The removal of carbon residue from ZnAl2O4 nanopowders by annealing at 500–800 °C leads to a decrease of specific surface area from 228.1 m2/g to 47.6 m2/g. At the same time, the average crystallite size increased from 5.1 nm to 14.9 nm. In order to overcome these drawbacks, a new solution for removing the carbon residue has been suggested: chemical oxidation using hydrogen peroxide. In terms of carbon removal, a H2O2 treatment for 8 h at 107 °C proved to be equivalent to a heat treatment of 1 h at 600 °C. The benefits of chemical oxidation over thermal oxidation were obvious. The specific surface area was much larger (188.1 m2/g) in the case of the powder treated with H2O2. The average crystallite size (5.8 nm) of ZnAl2O4 powder treated with H2O2 was smaller than the crystallite size (8.2 nm) of the ZnAl2O4 powder annealed at 600 °C. 相似文献
Aneurysms and vascular malformations of the brain represent an important source of intracranial hemorrhage and subsequent mortality and morbidity. We are only beginning to discern the involvement of microglia, the resident immune cell of the central nervous system, in these pathologies and their outcomes. Recent evidence suggests that activated proinflammatory microglia are implicated in the expansion of brain injury following subarachnoid hemorrhage (SAH) in both the acute and chronic phases, being also a main actor in vasospasm, considerably the most severe complication of SAH. On the other hand, anti-inflammatory microglia may be involved in the resolution of cerebral injury and hemorrhage. These immune cells have also been observed in high numbers in brain arteriovenous malformations (bAVM) and cerebral cavernomas (CCM), although their roles in these lesions are currently incompletely ascertained. The following review aims to shed a light on the most significant findings related to microglia and their roles in intracranial aneurysms and vascular malformations, as well as possibly establish the course for future research. 相似文献
The conventional pulsed gradient Hahn or stimulated echo methods for diffusion measurements are briefly reviewed. Compared to these techniques, unconventional NMR diffusometry variants based on gradients of the amplitude of the radio frequency field, on nonlinear (or multiple) echoes, and on imaging techniques open promising aspects depending on the application envisaged. A series of typical pulse sequences representing the diversity of NMR diffusometry methods is described and discussed with respect to advantages and disadvantages. 相似文献
A detailed characterization of a conventional low-flow electrospray ionization (ESI) source for mass spectrometry (MS) using solution compositions typical of reversed-phase liquid chromatography is reported. Contrary to conventional wisdom, the pulsating regime consistently provided better ESI-MS performance than the cone-jet regime for the interface and experimental conditions studied. This observation is supported by additional measurements showing that a conventional heated capillary interface affords more efficient sampling and transmission for the charged aerosol generated by a pulsating electrospray. The pulsating electrospray provided relatively constant MS signal intensities over a wide range of voltages, while the signal decreased slightly with increasing voltage for the cone-jet electrospray. The MS signal also decreased with increasing emitter-interface distance for both pulsating and cone-jet electrosprays due to the expansion of the charged aerosol plume. At flow rates below 100 nL/min, the MS signal increased with increasing flow rate due to increased number of gas-phase ions produced. At flow rates greater than 100 nL/min, the signal reached a plateau due to decreasing ionization efficiency at larger flow rates. These results suggest approaches for improving MS interface performance for low-flow (nano- to micro-) electrosprays. 相似文献
Heatline visualization technique is used to understand heat transport path in an inclined non-uniformly heated enclosure filled with water based CuO nanofluid. The cavity has square cross-section and it is non-uniformly heated from a wall and cooled from opposite wall while other walls are adiabatic. The governing equations which are continuity, momentum and energy equations are solved using finite volume method. The dimensionless heatfunction for nanofluid heat flow is defined and solved to determine heatline patterns. Calculations were performed for Rayleigh numbers of 103, 104 and 105, inclination angle of 0°, 30°, 60° and 90°, and nanoparticle fraction of 0, 0.02, 0.04, 0.06, 0.08 and 0.1. It is observed that heat transfer in the cavity increases by adding nanoparticles. The rate of increase is greater for the enclosures with low Rayleigh number. Visualization of heatline is successfully applied to nanoparticle convective flows. Based on the heatline patterns, three heat transfer regions are observed and discussed in details. 相似文献
The aim of the present contribution is to understand how ionic strength, brought by the addition of salt to laponite/PEO nanocomposite dispersions, influences the texture and adhesion characteristics at nano‐ and microscales in multilayered nanocomposite films prepared from such dispersions. At the nano‐scale, SAXS and XRD measurements indicated that the clay platelets orient parallel to the film plane and that the polymer chains intercalate the clay platelets regardless of salt addition. A gradual transition from an agglomerated structure, containing polymer‐rich and clay‐rich domains, to a fine‐balanced structure with smaller distinct details without excess PEO was observed, via AFM, on the exposed edges of cryo‐microtomed films with increasing ionic strength.