scheme and Internet Control Message Protocol (ICMPv6). IPv6 is vulnerable to numerous attacks like Denial of Service (DoS) and Distributed Denial of Service (DDoS) which is one of the most dangerous attacks executed through ICMPv6 messages that impose security and financial implications. Therefore, an Intrusion Detection System (IDS) is a monitoring system of the security of a network that detects suspicious activities and deals with a massive amount of data comprised of repetitive and inappropriate features which affect the detection rate. A feature selection (FS) technique helps to reduce the computation time and complexity by selecting the optimum subset of features. This paper proposes a method for detecting DDoS flooding attacks (FA) based on ICMPv6 messages using a Binary Flower Pollination Algorithm (BFPA-FA). The proposed method (BFPA-FA) employs FS technology with a support vector machine (SVM) to identify the most relevant, influential features. Moreover, The ICMPv6-DDoS dataset was used to demonstrate the effectiveness of the proposed method through different attack scenarios. The results show that the proposed method BFPA-FA achieved the best accuracy rate (97.96%) for the ICMPv6 DDoS detection with a reduced number of features (9) to half the total (19) features. The proven proposed method BFPA-FA is effective in the ICMPv6 DDoS attacks via IDS.