Green Blends Based on Ionic Liquids with Improved Performance for Membrane Technology: Perspectives for Environmental Applications

Present research was directed towards the development of new high-performance and cost-effective polysulfone membranes (PSFQ) by introducing ionic liquids (ILs—Cyphos 101 IL and Aliquat 336) into their matrix. Variation of ILs was performed with the aim to find the one that brings new properties and improves the functionality and selectivity of PSFQ membranes in ultrafiltration processes. Based on the obtained results of the rheological study, we established the compatibility of compounds and optimal content of the used ILs, namely 3 wt% and 15 wt% Cyphos 101 IL and compositions varying between 3 and 15 wt % Aliquat 336. Results indicated that the ILs acted as plasticizers when they were added to the system, a helpful aspect in processing membranes used in water decontamination. The efficiency and performance of the membranes were evaluated by their use in the treatment of diclofenac (DCF)-containing waters. Membranes obtained from PSFQ/Aliquat 336 solution containing 15 wt% IL exhibited a 97% removal degree of DCF in the treatment process of 50 mL solution containing 3 mg/L DCF. The separation efficiency was kept constant for four filtration/cleaning cycles. The results indicated an improvement in membrane performance as the amount of IL in their structure increased, which confirms the potential for application in water treatment processes.     

Whole life cost performance of domestic rainwater harvesting systems in the United Kingdom

Rainwater harvesting (RWH) can be used to reduce the demand for potable mains water. At the single‐building scale, previous research has focused on water‐saving potential, while financial assessment has either been omitted or considered in an ad hoc manner. This paper reports on the application of a more rigorous financial analysis of domestic RWH systems than had been conducted previously. Whole life costing was selected as the most appropriate financial assessment technique. A total of 3840 domestic system configurations were assessed at a daily time step, taking into account various stakeholder perspectives and future cost scenarios. In each case, it was found that harvesting rainwater was significantly less cost effective than relying solely on mains‐only water. The domestic RWH systems generally resulted in financial losses approximately equal to their capital costs. Without significant financial support, domestic RWH is unlikely to be cost effective for all reasonably foreseeable scenarios.